Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 30, Problem 30.44P
Rank the following compounds in order of increasing ability to undergo anionic chain-growth
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Provide the polymer showing 5 repeating units for the following alkene:
CH2CH=CH2CH3
The Alkene that produces the
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CH3 CH3
CH3
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CH2CHCH2CHCH2CHCH2CH-
Propylene O
Styrene O
Butadiene-1,3 O
Ethylene O
Write a balanced equation for the reaction of dihydroxy dimethylsilane (right)to form the condensation polymer known as Silly Putty.
Chapter 30 Solutions
Organic Chemistry
Ch. 30 - Prob. 30.1PCh. 30 - Prob. 30.2PCh. 30 - Prob. 30.3PCh. 30 - Draw the mechanism for the radical polymerization...Ch. 30 - Prob. 30.5PCh. 30 - Prob. 30.6PCh. 30 - Prob. 30.7PCh. 30 - Prob. 30.8PCh. 30 - Prob. 30.9PCh. 30 - Prob. 30.10P
Ch. 30 - Prob. 30.11PCh. 30 - Problem 30.12
What polymer is formed by anionic...Ch. 30 - Prob. 30.13PCh. 30 - Prob. 30.14PCh. 30 - Problem 30.15
What polyamide is formed from each...Ch. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Prob. 30.18PCh. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Prob. 30.23PCh. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30.26 Draw the structure of the polymer formed by...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - Prob. 30.37PCh. 30 - Prob. 30.38PCh. 30 - 30.39 Draw a stepwise mechanism for the...Ch. 30 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 30 - Prob. 30.41PCh. 30 - Prob. 30.42PCh. 30 - 30.43 Although styrene undergoes both cationic and...Ch. 30 - 30.44 Rank the following compounds in order of...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - 30.47 Draw a stepwise mechanism for the following...Ch. 30 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 30 - 30.49 Draw the products of each reaction.
a. e....Ch. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 30 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - 30.56 Compound A is a novel poly (ester amide)...Ch. 30 - 30.57 Researchers at Rutgers University have...Ch. 30 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 30 - 30.59 Although chain branching in radical...Ch. 30 - Prob. 30.60P
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- Haloalkanes undergo nucleophilic substitution whereas haloarenes undergo electrophilic substitution. Explain.arrow_forwardCharacterize EACH of the three given statements as being TRUE or FALSE and then indicate the collective true - false status of the statements using the choices. (1) Alcohols have higher boiling points than alkanes of similar molecular mass because of hydrogen bonding. (2) Polyols have similar boiling points to tertiary alcohols. (3) Primary and secondary alcohols give the same type of product when subjected to mild oxidizing agents. Group of answer choices All three statements are true. Two of the three statements are true. Only one of the statements is true. None of the statements are true.arrow_forwardPropylene does not undergo free radical polymerization readily because there are two competing steps after initiation: propagation and hydrogen atom abstraction.(a) Using a generic radical R• as a reactant with propylene, draw the mechanism and products for the two competing steps.(b) Which step produces the more stable product?(c) How do your results explain propylene’s poor reactivity in free radical polymerization?arrow_forward
- The reaction that occurs between 1,3-butadine and ethene at high temp and pressure is a/an: O substitution reaction O addition reaction oxidation-reduction reactionarrow_forwardPolymerisation reactions usually occur with molecules which have o no carbon-carbon double bonds o lots of carbon-carbon double bonds o only carbon-carbon single bonds o only carbon-carbon triple bondsarrow_forwardWhich of the following statements is/are true regarding Alkene A and the products of an ozonolysis (O_(3)) reaction? (i) One of the alkene carbon atoms of alkene A is disubstituted and the other is monosubstituted (ii) One of the alkene carbon atoms of alkene A is monosubstituted and the other is unsubstituted (iii) Ozonolysis of alkene A followed by work up under reductive conditions gives products 1 and 2, but if work up is under oxidative conditions products 1 and 3 form (iv) Ozonolysis of alkene A followed by work up under reductive conditions gives products 1 and 3 but if work up is under oxidative conditions products 1 and 2 form.. a. (i) and (iii) are truearrow_forward
- The heat of combustion of decahydronaphthalene(C10H18) is -6286 kJ/mol. The heat of combustion ofnaphthalene (C10H8) is -5157 kJ/mol. (In both casesCO2(g) and H2O(l) are the products.) Calculate the heat of hydrogenationand the resonance energy of naphthalene.arrow_forwardWrite a structural formula for the principal organic product or products of the following reactionarrow_forwardWhat polymer is formed when methyl α-methylacrylate [CH 2 C(CH 3)CO2CH 3] is polymerized? This polymer is used in Lucite and Plexiglas, transparent materials that are lighter but more impact resistant than glass.arrow_forward
- The reaction of p-cresol with CH2=O resembles the reaction of phenol (PhOH) with CH2=O, except that the resulting polymer is thermoplastic but not thermosetting. Draw the structure of the polymer formed, and explain why the properties of these two polymers are so different.arrow_forwardStyrene derivatives such as A can be polymerized by way of cationic rather than radical intermediates. Cationic polymerization is an example of electrophilic addition to an alkene involving carbocations. a.) Draw a short segment of the polymer formed by the polymerization ofA.b.) Why does A react faster than styrene (C6H5CH=CH2) in a cationicpolymerization?arrow_forwardWhen a substituted benzene undergoes an electrophilic aromatic substitution reaction, where doesthe new substituent attach itself?arrow_forward
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