EBK CHEMISTRY
9th Edition
ISBN: 8220100453809
Author: ZUMDAHL
Publisher: Cengage Learning US
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Chapter 7, Problem 22Q
Describe briefly why the study of
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Chapter 7 Solutions
EBK CHEMISTRY
Ch. 7 - Four types of electromagnetic radiation (EMR) are...Ch. 7 - Characterize the Bohr model of the atom. In the...Ch. 7 - What experimental evidence supports the quantum...Ch. 7 - List the most important ideas of the quantum...Ch. 7 - What are quantum numbers? What information do we...Ch. 7 - How do 2p orbitals differ from each other? How do...Ch. 7 - Four blocks of elements in a periodic table refer...Ch. 7 - What is the difference between core electrons and...Ch. 7 - Prob. 9RQCh. 7 - The radius trend and the ionization energy trend...
Ch. 7 - Prob. 1ALQCh. 7 - Defend and criticize Bohrs model. Why was it...Ch. 7 - The first four ionization energies for the...Ch. 7 - Compare the first ionization energy of helium to...Ch. 7 - Which has the larger second ionization energy,...Ch. 7 - Explain why a graph of ionization energy versus...Ch. 7 - Without referring to your text, predict the trend...Ch. 7 - Account for the fact that the line that separates...Ch. 7 - Explain electron from a quantum mechanical...Ch. 7 - Choose the best response for the following. The...Ch. 7 - Consider the following statement "The ionization...Ch. 7 - Prob. 12ALQCh. 7 - How does probability fit into the description of...Ch. 7 - What is meant by an orbital?Ch. 7 - Explain the difference between the probability...Ch. 7 - Is the following statement true or false? The...Ch. 7 - Which is higher in energy, the 2s or 2p orbital,...Ch. 7 - Prove mathematically that it is more energetically...Ch. 7 - What type of relationship (direct or inverse) e...Ch. 7 - What do we mean by the frequency of...Ch. 7 - Explain the photoelectric effectCh. 7 - Describe briefly why the study of electromagnetic...Ch. 7 - How does the wavelength of a fast-pitched baseball...Ch. 7 - The following is an energy-level diagram for...Ch. 7 - The Bohr model works for only one electron...Ch. 7 - We can represent both probability and radial...Ch. 7 - Consider the representations of the p and d atomic...Ch. 7 - The periodic table consists of four blocks of...Ch. 7 - Many times the claim is made that subshells...Ch. 7 - Prob. 30QCh. 7 - Elements with very large ionization energies also...Ch. 7 - The changes in electron affinity as one goes down...Ch. 7 - Why is it much harder to explain the line spectra...Ch. 7 - Scientists use emission spectra to confirm the...Ch. 7 - Does the minimization of electron-electron...Ch. 7 - In the hydtogen atom, what is the physical...Ch. 7 - The work function is the energy required to remove...Ch. 7 - Many more anhydrous lithium salts are hygroscopic...Ch. 7 - The laser in an audio CD player uses light with u...Ch. 7 - An FM radio station broadcasts at 99.5 MHz....Ch. 7 - Microwave radiation has a wavelength on the order...Ch. 7 - A photon of ultraviolet (UV) light possesses...Ch. 7 - Octyl methoxycinoamate and oxybenzone are common...Ch. 7 - Human color vision is " produced" by the nervous...Ch. 7 - Consider the following waves representing...Ch. 7 - One type of electromagnetic radiation has a...Ch. 7 - Carbon absorbs energy at a wavelength of 150. nm....Ch. 7 - X rays have wavelengths on the order of 1 1010 m....Ch. 7 - The work function of an element is the energy...Ch. 7 - It takes 208.4 kJ of energy to remove 1 mole of...Ch. 7 - It takes 7.21 1019 J of energy to remove an...Ch. 7 - Ionization energy is the energy required to remove...Ch. 7 - Calculate the de Broglie wavelength for each of...Ch. 7 - Neutron diffraction is used in determining the...Ch. 7 - A particle has a velocity that is 90.% of the...Ch. 7 - Calculate the velocities of electrons with de...Ch. 7 - Calculate the wavelength of light emiued when each...Ch. 7 - Calculate the wavelength of light emitted when...Ch. 7 - Using vertical lines, indicate the transitions...Ch. 7 - Using vertical lines, indicate the transitions...Ch. 7 - Calculate the longest and shortest wavelengths of...Ch. 7 - Assume that a hydrogen atoms electron has been...Ch. 7 - Does a photon of visible light ( 400 to 700 nm)...Ch. 7 - An electron is excited from the n = 1 ground state...Ch. 7 - Calculate the maximum wavelength of light capable...Ch. 7 - Consider an electron for a hydrogen atom in an...Ch. 7 - An excited hydrogen atom with an electron in the n...Ch. 7 - An excited hydrogen atom emits light with a...Ch. 7 - Using the Heisenberg uncertainty principle,...Ch. 7 - The Heisenberg uncertainty principle can be...Ch. 7 - What are the possible values for the quantum...Ch. 7 - Identify each of the following orbitals and...Ch. 7 - Which of the following sets of quantum numbers are...Ch. 7 - Which of the following sets of quantum numbers are...Ch. 7 - What is the physical significance of the value of...Ch. 7 - In defining the sizes of orbitals, why must we use...Ch. 7 - Total radial probability distributions for the...Ch. 7 - Tbe relative orbital levels for the hydrogen atom...Ch. 7 - How many orbitals in an atom can have the...Ch. 7 - How many electrons in an atom can have the...Ch. 7 - Give the maximum number of electrons in an atom...Ch. 7 - Give the maximum number of electrons in an atom...Ch. 7 - Draw atomic orbital diagrams representing the...Ch. 7 - For elements l36, there are two exceptions to the...Ch. 7 - The elements Si, Ga, As, Ge, Al, Cd, S, and Se are...Ch. 7 - The elements Cu, O, La, Y, Ba, Tl, and Bi are all...Ch. 7 - Write the expected electron configurations for...Ch. 7 - Write the expected electron configurations for...Ch. 7 - Write the expected ground-state electron...Ch. 7 - Using only the periodic table inside the front...Ch. 7 - Given the valence electron orbital level diagram...Ch. 7 - Identify the following elements. a. An excited...Ch. 7 - In the ground state of mercury, Hg, a. how many...Ch. 7 - In the ground state of element 115, Uup, a. how...Ch. 7 - Give a possible set of values of the four quantum...Ch. 7 - Give a possible set of values of the four quantum...Ch. 7 - Valence electrons are those electrons in the...Ch. 7 - How many valence electrons do each of the...Ch. 7 - A certain oxygen atom has the electron...Ch. 7 - Which of the following electron configurations...Ch. 7 - Which of elements 1-36 have two unpaired electrons...Ch. 7 - Which of elements 136 have one unpaired electron...Ch. 7 - One bit of evidence that the quantum mechanical...Ch. 7 - Identify how many unpaired electrons are present...Ch. 7 - Prob. 105ECh. 7 - Arrange the following groups of atoms in order of...Ch. 7 - Prob. 107ECh. 7 - Arrange the atoms in Exercise 108 in order of...Ch. 7 - In each of the following sets, which atom or ion...Ch. 7 - In each of the following sets, which atom or ion...Ch. 7 - Element 106 has been named seaborgium, Sg, in...Ch. 7 - The first ionization energies of As and Se are...Ch. 7 - Rank the elements Be, B, C, N, and O in order of...Ch. 7 - Consider the following ionization energies for...Ch. 7 - The following graph plots the first, second, and...Ch. 7 - For each of the following pairs of elements (C and...Ch. 7 - For each of the following pairs of elements (Mg...Ch. 7 - The electron affinities of the elements from...Ch. 7 - In the second row of the periodic table, Be, N,...Ch. 7 - Prob. 121ECh. 7 - Order the atoms in each of the following sets from...Ch. 7 - The electron affinity for sulfur is more negative...Ch. 7 - Which has the more negative electron affinity, the...Ch. 7 - Write equations corresponding to the following: a....Ch. 7 - Using data from the text, determine the following...Ch. 7 - Prob. 127ECh. 7 - Cesium was discovered in natural mineral waters in...Ch. 7 - 'The bright yellow light emitted by a sodium vapor...Ch. 7 - Does the information on alkali metals in Table 2-8...Ch. 7 - Predict the atomic number of the next alkali metal...Ch. 7 - Complete and balance the equations for the...Ch. 7 - Prob. 134ECh. 7 - "Lithium" is often prescribed as a...Ch. 7 - A carbon-oxygen double bond in a certain organic...Ch. 7 - Photogray lenses incorporate small amounts of...Ch. 7 - Mars is roughly 60 million km from the earth. How...Ch. 7 - Consider the following approximate visible light...Ch. 7 - One of the visible lines in the hydrogen emission...Ch. 7 - Using Fig. 2-30, list the elements (ignore the...Ch. 7 - Are the following statements true for the hydrogen...Ch. 7 - Although no currently known elements contain...Ch. 7 - Which of the following orbital designations are...Ch. 7 - The four most abundant elements by mass in the...Ch. 7 - Consider the eight most abundant elements in the...Ch. 7 - An ion having a 4+ charge and a mass of 49.9 u has...Ch. 7 - The successive ionization energies for an unknown...Ch. 7 - In the ground state of cadmium, Cd, a. how many...Ch. 7 - Prob. 152CWPCh. 