General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 7, Problem 115IAE
Interpretation Introduction
Interpretation:
The amount of work done when the steel cylinder is suddenly removed from the piston in the given process needs to be determined.
Concept introduction:
The work done can be calculated as follows:
Here, P is pressure and
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionChapter 7 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 7 - Calculate the quantity of heat, in kilojoules, (a)...Ch. 7 - Calculate the final temperature that results when...Ch. 7 - Refer to Example 7-2. The experiment is repeated...Ch. 7 - A 75.0 g piece of Ag metal is heated to 80.0C and...Ch. 7 - A 465 g chunk of iron is removed from an oven and...Ch. 7 - A piece of stainless steel (C2=0.50Jg-1C-1) is...Ch. 7 - A 1.00 kg sample of magnesium at 40.0C is added to...Ch. 7 - Brass has a density of 8.40 g/cm2 and a specific...Ch. 7 - A 74.8 g sample of copper at 143.2C is added to an...Ch. 7 - A 69.0 g sample of gold at 127.1C is added to an...
Ch. 7 - In the form of heat, 6052 J of energy is...Ch. 7 - What is the final temperature (in C) of 1.24 g of...Ch. 7 - How much heat, in kilojoules, is associated with...Ch. 7 - The standard enthalpy of reaction for the...Ch. 7 - How much heat, in kilojoules, is evolved the...Ch. 7 - Upon complete combustion the indicated substances...Ch. 7 - The combustion of methane gas, the principal...Ch. 7 - Refer to the Integrative Example. What volume of...Ch. 7 - The combustion of hydrogen-oxygen mixtures is used...Ch. 7 - Thermite mixtures are used for certain types of...Ch. 7 - A 0.205 g pellet of potassium hydroxide, KOH, is...Ch. 7 - The heat of solution of Kl(s) in water is...Ch. 7 - You are planning lecture demonstration to...Ch. 7 - Care must be taken in preparing solutions of...Ch. 7 - Refer to Example 7-4. The product of the...Ch. 7 - Prob. 26ECh. 7 - Prob. 27ECh. 7 - Prob. 28ECh. 7 - What mass of ice can be meted the same quantity of...Ch. 7 - What will be the final temperature of the water in...Ch. 7 - A 125 g stainless steel ball bearings...Ch. 7 - Prob. 32ECh. 7 - The enthalpy of sublimation (solid gas) for dry...Ch. 7 - The enthalpy of vaporization forN2 (I)is 5.56...Ch. 7 - A sample gives off 5228 cal when burned in a bomb...Ch. 7 - The following substances undergo complete...Ch. 7 - A bomb calorimetry experiment is performed...Ch. 7 - A coffee-cup calorimeter contains 100.0 mL of...Ch. 7 - A 0.75 g sample of KCI is added to 350 g H2O in a...Ch. 7 - The heat of solution of potassium acetate in water...Ch. 7 - Prob. 41ECh. 7 - Salicylic acid, C7H5O2 , has been suggested as a...Ch. 7 - Refer to Example 7-3. Based on the heat of...Ch. 7 - A 1.397 g sample of thymol, C10H14O(s) (a...Ch. 7 - A g of NaCI is added to a Styrofoam cup of water,...Ch. 7 - can determine purity of solid materials by using...Ch. 7 - Calculate the quantity of work associated with a...Ch. 7 - Calculate the quantity of work, in joules,...Ch. 7 - A 1.00 g sample of Ne(g) at 1 atm pressure and 27C...Ch. 7 - Compressed air in aerosol cans is used to free...Ch. 7 - In each of the following processes, is any work...Ch. 7 - In each of the following processes, any work done...Ch. 7 - If 325 J of work is done by a system at a pressure...Ch. 7 - A movable piston a cylinder holding 5.0 L N2(g) is...Ch. 7 - What is the change in internal energy of a system...Ch. 7 - Whet the change in internal energy of e system if...Ch. 7 - The internal energy of a fixed quantity of an...Ch. 7 - Prob. 58ECh. 7 - Prob. 59ECh. 7 - Prob. 60ECh. 7 - There are other forms of work besides PV work. For...Ch. 7 - Another form of work is extension, defined as