Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 25.6, Problem 4P
Why does the OH group add to the β-carbon rather than to the α-carbon in the second reaction in the β-oxidation of fats? (Hint: See Section 16.15.)
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In the breakdown of fatty acids, we see the activation of a carboxylic
acid by its conversion to a
amine
ester
alcohol
thioester
carbonyl
aldehyde
Using the following as possible steps in a pathway:
2 ClF (g) + O2 (g) → Cl2O (g) + OF2 (g)
ΔH° = 167.5 kJ
2 OF2 (g) → 2 F2 (g) + O2 (g)
ΔH° = 43.5 kJ
2 ClF3 (l) + 2 O2 (g) → Cl2O (g) + 3 OF2 (g)
ΔH° = 394.1 kJ
Determine a ΔH° for the reaction of gaseous chlorine monofluoride with gaseous fluorine to produce liquid chlorine trifluoride. Balance with the lowest whole number coefficients. Place your answer in the box provided.
You are given 150 mL of an oil made up of a mixture of 3 fatty acids:
palmitoleic acid (C 16:1 (n-7))
erucic acid (C 22:1 (n-9))
stearidonic acid (C 18:4 (n-3))
You know that the 150 mL sample of this oil was prepared by adding 60 mL of palmitoleic acid to 90 mL of a mixture of erucic acid and stearidonic acid.
Using a hydrometer you carefully measure the density of the 150 mL sample of oil and your analysis indicates that it has a density of 0.900 g/cm3.
The densities of the individual fatty acids are:
palmitoleic acid = 0.894 g/cm3
erucic acid = 0.860 g/cm3
stearidonic acid = 0.9334 g/cm3
Can you determine the volumes (in mL) of erucic acid and stearidonic acid in the total volume (150 mL) of the oil mixture?
Chapter 25 Solutions
Organic Chemistry
Ch. 25.6 - Prob. 2PCh. 25.6 - Prob. 3PCh. 25.6 - Why does the OH group add to the -carbon rather...Ch. 25.6 - Prob. 5PCh. 25.6 - How many molecules of NADH are formed from the...Ch. 25.7 - Prob. 7PCh. 25.7 - Prob. 8PCh. 25.7 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 25.7 - Prob. 10PCh. 25.8 - Prob. 11P
Ch. 25.8 - Prob. 12PCh. 25.8 - Prob. 13PCh. 25.8 - Propose a mechanism for the reduction of...Ch. 25.9 - Prob. 15PCh. 25.9 - Prob. 16PCh. 25.10 - Acid-catalyzed dehydration reactions are normally...Ch. 25.10 - Prob. 18PCh. 25.10 - Prob. 19PCh. 25.10 - Acid-catalyzed dehydration reactions are normally...Ch. 25.10 - Prob. 21PCh. 25.10 - Prob. 22PCh. 25.11 - Prob. 23PCh. 25.12 - a. What is the name of the enzyme that converts...Ch. 25.15 - Prob. 25PCh. 25.16 - Prob. 26PCh. 25.16 - Prob. 27PCh. 25.17 - Propose mechanisms for the Claisen condensation...Ch. 25.17 - Prob. 29PCh. 25.17 - Propose a mechanism for the conversion of...Ch. 25.17 - Propose a mechanism for the biosynthesis of...Ch. 25.17 - Propose a mechanism for the conversion of the E...Ch. 25.17 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.17 - Prob. 35PCh. 25.18 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25 - Prob. 38PCh. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Prob. 41PCh. 25 - Prob. 42PCh. 25 - Prob. 43PCh. 25 - Prob. 44PCh. 25 - Prob. 45PCh. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Prob. 48PCh. 25 - Prob. 49PCh. 25 - Prob. 50PCh. 25 - Prob. 51PCh. 25 - Prob. 52PCh. 25 - Prob. 53PCh. 25 - Prob. 54PCh. 25 - Prob. 55PCh. 25 - Prob. 56PCh. 25 - Prob. 57PCh. 25 - Prob. 58PCh. 25 - Prob. 59PCh. 25 - Prob. 60PCh. 25 - Prob. 61PCh. 25 - Prob. 62PCh. 25 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 25 - A student is trying to determine the mechanism for...Ch. 25 - What would be the results of the experiment in...Ch. 25 - Prob. 66PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - Eudesmol is a sesquiterpene found in eucalyptus....
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