Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781337468039
Author: Skoog
Publisher: Cengage
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Chapter 5, Problem 5.7QAP
Interpretation Introduction

(a)

Interpretation:

The signal-to-noise ratio is to be stated.

Concept introduction:

The signal and noise are two components of instrument measurement. One component is the signal, which carries information that is of interest to scientists and another component is noise, which is the unwanted fluctuations of signals.

Expert Solution
Check Mark

Answer to Problem 5.7QAP

The signal-to-noise ratio is 338.74.

Explanation of Solution

The magnitude of signal is denoted by S and the magnitude of noise is denoted by N.

The expression for the mean of the measurements is:

x¯=i=1NxlN ...... (I)

Here, the total number of measurement is N and the measurement is xi where i=1,2,3,4,...,9.

Substitute 1.003 for x1, 1.000 for x2. 1.001 for x3, 1.004 for x4, 1.005 for x5, 1.006 for x6, 1.001 for x7, 0.999 for x8, 1.007 for x9, and 9 for N.

x¯=[1.002+1.000+0.997+1.004+1.003+1.001+1.005+0.999+1.007]9=9.0189=1.002

The expression for the standard deviation is:

s=i=1N(xix¯)2N1 ...... (II)

Substitute 1.003 for x1, 1.000 for x2. 1.001 for x3, 1.004 for x4, 1.005 for x5, 1.006 for x6, 1.001 for x7, 0.999 for x8, 1.007 for x9, 1.002 for x¯, and 9 for N.

s=[(1.0031.002)2+(1.0001.002)2+(1.0011.002)2+(1.0041.002)2+(1.0051.002)2+(1.0011.002)2+(1.0061.002)2+(0.9991.002)2+(1.0071.002)2]91=[(106)+(4×106)+(106)+(4×106)+(9×106)+(106)+(16×106)+(9×106)+(25×106)]91=70×1068=2.958×103

The expression for the signal to noise ratio is:

SN=x¯s ...... (III)

Substitute 2.5 for s and 1.002 for x¯ in Equation (III).

SN=1.0022.958×103=338.74

Interpretation Introduction

(b)

Interpretation:

The number of measurements required to obtain a S/N of 500 is to be stated.

Concept introduction:

The signal and noise are two components of instrument measurement. One component is the signal, which carries information that is of interest to scientists and another component is noise, which is the unwanted fluctuations of signals. For n number of repetitions, the signal to noise ratio is proportional to square root of number of repetitions.

Expert Solution
Check Mark

Answer to Problem 5.7QAP

The number of measurement required to obtain a S/N of 500 is 18.

Explanation of Solution

The expression for n number of repetitions is:

(SN)n=n(SN)i ...... (IV)

Here, the signal to noise at initial point is (SN)i.

Substitute 338.74 for (SN)n and 9 for N in Equation (IV).

338.74=9(SN)i(SN)i=338.743(SN)i=112.913

Substitute 112.913 for (SN)i and 500 for (SN)n in Equation (IV).

500=n(112.913)n=(500112.913)2n=19.6n20

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