The detailed mechanism for the reduction reaction of ketone to alcohol by dissolving metal is to be drawn. Concept introduction: In dissolving metal reduction, the reaction begins with addition of solvated electron to C=O bond. The solvated electron is generated by dissolving a solid metal like sodium in a solvent like liquid ammonia, where the metal loses an electron. The solvent used solvates this electron and stabilizes it; thus it is called solvated electron. The mechanism of reduction of ketone to alcohol by dissolving metal includes radical addition to carbonyl group, followed by proton transfer reaction. These processes occur twice in the mechanism.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 25, Problem 25.23P

Interpretation Introduction

Interpretation:

The detailed mechanism for the reduction reaction of ketone to alcohol by dissolving metal is to be drawn.

Concept introduction:

In dissolving metal reduction, the reaction begins with addition of solvated electron to C=O bond. The solvated electron is generated by dissolving a solid metal like sodium in a solvent like liquid ammonia, where the metal loses an electron. The solvent used solvates this electron and stabilizes it; thus it is called solvated electron. The mechanism of reduction of ketone to alcohol by dissolving metal includes radical addition to carbonyl group, followed by proton transfer reaction. These processes occur twice in the mechanism.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

this is an organic chemistry question please answer accordindly!! please post the solution draw the figures on a paper please hand drawn and post, please answer EACH part till the end and dont just provide wordy explanations, please draw them on a paper and post clearly!! answer the full question with all details EACH PART CLEARLY please thanks!! im reposting this please solve all parts and draw it not just word explanations!!

A mixture of 0.412 M C12, 0.544 M F2, and 0.843 M CIF is enclosed in a vessel and heated to 2500 K. C12(g) + F2(g )2CIF(g) Kc = 20.0 at 2500 K Calculate the equilibrium concentration of each gas at 2500 K. [C12] = M [F2] = M [ CIF] =

Show reaction mechanism with explanation. don't give Ai generated solution

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 25, Problem 25.23P

Interpretation Introduction

Interpretation:

The detailed mechanism for the reduction reaction of ketone to alcohol by dissolving metal is to be drawn.

Concept introduction:

In dissolving metal reduction, the reaction begins with addition of solvated electron to C=O bond. The solvated electron is generated by dissolving a solid metal like sodium in a solvent like liquid ammonia, where the metal loses an electron. The solvent used solvates this electron and stabilizes it; thus it is called solvated electron. The mechanism of reduction of ketone to alcohol by dissolving metal includes radical addition to carbonyl group, followed by proton transfer reaction. These processes occur twice in the mechanism.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 25, Problem 25.23P

Interpretation Introduction

Interpretation:

The detailed mechanism for the reduction reaction of ketone to alcohol by dissolving metal is to be drawn.

Concept introduction:

In dissolving metal reduction, the reaction begins with addition of solvated electron to C=O bond. The solvated electron is generated by dissolving a solid metal like sodium in a solvent like liquid ammonia, where the metal loses an electron. The solvent used solvates this electron and stabilizes it; thus it is called solvated electron. The mechanism of reduction of ketone to alcohol by dissolving metal includes radical addition to carbonyl group, followed by proton transfer reaction. These processes occur twice in the mechanism.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 25, Problem 25.23P

Interpretation Introduction