Essential University Physics (3rd Edition)
Essential University Physics (3rd Edition)
3rd Edition
ISBN: 9780134202709
Author: Richard Wolfson
Publisher: PEARSON
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Chapter 35, Problem 53P
To determine

The number of visible lines in the spectrum emitted by the ensemble of square-well system.

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A sodium atom in one of the states labeled “Lowest excited levels” in Fig. remains in that state, on average, for 1.6 * 10-8 s before it makes a transition to the ground state, emitting a photon with wavelength 589.0 nm and energy 2.105 eV. What is the uncertainty in energy of that excited state? What is the wavelength spread of the corresponding spectral line?
The smallest observed frequency for a transition between states of an electron in a one-dimensional box is 3.0 X 10¹3 s¹. What is the length of the box?
The electrons within the T-system of conjugated hydrocarbons may be treated as particles confined within a one-dimensional box. The lowest energy transition in the spectrum of a polyene hydrocarbon corresponds to excitation of an electron from the highest occupied energy level to the lowest unoccupied level. If the hydrocarbon contains 6 electrons and has a spectral transition at a wavelength of 278 nm, estimate the effective length of the TT-system. The estimated length = nm. Hint: you will need to fill the energy diagram to know which energy levels are involved in the transition. me = 9.110 x 1031 kg (Enter in e-notation, e.g. 1.23e-4, tolerance ±5%)
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