Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.23P
Interpretation Introduction

Interpretation:

The final volume and mass of liquid water should be deduced based on the given initial and final condition of steam

Concept Introduction:

  • For a two-phase liquid-vapor equilibrium mixture the specific volume (V), enthalpy (H) and entropy (S) are given as:

V = Vf + x(Vg-Vf) -----(1)H = Hf + x(Hg-Hf)-----(2)S = Sf + x(Sg-Sf)--------(3)where, Vg and Vf are the specific volumes in the vapor and liquid phases respectively Hg and Hf are the specific enthalpies in the vapor and liquid phases respectivelySg and Sf are the specific entropies in the vapor and liquid phases respectivelyx = steam quality 

Final mass of liquid water = 0.377 kg

Final volume of liquid water = 0.00378 m3

Given:

Volume of vessel V = 0.15 m3

Initial Temperature of saturated steam = 150C0

Final temperature = 30C0

Explanation:

Based on the steam tables at Temperature = 150C0 we have:

Specific volume of liquid, vf = 0.001091 m3/kg

Specific volume of vapor, vg = 0.39248 m3/kg

Again from the steam tables, at Temperature = 30C0 we have:

Specific volume of liquid, vf = 0.001004 m3/kg

Specific volume of vapor, vg = 32.879 m3/kg

Calculation:

Step 1:

Calculate the final mass of liquid water

In the initial state, the total mass is equivalent to the mass of the vapor

The total volume V = 0.15 m3

Specific volume of vapor, vg = 0.39248 m3/kg

  Total Mass, mtotal = Vvg=0.15 m30.39248 m3/kg=0.382 kgNow,Vtotal = mtotal×vf+ mvap×vgwhere, mvap = mass of vapor phase in the final state0.15 = 0.382×0.001004+ mvap×32.879mvap = 0.00455 kgThus, mliq = mtotal - mvap = 0.382 - 0.00455 = 0.377 kg

Step 2:

Calculate final volume of liquid water

Volume of liquid water is given as:-Vliq = mliq×vf      = 0.377×0.001004 = 0.000378 m3

Thus,

The final mass of liquid water = 0.377 kg

The final volume of liquid water = 0.00378 m3

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Chapter 6 Solutions

Introduction to Chemical Engineering Thermodynamics

Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Prob. 6.14PCh. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Prob. 6.19PCh. 6 - Prob. 6.20PCh. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.23PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - What is the mole fraction of water vapor in air...Ch. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Prob. 6.35PCh. 6 - Prob. 6.36PCh. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - Prob. 6.39PCh. 6 - Prob. 6.40PCh. 6 - Prob. 6.41PCh. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Prob. 6.44PCh. 6 - Prob. 6.45PCh. 6 - Prob. 6.46PCh. 6 - Prob. 6.47PCh. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - Prob. 6.53PCh. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Prob. 6.59PCh. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.71PCh. 6 - Prob. 6.72PCh. 6 - Prob. 6.73PCh. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - Prob. 6.78PCh. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - The temperature dependence of the second virial...Ch. 6 - Prob. 6.83PCh. 6 - Prob. 6.84PCh. 6 - Prob. 6.85PCh. 6 - Prob. 6.86PCh. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - Prob. 6.90PCh. 6 - Prob. 6.91PCh. 6 - Prob. 6.92PCh. 6 - Prob. 6.93PCh. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99PCh. 6 - Prob. 6.100P
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