Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 26, Problem 26.16P
Interpretation Introduction

Interpretation:

The amount of epoxy alcohol obtained from 100g of racemic epoxy ester has to be calculated.

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Calculate the maximum number of possible stereoisomers of 2-methylocta-4,6-1-amine using the following formula:  Maximum number of possible stereoisomers = 2n (where n= the number of chiral carbons in your molecule). This calculation does not include E- or Z- isomers for any compounds containing double bonds
Lipases are enzymes that catalyze the hydrolysis of esters, especially esters of glycerol. Because enzymes are chiral catalysts, they catalyze the hydrolysis of only one enantiomer of a racemic mixture. For example, porcine pancreatic lipase catalyzes the hydrolysis of only one enantiomer of the following racemic epoxyester. Calculate the number of grams of epoxyalcohol that can be obtained from 100 g of racemic epoxyester by this method." „HO 'OH + On lipase CHO. H H A racemic mixture This enantiomer This epoxyalcohol is recovered is obtained in unhydrolyzed pure form
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