Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 5.5, Problem 5.6PSP

(a)

Interpretation Introduction

Interpretation:

From the given n and l value the subshell has to be predicted.

Concept Introduction:

The relationships among n, l, and ml for the first four shells are given by

nlSubshellPossible mlvaluesNumber of atomic orbitals in subshell 2l+1Total number of atomic orbitals in shell n2
101s011
202s01 
212p1,0,134
303s01 
313p1,0,13 
323d2,1,0,1,259
404s01 
414p1,0,13 
424d2,1,0,1,25 
434f3,2,1,0,1,2,3716

(b)

Interpretation Introduction

Interpretation:

The number of atomic orbitals is in 6dxysubshell have to be identified.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

The possible ml values for given 6dxysubshell have to be identified.

Concept Introduction:

Refer to part (a)

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Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.  (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ­ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
(a) How does the Bohr model differ from the quantum mechanical model of the atom? Describe at least 2 differences.(b) Define each of the 4 quantum numbers (n, l, ml, ms) and what they physically represent about the orbital and/or electron.(d) How many quantum numbers are needed to completely define a specific orbital? Provide the quantum numbers for the 2s orbital.(d) How many quantum numbers are needed to completely define a specific electron? Provide the quantum numbers for the second electron to fill into a 2s orbital.

Chapter 5 Solutions

Chemistry: The Molecular Science

Ch. 5.4 - Calculate the de Broglie wavelength of a neutron...Ch. 5.5 - Prob. 5.7ECh. 5.5 - Prob. 5.8ECh. 5.5 - Prob. 5.6PSPCh. 5.5 - Prob. 5.9ECh. 5.5 - Prob. 5.10CECh. 5.5 - Prob. 5.11ECh. 5.5 - Prob. 5.12ECh. 5.5 - Prob. 5.13CECh. 5.7 - Use atomic orbital box diagrams to determine which...Ch. 5.7 - Prob. 5.7PSPCh. 5.7 - Prob. 5.15ECh. 5.7 - Prob. 5.8PSPCh. 5.8 - (a) What Period 3 anion with a 2 charge has the...Ch. 5.8 - Prob. 5.10PSPCh. 5.8 - Fluoride ion, F, has no unpaired electrons....Ch. 5.9 - Prob. 5.11PSPCh. 5.10 - Which of these isoelectronic ions, Ba2+, Cs+, or...Ch. 5.11 - Prob. 5.13PSPCh. 5.13 - Consider these ionic compounds: KCl, CaS, CaO,...Ch. 5 - Prob. 1QRTCh. 5 - Prob. 2QRTCh. 5 - Prob. 3QRTCh. 5 - Prob. 4QRTCh. 5 - Prob. 5QRTCh. 5 - Prob. 6QRTCh. 5 - Prob. 7QRTCh. 5 - Prob. 8QRTCh. 5 - Write the electron configurations for the valence...Ch. 5 - Prob. 10QRTCh. 5 - Prob. 11QRTCh. 5 - Prob. 12QRTCh. 5 - Prob. 13QRTCh. 5 - The colors of the visible spectrum and the...Ch. 5 - Prob. 15QRTCh. 5 - Prob. 16QRTCh. 5 - Prob. 17QRTCh. 5 - Prob. 18QRTCh. 5 - Prob. 19QRTCh. 5 - Light of very long wavelength strikes a...Ch. 5 - Prob. 21QRTCh. 5 - Prob. 22QRTCh. 5 - Prob. 23QRTCh. 5 - A photoemissive material has a threshold energy,...Ch. 5 - Prob. 25QRTCh. 5 - Prob. 26QRTCh. 5 - Prob. 27QRTCh. 5 - Prob. 28QRTCh. 5 - Prob. 29QRTCh. 5 - Prob. 30QRTCh. 5 - Prob. 31QRTCh. 5 - Calculate the energy and wavelength of the photon...Ch. 5 - Calculate the energy and the wavelength of the...Ch. 5 - Spectroscopists have observed He+ in outer space....Ch. 5 - Prob. 35QRTCh. 5 - Prob. 36QRTCh. 5 - Prob. 37QRTCh. 5 - Prob. 38QRTCh. 5 - Prob. 39QRTCh. 5 - Prob. 40QRTCh. 5 - Prob. 41QRTCh. 5 - Give possible values for all four quantum numbers...Ch. 5 - Prob. 43QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 45QRTCh. 5 - Prob. 46QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 48QRTCh. 5 - Prob. 49QRTCh. 5 - Prob. 50QRTCh. 5 - Prob. 51QRTCh. 5 - Prob. 52QRTCh. 5 - Prob. 53QRTCh. 5 - Titanium metal and Cr2+ have the same number of...Ch. 5 - Consider a 2+ ion that has six 3d electrons; which...Ch. 5 - Prob. 56QRTCh. 5 - Prob. 57QRTCh. 5 - Prob. 58QRTCh. 5 - Prob. 59QRTCh. 5 - Prob. 60QRTCh. 5 - Prob. 61QRTCh. 5 - Prob. 62QRTCh. 5 - Prob. 63QRTCh. 5 - Prob. 64QRTCh. 5 - Prob. 65QRTCh. 5 - Prob. 66QRTCh. 5 - Prob. 67QRTCh. 5 - Prob. 68QRTCh. 5 - Prob. 69QRTCh. 5 - Prob. 70QRTCh. 5 - Prob. 71QRTCh. 5 - Prob. 72QRTCh. 5 - Prob. 73QRTCh. 5 - Prob. 74QRTCh. 5 - Prob. 75QRTCh. 5 - Prob. 76QRTCh. 5 - Prob. 77QRTCh. 5 - Prob. 78QRTCh. 5 - Use electron configurations to explain why (a)...Ch. 5 - Prob. 80QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 82QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 84QRTCh. 5 - Prob. 85QRTCh. 5 - Prob. 86QRTCh. 5 - Prob. 87QRTCh. 5 - Prob. 88QRTCh. 5 - Prob. 89QRTCh. 5 - Compare the elements B, Al, C, Si. (a) Which has...Ch. 5 - Prob. 91QRTCh. 5 - Prob. 92QRTCh. 5 - Prob. 93QRTCh. 5 - Prob. 94QRTCh. 5 - Determine the lattice energy for LiCl(s) given...Ch. 5 - Prob. 96QRTCh. 5 - Prob. 97QRTCh. 5 - Prob. 98QRTCh. 5 - Prob. 99QRTCh. 5 - Prob. 100QRTCh. 5 - Prob. 101QRTCh. 5 - Prob. 102QRTCh. 5 - Prob. 103QRTCh. 5 - Prob. 104QRTCh. 5 - Prob. 105QRTCh. 5 - Prob. 106QRTCh. 5 - Prob. 107QRTCh. 5 - Prob. 108QRTCh. 5 - Prob. 109QRTCh. 5 - Prob. 113QRTCh. 5 - Prob. 114QRTCh. 5 - Prob. 115QRTCh. 5 - Prob. 116QRTCh. 5 - Prob. 117QRTCh. 5 - Prob. 119QRTCh. 5 - Prob. 120QRTCh. 5 - Prob. 121QRTCh. 5 - Prob. 123QRTCh. 5 - Prob. 124QRTCh. 5 - Prob. 125QRTCh. 5 - Prob. 126QRTCh. 5 - Prob. 127QRTCh. 5 - Prob. 128QRTCh. 5 - Prob. 129QRTCh. 5 - Calculate the effective nuclear charge, Z, on...Ch. 5 - Prob. 131QRTCh. 5 - Prob. 133QRTCh. 5 - Prob. 134QRTCh. 5 - Prob. 135QRTCh. 5 - According to a relationship developed by Niels...Ch. 5 - Prob. 137QRTCh. 5 - Prob. 138QRTCh. 5 - Prob. 139QRTCh. 5 - Prob. 140QRTCh. 5 - Prob. 141QRTCh. 5 - Prob. 142QRTCh. 5 - Prob. 143QRTCh. 5 - Prob. 144QRTCh. 5 - Prob. 5.ACPCh. 5 - Prob. 5.CCP
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