the...Ch. 7 - Only one of the following quantities is equal to...Ch. 7 - Determine whether H is equal to, greater than, or...Ch. 7 - The heat of combustion of propan-2-ol at 298.15 K,...Ch. 7 - Prob. 66ECh. 7 - The standard enthalpy of formation of NH2(g) is...Ch. 7 - Use Hess's law to determine rH for the reaction...Ch. 7 - Use Hess's law to determine rH for the reaction 2...Ch. 7 - Given the following information:...Ch. 7 - For the reaction C2H4(g)+CIz(g)C2H4CI2(I) ,...Ch. 7 - Determine rH for this reaction from the data...Ch. 7 - Substitute natural gas (SNG) is a gaseous mature...Ch. 7 - CCI4 , an important commercial solvent, is...Ch. 7 - Use Hess's law and the following data...Ch. 7 - The standard heats of combustion (rH) of butane-l...Ch. 7 - One glucose molecule, C6H12O6(s) is converted to...Ch. 7 - The standard of fermentation of glucose to ethanol...Ch. 7 - Use standard enthalpies of formation from Table...Ch. 7 - Use standard enthalpies of formation from Tables...Ch. 7 - Use the information given here. date from Appendix...Ch. 7 - Prob. 82ECh. 7 - Prob. 83ECh. 7 - Use data from Appendix D to calculate rH for the...Ch. 7 - Prob. 85ECh. 7 - Use data from Table 7.2, together with the...Ch. 7 - Use data from Table 7.2 and rH for re following...Ch. 7 - Use data from Table 7.2 and rH for the following...Ch. 7 - Prob. 89ECh. 7 - Prob. 90ECh. 7 - The decomposition of limestone, CaCO2(s) into...Ch. 7 - Use data from Table 7.2 to calculate the volume of...Ch. 7 - Ants release formic acid (HCOOH) when they bite....Ch. 7 - Prob. 94ECh. 7 - A British thermal unit (Btu) is defined as the...Ch. 7 - What volume of 18.5C water must be added, together...Ch. 7 - A 7.26 kg shot (as used the sporting event, the...Ch. 7 - An alternative approach to bomb calorimetry is to...Ch. 7 - Prob. 99IAECh. 7 - Prob. 100IAECh. 7 - Determine the missing values of rH in the diagram...Ch. 7 - A particular natural gas consists, in mole...Ch. 7 - Prob. 103IAECh. 7 - Prob. 104IAECh. 7 - A calorimeter that measures an exothermic heat of...Ch. 7 - For the reaction C2H4(g)+3O2(g)2CO2(g)+2H2O(I)...Ch. 7 - Some of the butane, C4H10(g) , in a 200.0 L...Ch. 7 - The metabolism of glucose, C5H12O5 yields CO2(g)...Ch. 7 - Prob. 109IAECh. 7 - Upon complete combustion, a 1.00 L sample (at STP)...Ch. 7 - Prob. 111IAECh. 7 - Refer to the discussion of the gasification of...Ch. 7 - A 1.103 g sample of a gaseous...Ch. 7 - Several factors are involved in determining the...Ch. 7 - Prob. 115IAECh. 7 - Prob. 116IAECh. 7 - Prob. 117IAECh. 7 - In the Are You Wondering 7-1 box, the temperature...Ch. 7 - Prob. 119IAECh. 7 - Prob. 120IAECh. 7 - Cetane, C15H34, is a typical petrodiesel with a...Ch. 7 - Carbon dioxide emissions have been implicated as a...Ch. 7 - Prob. 123FPCh. 7 - Prob. 124FPCh. 7 - We can use the heat liberated by a neutralization...Ch. 7 - In a student experiment to confirm Hess's law, the...Ch. 7 - Prob. 127FPCh. 7 - Refer to Example 7-5 dealing with the work done by...Ch. 7 - Look up the specific heat capacity of several...Ch. 7 - In your own words, define or explain the following...Ch. 7 - Prob. 131SAECh. 7 - Explain the important distinctions between each...Ch. 7 - The temperature increase of 225 mL of water at 25C...Ch. 7 - A plausible final temperature when 75.0 ml of...Ch. 7 - U= 100 J for a system that gives off 100 J of heat...Ch. 7 - Prob. 136SAECh. 7 - The standard molar enthalpy of formation of CO2(g)...Ch. 7 - Write the formation reaction for each of the...Ch. 7 - Compute rH for the following reactions. The value...Ch. 7 - When dissolved in water, 1.00 mol LiCI produces...Ch. 7 - Prob. 141SAECh. 7 - Prob. 142SAECh. 7 - Prob. 143SAECh. 