Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 7, Problem 57P

(a)

Interpretation Introduction

Interpretation:

The way by which given compound is synthesized from ethyne should be given.

Concept Introduction:

Lindlar catalyst: The catalyst is used for the hydrogenation of alkynes in a syn manner.  This means both hydrogen are added on the same side across the triple bond and the product obtained will be a cis product.

Sodium in liquid ammonia: The catalyst is used for the formation of trans alkenes from alkynes.  Because of its more reactivity towards triple bonds, the reaction will stop at the formation of alkenes.

Pd/C: Hydrogenation can done using this catalyst and converts alkenes to alkanes.  The addition will be a syn addition.

Erythro isomer: In a Fischer Projection formula, if identical substituents are on the same side, then the isomer can be called as erythro.

Threo isomer: In a Fischer projection formula, if identical substituents are on the different side, then the isomer can be called as threo.

Meso compound: It is a symmetric compound which has the plane of symmetry.  If there are two chirality centres and same set of four groups are attached on each chirality centre, then it can be called as meso compound.

(b)

Interpretation Introduction

Interpretation:

The way by which given compound is synthesized from ethyne should be given.

Concept Introduction:

Lindlar catalyst: The catalyst is used for the hydrogenation of alkynes in a syn manner.  This means both hydrogen are added on the same side across the triple bond and the product obtained will be a cis product.

Sodium in liquid ammonia: The catalyst is used for the formation of trans alkenes from alkynes.  Because of its more reactivity towards triple bonds, the reaction will stop at the formation of alkenes.

Pd/C: Hydrogenation can done using this catalyst and converts alkenes to alkanes.  The addition will be a syn addition.

Erythro isomer: In a Fischer Projection formula, if identical substituents are on the same side, then the isomer can be called as erythro.

Threo isomer: In a Fischer Projection formula, if identical substituents are on the different side, then the isomer can be called as threo.

Meso compound: It is a symmetric compound which has the plane of symmetry.  If there are two chirality centres and same set of four groups are attached on each chirality centre, then it can be called as meso compound.

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Chapter 7 Solutions

Organic Chemistry (8th Edition)

Ch. 7.6 - Prob. 12PCh. 7.6 - Prob. 13PCh. 7.7 - Prob. 14PCh. 7.7 - Which alkyne should be used for the synthesis of...Ch. 7.7 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.8 - Only one alkyne forms an aldehyde when it...Ch. 7.9 - Describe the alkyne you should start with and the...Ch. 7.9 - Prob. 20PCh. 7.10 - Prob. 21PCh. 7.10 - Prob. 22PCh. 7.10 - Prob. 23PCh. 7.10 - Rank the following from strongest base to weakest...Ch. 7.10 - Prob. 26PCh. 7.12 - Prob. 28PCh. 7 - What is the major product obtained from the...Ch. 7 - Draw a condensed structure for each of the...Ch. 7 - A student was given the structural formula of...Ch. 7 - Prob. 32PCh. 7 - What is each compounds systematic name?Ch. 7 - What reagents should be used to carry out the...Ch. 7 - Prob. 35PCh. 7 - Draw the mechanism for the following reaction:Ch. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - What is the major product of the reaction of 1 mol...Ch. 7 - Answer Problem 39, parts a-b, using 2-butyne as...Ch. 7 - What is each compounds systematic name? a....Ch. 7 - What is the molecular formula of a hydrocarbon...Ch. 7 - a. Starting with 3-methyl 1-butyne, how can you...Ch. 7 - Prob. 44PCh. 7 - Which of the following pairs are keto-enol...Ch. 7 - Prob. 46PCh. 7 - Do the equilibria of the following acid-base...Ch. 7 - What is each compounds systematic name?Ch. 7 - What stereoisomers are obtained when 2-butyne...Ch. 7 - Prob. 50PCh. 7 - Draw the keto tautomer for each of the following:Ch. 7 - Show how each of the following compounds can be...Ch. 7 - A chemist is planning to synthesize 3-octyne by...Ch. 7 - Prob. 54PCh. 7 - What stereoisomers are obtained from the following...Ch. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Show how the following compound can be prepared...Ch. 7 - Prob. 60P
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