Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27, Problem 29P
Draw short segments of the
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Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- Draw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.arrow_forwardExplain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forward| Exercises 317 9.21 Identify the reactants from which the following molecules were prepared. If an acetal, identify the carbonyl compound and the alcohol; if an imine, identify the carbonyl compound and the amine; if an alcohol, identify the carbonyl compound and the Grignard reagent (red = 0, blue = N): (a) (b) (c)arrow_forward
- Give the structure and names of the organic product expected from the reaction of 1-butyne with:arrow_forwardComplete the synthesis of the following compound from the starting material givenarrow_forwardWhich products are formed when hydrobromic acid is added to (a) trans-2-hexene, (b) 2-methyl- 2-pentene, and (c) 4-methylcyclohexene, and how many regioisomers can be formed in each case?arrow_forward
- (d) Another variation on this type of polymer is used in hair gels. In these, the polymer chains are cross-linked by a compound known as pentaerythritol. но- OH но- OH pentaerythritol ( By what type of chemicat reaction are the cross-links in this polymer formed? (i) it is important that the gel should be easily washed out of hair What is it about the structure of the polymer that allows this to happen?arrow_forwardThe reaction of p-cresol with CH2=O resembles the reaction of phenol (PhOH) with CH2=O, except that the resulting polymer is thermoplastic but not thermosetting. Draw the structure of the polymer formed, and explain why the properties of these two polymers are so different.arrow_forwardDescribe a sequence of reactions by which trans-2-pentene can be prepared from propyne.arrow_forward
- For small-scale and consumer welding applications, many hardware stores sell cylinders of MAAP gas, which is a mixture of propyne (methylacetylene) and 1,2-propadiene (allene), with other hydrocarbons. How would you prepare the methylacetylene/allene mixture from propene in the laboratory?arrow_forwardNH2 Dry-erase boards, or whiteboards, in classrooms consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. (a) Propose a structure for the polymer formed. (b) Why is this type of polymer suitable for use in whiteboards? 'N. H2N `NH2 Melaminearrow_forwardWrite the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forward
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