Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Textbook Question
Chapter 3, Problem 77P
For each of the following compound, determine whether the cis isomer or the trans isomer is more stable.
a. 
b. 
c. 
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Organic Chemistry
15.
ADLC Assignment Booklet A3
Decide whether each statement is true (T) or false (F). Place your answer in
the blank space given.
a. A hydrocarbon molecule with a triple bond is more stable than
a hydrocarbon molecule with all single bonds.
b. The difference between butter and corn oil is that the
hydrocarbon molecule in butter contains a double carbon-
carbon bond.
c. A bent shape is the property that accounts for many of the
healthy properties of oleic acid present in corn oil.
d. A diet with no fat is the healthiest diet.
e. In an industrially produced trans fat, only the relative position
of the hydrogen atoms on either side of the double bond is
changed.
f. Trans fatty acids have a greater likelihood of clogging arteries
because they tend to be solids at room temperature.
41. Draw the structure of a hydrocarbon that has six carbon atoms and
a. three vinylic hydrogens and two allylic hydrogens.
b. three vinylic hydrogens and one allylic hydrogen.
c. three vinylic hydrogens and no allylic hydrogens.
Chapter 3 Solutions
Organic Chemistry, Books a la Carte Edition (8th Edition)
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structure of a compound with molecular...Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Prob. 6PCh. 3.1 - Draw the structure for each of the following: a....Ch. 3.1 - Name the following compounds: a. CH3OCH2CH3 b....Ch. 3.2 - Prob. 9PCh. 3.2 - Draw the structure for each of the following: a....Ch. 3.2 - Give each substituent on the nine-carbon chain a...Ch. 3.2 - Prob. 14P
Ch. 3.3 - What is each compounds systematic name?Ch. 3.3 - Prob. 16PCh. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 21PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Prob. 25PCh. 3.6 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Draw condensed and skeletal structures for each of...Ch. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 32PCh. 3.9 - Prob. 33PCh. 3.9 - Prob. 34PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.10 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - Prob. 38PCh. 3.10 - Prob. 39PCh. 3.11 - a. Draw all the staggered and eclipsed conformers...Ch. 3.11 - Prob. 41PCh. 3.11 - Using Newman projections, draw the most stable...Ch. 3.12 - The bond angles in a regular polygon with n sides...Ch. 3.12 - Prob. 44PCh. 3.13 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.14 - Using the data in Table 3.9, calculate the...Ch. 3.14 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.15 - Prob. 48PCh. 3.15 - Which has a higher percentage of the...Ch. 3.15 - a. Draw the more stable chair conformer of...Ch. 3.15 - For each of the following disubstituted...Ch. 3.15 - a. Draw Newman projections of the two conformers...Ch. 3.15 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 56PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 66PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 69PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 72PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - What is each compound s systematic name?Ch. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 88PCh. 3 - Using the data obtained in Problem 85, calculate...Ch. 3 - Draw the conformers for the following...
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- What is the relationship between the following molecules? CH3 H. CH3 H. II H. H. H. H. H. H3C CH3 O Identicals Constitutional isomers O Resonance structures Conformational Isomersarrow_forwardClassify each attached pair of compounds as constitutional isomers or identical molecules.arrow_forward1. Name each compound and determine the relationship between the pairs of compounds. O a. Name: b. Name: N C. Relationship between structures above: Conformational isomer or Structural isomer 2. Name: 3. Is the following structure the cis stereoisomer or the trans stereoisomer?arrow_forward
- which of the following compound has gauche as it stable conformer? a. 1, 2- dicloroethane b. n- butane c. n- propane d. 1,2- dihydroxyethane which other factor along with torsion decide the stability of conformer?a. intermolecular hydrogen bonding b. intramolecular hydrogen bonding c. coordinate bonding d. ionic bondingarrow_forwardThe following is generic depiction of a reaction using the curve arrow formalism. -D Which of these statements is not correct for this reaction? Electrons move from C to B. Electrons move from B to A. O In the products, a bond forms between C and B. O In the products, A would have a positive charge.arrow_forward1. Write the IUPAC name of each compound. a. Br b. C.arrow_forward
- The dimethylcyclohexane with the structure shown below is: ÇH3 CH3 Select one: O a. a trans isomer with the CH3 groups in axial positions. O b. a cis isomer with the CH3 groups in equatorial positions. O c. a cis isomer with the CH3 groups in equatorial and axial positions. O d. a trans isomer with the CH3 groups in equatorial positions.arrow_forwardCyclopentene is an example of: O a. Exocyclic double bond O b. Endocyclic double bond Oc. Unsaturated double bond Od. A ring alicyclic compoundarrow_forward3. Which term best describes the alkene below? OMe a. cis only b. trans only c. both terms may be used d. neither cis nor transarrow_forward
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