7 - A 1.22 kg piece of iron at 126.5C is dropped into...Ch. 7 - Prob. 145SAECh. 7 - The standard molar heats of combustion of...Ch. 7 - Prob. 147SAECh. 7 - Prob. 148SAECh. 7 - Prob. 149SAECh. 7 - Prob. 150SAECh. 7 - Prob. 151SAECh. 7 - Prob. 152SAECh. 7 - Prob. 153SAECh. 7 - Prob. 154SAE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider a mixture of air and gasoline vapor in a cylinder with a piston. The original volume is 40. cm3. If the combustion of this mixture releases 950. J of energy, to what volume will the gases expand against a constant pressure of 650. torr if all the energy of combustion is converted into work to push back the piston?arrow_forwardAs a system increases in volume, it absorbs 52.5 J of energy in the form of heat from the surroundings. The piston is working against a pressure of 0.500 atm. The final volume of the system is 58.0 L. What was the initial volume of the system if the internal energy of the system decreased by 102.5 J?arrow_forwardAn industrial process for manufacturing sulfuric acid, H2SO4, uses hydrogen sulfide, H2S, from the purification of natural gas. In the first step of this process, the hydrogen sulfide is burned to obtain sulfur dioxide, SO2. 2H2S(g)+3O2(g)2H2O(l)+2SO2(g);H=1124kJ The density of sulfur dioxide at 25C and 1.00 atm is 2.62 g/L, and the molar heat capacity is 30.2 J/(mol C). (a) How much heat would be evolved in producing 1.00 L of SO2 at 25C and 1.00 atm? (b) Suppose heat from this reaction is used to heat 1.00 L of the SO2 from 25C to 500C for its use in the next step of the process. What percentage of the heat evolved is required for this?arrow_forward
- A volume of 1.50 L of argon gas is confined in a cylinder with a movable piston under a constant pressure of 1.22 105 Pa. When 1.25 kJ of energy in the form of heat is transferred from the surroundings to the gas, the internal energy of the gas increases by 1.11 kJ. What is the final volume of argon gas in the cylinder?arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardCalculate H when a 38-g sample of glucose, C6H12O6(s), burns in excess O2(g) to form CO2(g) and H2O() in a reaction at constant pressure and 298.15 K.arrow_forward
- On complete combustion at constant pressure, a 1.00-L sample of a gaseous mixture at 0C and 1.00 atm (STP) evolves 75.65 kJ of heat. If the gas is a mixture of ethane (C2H6) and propane (C3H8), what is the mole fraction of ethane in the mixture?arrow_forwardWhat is the change in internal energy when a gas contracts from 377mL to 119mLundera pressure of 1550 torr, whileat the same time being cooled by removing 124.0J ofheat energy?arrow_forwardThe internal energy of a gas decreases by 1.65 kJ when it transfers 1.87 kJ of energy in the form of heat to the surroundings. (a) Calculate the work done by the gas on the surroundings. (b) Does the volume of gas increase or decrease?arrow_forward
- Suppose that you are studying kinetic energy of helium molecules: A helium weather balloon rises to an altitude of 40,000 ft; the temperature of the gas drops to 70 F. (a) Make an appropriate choice of system and surroundings and describe it unambiguously. (b) Explain why you chose the system and surroundings you did. (c) Identify transfers of energy and material into and out of the system that would be important for you to monitor in your study.arrow_forwardConsider the reaction between methane and oxygen producing carbon dioxide and water. Suppose that the reaction is carried out in a furnace used to heat a house. If q=890kJ and w=+5kJ, what is E? H at 25C?arrow_forwardCalculate G and G at 37 C for the following equation. N2O(g, 1 atm) + H2(g, 0.4 atm) N2(g, 1 atm) + H2O()arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY