Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 4, Problem 4.39P
Give the structure and IUPAC name for each of the nine isomers having molecular formula
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8
5 Alkenes are unsaturated hydrocarbons. They show structural isomerism. Alkenes take part
in addition reactions and form polymers.
(a) Structural isomers have the same molecular formula but different structural formulae.
Give an example of structural isomerism.
molecular formula .
two structural formulae
(b) Ethene reacts with each of the following. Give the name and structural formula of each
product.
(i) steam
name of product
structure of product
(ii) hydrogen
name of product
structure of product
What alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2?
Give the common name for
NN
OH
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CH3-CH₂-C-N-CH₂-CH3
Spell out the common name of the compound.
Give the IUPAC name for
0 CH₂
||
CH₂-C-N-CH₂-CH₂-CH₂,
Spell out the IUPAC name of the compound.
diethylamine
Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and
connecting them with bonds. Add charges where needed.
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Chapter 4 Solutions
Organic Chemistry
Ch. 4 - Prob. 4.1PCh. 4 - Problem 4.2 Which of the following is not another...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Problem 4.7 Give the IUPAC name for each...Ch. 4 - Give the IUPAC name for each compound. a....Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.10P
Ch. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.15PCh. 4 - Prob. 4.16PCh. 4 - Problem 4.17 a. Draw the three staggered and...Ch. 4 - Problem 4.18 Rank the following conformations in...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Problem 4.24 Draw both conformations for and...Ch. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.27PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.30PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.33PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - 4.38 Give the IUPAC name for each compound.
a. c....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.41PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.43PCh. 4 - Prob. 4.44PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - 4.46 Considering rotation around the bond...Ch. 4 - Prob. 4.47PCh. 4 - 4.48 (a) Using Newman projections, draw all...Ch. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - 4.59 Classify each pair of compounds as...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.61PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.63PCh. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.69PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.71PCh. 4 - Prob. 4.72PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- What alkane, with molecular formula C7H16, forms seven monochlorinated products (disregarding stereoisomers) when heated with Cl2?arrow_forwardGive the IUPAC name for each of the fi ve constitutional isomers of molecular formula C 6H 14 in Problem 12.40.arrow_forwardWrite structural formulas for all ketones with the molecular formula C6H12O and give each its IUPAC name. Which of these ketones are chiral?arrow_forward
- What is the structure of a compound with the formula C7H14O that has an ether and cyclobutane ring, including its IUPAC name? In addition, what is the structure of the compound with the formula C7H14O that does NOT contain the functional groups: epoxide, ether, cycloalkane, alcohol, alkene. Indicate the functional groups used that are present in the structure made for this compound.arrow_forwarddraw the structure of two costitution isomers with the molecular formula of C4H10. Give the IUPAC name of each isomerarrow_forwardFUNCTIONAL GROUP IUPAC NAME STRUCTURAL FORMULA CH3 CH;CH;CH3 CH,CH, CH;CH, CH3 + CH2C – NH2 CH3arrow_forward
- Draw the condensed (or the line) structure for the following compounds and give their name i) an aldehyde functional containing 6 carbons ii) an alkene function in a ring with 5 carbons iii) an alcohol function with carbons iv) a branched alkyne functional group that has 9 carbonsarrow_forwardCH3 CH2 CH3 CH CH2 Provide the IUPAC name of the compound. Parent name: Substituents: Locants: IUPAC Name:arrow_forwardDraw three constitutional isomers having molecular formula C 7H 14 that contain a fi ve-membered ring and two CH 3 groups bonded to the ring. Give the IUPAC name for each isomerarrow_forward
- Provide the IUPAC name the compound CH3(CH2)4-C=C-CH2CH=CH(CH2)¬CH3. Parent name: Locants: IUPAC Name:arrow_forwardGive the structural formula (condensed or skeletal) of the given IUPAC names of saturated hydrocarbons. 1) 2-methyl-3-oxohept-4-enoic acid 2) 4-chloro-2-oxohexanoyl chloride 3) 4-nitro-4-propoxybut-1-ene 4) 1-hydroxyhex-5-yn-2-one 5) 1-methylpropyl 3-amino-3-(1-methylpropoxy)propanoate 6) 1-ethoxy-3-mercaptohexane-2-thionearrow_forward1: Give at least five (5) uses of Etherin medicine. CH3 CH,-0-C-CH, CH, common name: methyl-t-butyl ether (MTBE) IUPAC name: 2-methoxy-2-methylpropane diphenyl ether or phenyl ether phenoxybenzene Analyze the given ether. Then describe the structural formula.arrow_forward
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