(a)
Interpretation:
The compound, which exhibits weaker intermolecular forces, has to be given.
Concept introduction:
London Dispersion forces:
London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.
Hydrogen Bonding:
A
Dipole-dipole interactions:
Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position
(b)
Interpretation:
The compound that has lower boiling point has to be given.
(c)
Interpretation:
The compound that has lower melting point has to be given.
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Principles of General, Organic, Biological Chemistry
- What is the strongest intermolecular force present in 2-methylbutane, (CH3)2CHCH2CH3 ? a. Dipole-dipole forces b. Hydrogen bonding c. London forces d. Ionic bondingarrow_forwarda. Which substance, CH3 CH₂OH or CH3 CH₂ CH₂OH, would be expected to have a lower boiling point? Why? CH3 CH₂OH, because it has a stronger OH group. CH3 CH₂ CH₂OH, because it has stronger London forces. CH3 CH₂OH, because it has a smaller molar mass. CH3 CH₂ CH₂OH, because it has a larger molar mass. b. Which substance, CH4 or CH3OH, would be expected to have a lower boiling point? Why? OCH4, because only London forces are operating. OCH3OH, because it is capable of hydrogen bonding. CH4, because it is capable of hydrogen bonding. OCH, OH, because it has larger molar mass. c. Which substance, CH3 CH₂ CH2OH or CH3 CH₂ CH₂ CH₂ CH3, would be expected to have a lower boiling point? Why? CH3 CH₂ CH₂OH, because it is capable of hydrogen bonding. CH3 CH₂ CH₂ CH2 CH3, because it is not capable of hydrogen bonding. CH3 CH₂ CH₂OH, because it has a larger molar mass. CH3 CH₂ CH₂ CH₂ CH3, because it has a smaller molar mass.arrow_forwardWhich compound has the highest boiling point? O a. O b. HO- d. HO-arrow_forward
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- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning