Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 5, Problem 5.79P
Interpretation Introduction

Interpretation:

Standard reaction enthalpy and entropy for the given cell should be determined within the given temperature range where EΘcell at 293 K = 1.2335 V and EΘcell at 303 K = 1.2251 V.

Concept introduction:

Standard Gibbs energy is calculated as below,

  ΔrGΘνFEΘcellF = Faraday's constantν = No. of electrons transferredEΘcell = Standard cell potential at temperature, T

Standard entropy of reaction is determined as follows,

ΔrSΘ = νF(EΘcellEΘcell')TT'F = Faraday's constantν = No. of electrons transferredEΘcell = Standard cell potential at temperature, TEΘcell' = Standard cell potential at temperature, T'

Standard reaction enthalpy can be calculated using the given formula,

ΔrHΘ = ΔrGΘ + TΔrSΘΔrHΘ = Standard reaction enthalpyΔrSΘ = Standard entropy of reactionΔrGΘ = Standard Gibbs energy

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Chapter 5 Solutions

Elements Of Physical Chemistry

Ch. 5 - Prob. 5D.1STCh. 5 - Prob. 5D.2STCh. 5 - Prob. 5D.3STCh. 5 - Prob. 5D.4STCh. 5 - Prob. 5D.5STCh. 5 - Prob. 5E.1STCh. 5 - Prob. 5E.2STCh. 5 - Prob. 5F.1STCh. 5 - Prob. 5F.2STCh. 5 - Prob. 5F.3STCh. 5 - Prob. 5F.4STCh. 5 - Prob. 5F.5STCh. 5 - Prob. 5G.1STCh. 5 - Prob. 5G.2STCh. 5 - Prob. 5G.3STCh. 5 - Prob. 5H.1STCh. 5 - Prob. 5H.2STCh. 5 - Prob. 5H.3STCh. 5 - Prob. 5I.1STCh. 5 - Prob. 5I.2STCh. 5 - Prob. 5I.3STCh. 5 - Prob. 5I.4STCh. 5 - Prob. 5I.5STCh. 5 - Prob. 5I.6STCh. 5 - Prob. 5J.1STCh. 5 - Prob. 5J.2STCh. 5 - Prob. 5J.3STCh. 5 - Prob. 5J.4STCh. 5 - Prob. 5J.5STCh. 5 - Prob. 5A.1ECh. 5 - Prob. 5A.2ECh. 5 - Prob. 5A.3ECh. 5 - Prob. 5A.4ECh. 5 - Prob. 5A.5ECh. 5 - Prob. 5A.6ECh. 5 - Prob. 5A.7ECh. 5 - Prob. 5A.8ECh. 5 - Prob. 5A.9ECh. 5 - Prob. 5A.10ECh. 5 - Prob. 5A.11ECh. 5 - Prob. 5A.12ECh. 5 - Prob. 5A.13ECh. 5 - Prob. 5B.1ECh. 5 - Prob. 5B.2ECh. 5 - Prob. 5B.3ECh. 5 - Prob. 5B.4ECh. 5 - Prob. 5B.5ECh. 5 - Prob. 5C.1ECh. 5 - Prob. 5C.2ECh. 5 - Prob. 5C.3ECh. 5 - Prob. 5C.4ECh. 5 - Prob. 5D.1ECh. 5 - Prob. 5D.2ECh. 5 - Prob. 5D.3ECh. 5 - Prob. 5D.4ECh. 5 - Prob. 5E.1ECh. 5 - Prob. 5E.2ECh. 5 - Prob. 5F.4ECh. 5 - Prob. 5G.1ECh. 5 - Prob. 5G.2ECh. 5 - Prob. 5G.3ECh. 5 - Prob. 5H.1ECh. 5 - Prob. 5H.2ECh. 5 - Prob. 5H.3ECh. 5 - Prob. 5H.4ECh. 5 - Prob. 5I.1ECh. 5 - Prob. 5I.2ECh. 5 - Prob. 5I.3ECh. 5 - Prob. 5I.4ECh. 5 - Prob. 5J.1ECh. 5 - Prob. 5J.2ECh. 5 - Prob. 5J.3ECh. 5 - Prob. 5J.4ECh. 5 - Prob. 5.1DQCh. 5 - Prob. 5.2DQCh. 5 - Prob. 5.3DQCh. 5 - Prob. 5.4DQCh. 5 - Prob. 5.5DQCh. 5 - Prob. 5.6DQCh. 5 - Prob. 5.7DQCh. 5 - Prob. 5.8DQCh. 5 - Prob. 5.9DQCh. 5 - Prob. 5.10DQCh. 5 - Prob. 5.11DQCh. 5 - Prob. 5.12DQCh. 5 - Prob. 5.13DQCh. 5 - Prob. 5.14DQCh. 5 - Prob. 5.15DQCh. 5 - Prob. 5.16DQCh. 5 - Prob. 5.17DQCh. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - Prob. 5.9PCh. 5 - Prob. 5.10PCh. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - Prob. 5.34PCh. 5 - Prob. 5.35PCh. 5 - Prob. 5.36PCh. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.58PCh. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.66PCh. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Prob. 5.79PCh. 5 - Prob. 5.1PRCh. 5 - Prob. 5.2PRCh. 5 - Prob. 5.3PRCh. 5 - Prob. 5.4PR
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