Campbell Biology in Focus (2nd Edition)
Campbell Biology in Focus (2nd Edition)
2nd Edition
ISBN: 9780321962751
Author: Lisa A. Urry, Michael L. Cain, Steven A. Wasserman, Peter V. Minorsky, Jane B. Reece
Publisher: PEARSON
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Chapter 3.1, Problem 4CC
Summary Introduction

To draw:

The structure where, from a cysteine molecule, the NH2 group is replaced with a COOH (carboxyl) group. Also, determine how this change would alter the chemical properties and state whether the central carbon atomis asymmetric after or before the alteration.

Concept introduction:

Amino acids are the molecules that are organic and consist of both the carboxyl and amino groups.

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The figure below illustrates the molecular structures of two fatty acids. A B H₂C The structural formula of erucic acid and behenic acid с H₂C D erucic acid behenic acid Which of the following best explains why erucic acid is liquid at room temperature but behenic acid is solid at room temperature? O OH The presence of a double carbon to carbon bond in erucic acid prevents the molecule from packing closely together. The lack of any double carbon-carbon bonds in behenic acid causes the molecule to be come polar and therefore packed more tightly. The larger number of carbon atoms in erucic acid prevents the molecule from packing tightly together. OH The smaller number of carbon atoms in behenic acid creates stronger covalent bonds between the carbon atoms allowing for them to pack more tightly together.
DRAW IT Suppose you had an organic molecule suchas cysteine (see Figure 4.9, sulfhydryl group example),and you chemically removed the —NH2 group andreplaced it with —COOH. Draw this structure. Howwould this change the chemical properties of themolecule? Is the central carbon asymmetric beforethe change? After?
When a substance such as sodium chloride is dissolved in water, the ions become completely surrounded by water molecules, forming structures called hydration spheres. When the sodium salt of a fatty acid is mixed with water, the carboxylate group of the molecule becomes hydrated, but the hydrophobic portion of the molecule is poorly hydrated, if at all. Using a circle to represent the carboxylate group and an attached squiggly line to represent the hydrocarbon chain of a fatty acid, draw a picture of how fatty acids interact with water.

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Campbell Biology in Focus (2nd Edition)

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