(a)
Interpretation: Product of the given coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Answer to Problem 26.1P
The product of the given coupling reaction is octane as shown below.
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents act as nucleophille and react with organic halides to form coupling products that contains new
Figure 1
Product formed from the coupling reaction is shown in Figure 1.
(b)
Interpretation: Product of the coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.
Answer to Problem 26.1P
The product of the coupling reaction is
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents act as nucleophille and react with organic halides to form coupling products that contains new
Figure 2
Product formed from the coupling reaction is shown in Figure 2.
(c)
Interpretation: Product of the coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.
Answer to Problem 26.1P
The product of the coupling reaction is
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents acting as nucleophille and react with organic halides to form coupling products that contains new
Figure 3
Product formed from the coupling reaction is shown in Figure 3.
(d)
Interpretation: Product of the coupling reaction is to be predicted.
Concept introduction: Organocuprate reagents
Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.
Answer to Problem 26.1P
The product of the coupling reaction is
Explanation of Solution
Species containing copper-carbon bonds are known as organocuprate reagents. These reagents act as nucleophille and react with organic halides to form coupling products that contains new
Figure 4
Product formed from the coupling reaction is shown in Figure 4.
Want to see more full solutions like this?
Chapter 26 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Draw the products formed in each reaction sequence. a. b. CI [1] Ph3P Br [2] BuLi H [3] [1] Ph3P [2] BuLi [3] Harrow_forwardd) Explain why A is less reactive than B towards a nucleophilic attack. H. A Barrow_forwardDraw a stepwise mechanism and the product for the following substitution reaction: NaOCH3 acetone H3C- I CH3I finish structure draw structure ...arrow_forward
- Draw the structure of reactant A.arrow_forwardDraw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form asubstituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that canbe used as a synthetic detergent to clean away dirt.arrow_forwardElectrophilic Addition Soubong neblA-aleid rose 9160910 31 babeen ene singo 14.43 Draw the products formed when each compound is treated with one equivalent of HBr. a. b. C.arrow_forward
- What is the major organic product obtained from the following reaction? A. B. CI لله مللی حمله C. D. فيarrow_forwardHow would you convert cyclohexanone into each compound using any required inorganic reagents and needed organic compounds? a. b.arrow_forward16.41 Draw the products of each reaction. а. HNO3 H2SO4 'NO2 HO b. AICI3 CI С. H. Br2 FeBr3arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY