(a)
Interpretation:
The effective nuclear charge on two p electrons in
Concept Introduction:
Calculation of effective nuclear charge:
The effective
(a)
Explanation of Solution
These
(b)
Interpretation:
The calculated effective nuclear charge consistent with relative size of
Concept Introduction:
Refer to part a.
(b)
Explanation of Solution
These
The calculated effective nuclear charges are larger for more positive ions in an isoelectronic series. A greater effective nuclear charge has the capacity to pull the electrons closer to the nucleus, making the ions smaller. This does explain the reduction in relative sizes for more positive ions.
(c)
Interpretation:
The effective nuclear charge on four d electrons in a tin atom has to be calculated.
Concept Introduction:
Refer to part a.
(c)
Explanation of Solution
The electron configuration of tin is given by
There are four electrons in a group to the right of
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Chapter 5 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
- Palladium, with an electron configuration of [Kr] 4d10, is an exception to the aufbau principle. Write the electron configuration of the 2+ cation of palladium. Does the fact that palladium is an exception influence the electron configuration of Pd2+?arrow_forward5. The atoms and ions Ne, N³-, F, Mg2+, and Si4+ are part of an isoelectronic series. (a) Which of these will have the smallest effective nuclear charge acting on the outermost electron? (b) Which one possess the greatest effective nuclear charge? (c) Which ion will be the largest in size? Explain why.arrow_forwardb) For each pair indicate which Ion you would expect to have the largest Radius: (a) 02 and O; (b) N³ and Mg2+ (c) Al3* and Alarrow_forward
- la) For each of the following pairs indicate which element you would expect to have the larger First Ionization Energy and which one would have the larger radius: (a) Ca and Cl; (b) Sn and Tl; (c) Ba and Bi (d) Fr and Cs b) For each pair indicate which Ion you would expect to have the largest Radius: (a) 0²- and O; (b) N³ and Mg²+ (c) Al3* and Al ne Elearrow_forwardConsider these ground-state ionization energies of one-electron species:H=1.31X10³kJ/mol ,He⁺=5.24X10³kJ/mol Li²⁺=1.41X10⁴kJ/mol (a) Write a general expression for the ionization energy of anyone-electron species. (b) Use your expression to calculate theionization energy of B⁴⁺. (c) What is the minimum wavelengthrequired to remove the electron from the n=3 level of He⁺?(d) What is the minimum wavelength required to remove the electron from the n=2 level of Be³⁺?arrow_forwardParticles called muons exist in cosmic rays and can be created in particle accelerators. Muons are very similar to electrons, having the same charge and spin, but they have a mass 207 times greater. When muons arecaptured by an atom, they orbit just like an electron but with a smaller radius, since the mass in aB =0.529x 10-10 m is 207 me .(a) Calculate the radius of the n=1 orbit for a muon in a uranium ion( Z=92).(b) Compare this with the 7.5-fm radius of a uranium nucleus. Note that since the muon orbits inside the electron, it falls into a hydrogen-like orbit. Since your answer is less than the radius of the nucleus, you can seethat the photons emitted as the muon falls into its lowest orbit can give information about the nucleus.arrow_forward
- (1) What is the name of the element with a valence electron configuration of 2s22p3?fill in the blank 1(2) What is the name of the element with a valence electron configuration of 3s2?arrow_forward(a) Describe the trends of atomic size and ionization energy, respectively, in the Periodic Table: (1) from left to right across a period, and (ii) from top to bottom down a group. (b) Rank the following elements: Na, Mg, Al, and K, in increasing order of: (i) atomic size; (ii) ionization energy, and (iii) reactivity. (c) Rank the following elements: F, CI, Br and I, in increasing order of: (i) atomic size; (ii) electron affinity, (iii) electronegativity, and (iv) reactivity.arrow_forwardThe electron in the hydrogen atom (in its ground state) orbits the nucleus at a distance of 0.5292 Å. (a) Calculate the gravitational force and (b) the electrostatic force of attraction between the two. (c) Comment on the magnitude and the importance of these two forces. [G, gravitational constant = 6.672 x 10-11 N m2 kg-2; 4+Єo = 1.113 x 10-10 C2 m-1 J-1]arrow_forward
- 6) (a) The solubility of carbon tetrachloride (CCI4) in water at 25°C is 1.2 g/L. The solubility of chloroform (CHCI3) at the same temperature is 10.1g/L. Why is chloroform almost 10 times more soluble in water than is carbon tetrachloride? (b) Explain the difference between the Bohr model for the hydrogen atom and the quantum-mechanical model. Is the Bohr model consistent with Heisenberg's uncertainty principle? (Ctrl)arrow_forwardNa +, K +, Ca 2 +, and Mg 2 + are the four major cations in the body. For each cation, give the following information: (a) the number of protons; (b) the number of electrons; (c) the noble gas that has the same electronic confi guration; (d) its role in the body.arrow_forwardQ1. This question is about atomic structure. (a) Write the full electron configuration for each of the following species. CH Fe2+ (b) Write an equation, including state symbols, to represent the process that occurs when the third ionisation energy of manganese is measured. (c) State which of the elements magnesium and aluminium has the lower first ionisation energy Explain your answer. (d) A sample of nickel was analysed in a time of flight (TOF) mass spectrometer. The sample was ionised by electron impact ionisation. The spectrum produced showed three peaks with abundances as set out in the table. m/z Abundance /% 58 61.0 60 29.1 61 9.9 Give the symbol, including mass number, of the ion that would reach the detector first in the sample. Calculate the relative atomic mass of the nickel in the sample. Give your answer to one decimal place. Page 2 of 12 Symbol of ion Relative atomic massarrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co