7 - It takes 476 kJ to remove 1 mole of electrons from...Ch. 7 - Calculate, to four significant figures, the...Ch. 7 - Assume that a hydrogen atoms electron bas been...Ch. 7 - Determine the maximum number of electrons that can...Ch. 7 - Consider the ground state of arsenic, As. How many...Ch. 7 - Which of the following statements is(are) true? a....Ch. 7 - Identify the following three elements. a. The...Ch. 7 - For each of the following pairs of elements,...Ch. 7 - Which of the following statements is(are) true? a....Ch. 7 - Three elements have the electron configurations...Ch. 7 - The figure below represents part of the emission...Ch. 7 - One of the emission spectral lines for Be3+ has a...Ch. 7 - The figure below represents part of the emission...Ch. 7 - When lhe excited electron in a hydrogen atom falls...Ch. 7 - Prob. 167CPCh. 7 - For hydrogen atoms, the wave function for the...Ch. 7 - The wave function for the 2pz, orbital in the...Ch. 7 - Answer the following questions, assuming that ms,...Ch. 7 - Assume that we are in another universe with...Ch. 7 - Without looking at data in the text, sketch a...Ch. 7 - The following numbers are the ratios of second...Ch. 7 - We expect the atomic radius to increase going down...Ch. 7 - The ionization energy for a 1s electron in a...Ch. 7 - An atom of a particular element is traveling at...Ch. 7 - As the weapons officer aboard the Srarship...Ch. 7 - Answer the following questions based on the given...
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- describe trace analysis and explain its role in materials testing.arrow_forwardDetermine whether each statement that follows is true or false: a Electron energies are quantized in excited states but not in the ground state. b Line spectra of the elements are experimental evidence of the quantization of electron energies. c Energy is released as an electron passes from ground state to an excited state. d The energy of an electron may be between two quantized energy levels. e The Bohr model explanation of line spectra is still thought to be correct. f The quantum mechanical model of the atom describes orbitals in which electrons travel around the nucleus. g Orbitals are regions in which there is a high probability of finding an electron. h All energy sublevels have the same number of orbitals. i The 3p orbitals of an atom are larger than its 2p orbitals but smaller than its 4p orbitals. j At a given sublevel, the maximum number of d electrons is 5. k The halogens are found in Group 7A/17 of the periodic table. l The dot structure of the alkaline earths is X, where X is the symbol of element in the family. m Stable ions formed by alkaline earth metals are isoelectronic with noble gas atoms. n Atomic numbers 23 and 45 both belong to transition elements. o Atomic number 52, 35, and 18 are arranged in order of increasing atomic size. p Atomic number 7, 16, and 35 are all nonmetals.arrow_forwardWhat major assumption (that was analogous to what had already been demonstrated for electromagnetic radiation) did de Broglie and Schrodinger make about the motion of tiny panicles?arrow_forward
- Planck originated the idea that energies can be quantized. What does the term quantized mean? What was Planck trying to explain when he was led to the concept of quantization of energy? Give the formula he arrived at and explain each of the terms in the formula.arrow_forwardExplain the difference between (a) the Bohr model of the atom and the quantum mechanical model. (b) wavelength and frequency. (c) the geometries of the three different p orbitals.arrow_forwardWhich statement is true of the quantum mechanical model, but not of the Bohr model? a. Electrons orbit the nucleus in simple circular orbits, just like planets orbit the Sun. b. The exact path that an electron follows within an atom cannot be specified. c. The electron is attracted to the nucleus of the atom.arrow_forward
- The spectra of hydrogen and of calcium are shown in Figure 6.13. What causes the lines in these spectra? Why are the colors of the lines different? Suggest a reason for the observation that the spectrum of calcium is more complicated than the spectrum of hydrogen.arrow_forwardThe “Chemistry in Focus" segment The Chemistry of Bohrium discusses element 107. bohrium (Bh). What is the expected electron configuration of Bh?arrow_forwardCharacterize the Bohr model of the atom. In the Bohr model, what do we mean when we say something is quantized? How does the Bohr model of the hydrogen atom explain the hydrogen emission spectrum? Why is the Bohr model fundamentally incorrect?arrow_forward
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