Concept explainers
(a)
Interpretation:
The plausible mechanism for the given transformations should be drawn and identified.
Concept Introduction:
Dehydration reaction:
Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid.
Alcohol is reaction with concentrated sulfuric acid, first alcohol gets protonated forms carbocation (more stable carbocation) followed by elimination of proton (
Tertiary carbocation is more stable than the secondary, secondary carbocation is more stable than primary.
In dehydration reaction, sulfuric acid is act as a proton donor, and which is used to protonate the alcohol and makes carbocation therefore sulfuric acid is the driving force of the reaction. Dehydration reaction will not go without acid (sulfuric acid).
(b)
Interpretation:
The plausible mechanism for the given transformations should be drawn and identified.
Concept Introduction:
Dehydration reaction:
Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid.
Alcohol is reaction with concentrated sulfuric acid, first alcohol gets protonated forms carbocation (more stable carbocation) followed by elimination of proton (
Tertiary carbocation is more stable than the secondary, secondary carbocation is more stable than primary.
In dehydration reaction, sulfuric acid is act as a proton donor, and which is used to protonate the alcohol and makes carbocation therefore sulfuric acid is the driving force of the reaction. Dehydration reaction will not go without acid (sulfuric acid).
(c)
Interpretation:
The plausible mechanism for the given transformations should be drawn and identified.
Concept Introduction:
Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via
E1 reaction is a unimolecular elimination reaction to produce alkene compounds in which carbocation is formed as an intermediate and it has stepwise mechanism.
E2 reaction is a bimolecular elimination reaction in which alkene compounds formed in a single step.
Example,
Alkenes are formed when alcohols are treated with strong acid via eliminating one β-proton and the
Alkenes are formed when
Curved arrows are used for drawing the mechanism of reaction.
The tertiary carbocation is more stable than secondary carbocation.
(d)
Interpretation:
The plausible mechanism for the given transformations should be drawn and identified.
Concept Introduction:
Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via
E1 reaction is a unimolecular elimination reaction to produce alkene compounds in which carbocation is formed as an intermediate and it has stepwise mechanism.
E2 reaction is a bimolecular elimination reaction in which alkene compounds formed in a single step.
Example,
Alkenes are formed when alcohols are treated with strong acid via eliminating one β-proton and the
Alkenes are formed when alkyl halides are treated with bases via eliminating one β-proton and one α-halo group of the alkyl halide.
Curved arrows are used for drawing the mechanism of reaction.
The tertiary carbocation is more stable than secondary carbocation.
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Chapter 7 Solutions
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