Chemistry: Atoms First
Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
Question
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Chapter 24, Problem 24.31QP

(a)

Interpretation Introduction

Interpretation:

What type of semiconductor that would be formed from the given combination of elements has to be explained.

Concept Introduction:

Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it.  Semiconductors electrically conductivity lie between conductor and insulator.  Semiconductors have small energy gap between valence band and conduction band.

Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor.  The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.

  • n- type semiconductor:  (conduction is due to movement of extra electrons)

The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increase the conductivity.

Example: Silicon (natural semiconductor) and Phosphorus

  • p-type semiconductor: (conduction is due to movement of holes)

The element added will have less valence electron than the natural semiconductor.  Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element.  A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.

Example: Silicon (natural semiconductor) and Gallium

(b)

Interpretation Introduction

Interpretation:

What type of semiconductor that would be formed from the given combination of elements has to be explained

Concept Introduction:

Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it.  Semiconductors electrically conductivity lie between conductor and insulator.  Semiconductors have small energy gap between valence band and conduction band.

Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor.  The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.

  • n- type semiconductor:  (conduction is due to movement of extra electrons)

The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increase the conductivity.

Example: Silicon (natural semiconductor) and Phosphorus

  • p-type semiconductor: (conduction is due to movement of holes)

The element added will have less valence electron than the natural semiconductor.  Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element.  A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.

Example: Silicon (natural semiconductor) and Gallium

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Students have asked these similar questions
a) Explain the band structure of an electrical conductor (metal), a semiconductor, and an insulator at 0 K by showing the valence and conduction bands and fermi energy levels. Explain how the electrical conduction takes place in these three types of materials. Give an example for each type of material. b)Explain what n and p-type semiconductors are using their band structures. Why?
(a) What change occurs when AgCl is doped with CdCl2?(b) What type of semiconductor is produced when silicon is doped with boron?
Define a semiconductor? Describe the two main types of semiconductorswhen it is doped with(a) group 13 element, (b) group 15 element.

Chapter 24 Solutions

Chemistry: Atoms First

Ch. 24.3 - Would the following molecule make a good liquid...Ch. 24.3 - Prob. 3PPACh. 24.3 - Prob. 3PPBCh. 24.3 - Prob. 3PPCCh. 24.3 - Prob. 24.3.1SRCh. 24.3 - Prob. 24.3.2SRCh. 24.6 - Prob. 24.4WECh. 24.6 - Prob. 4PPACh. 24.6 - Prob. 4PPBCh. 24.6 - Prob. 4PPCCh. 24.6 - Prob. 24.5WECh. 24.6 - Prob. 5PPACh. 24.6 - Prob. 5PPBCh. 24.6 - Prob. 5PPCCh. 24.6 - Prob. 24.6.1SRCh. 24 - Bakelite, the first commercially produced polymer,...Ch. 24 - Prob. 24.2QPCh. 24 - Prob. 24.3QPCh. 24 - Prob. 24.4QPCh. 24 - Prob. 24.5QPCh. 24 - Prob. 24.6QPCh. 24 - Prob. 24.7QPCh. 24 - Describe two natural types of composite materials...Ch. 24 - Prob. 24.9QPCh. 24 - Amorphous silica (SiO2) can be formed in uniform...Ch. 24 - Prob. 24.11QPCh. 24 - Prob. 24.12QPCh. 24 - Prob. 24.13QPCh. 24 - Prob. 24.14QPCh. 24 - Prob. 24.15QPCh. 24 - Prob. 24.16QPCh. 24 - Prob. 24.17QPCh. 24 - Prob. 24.18QPCh. 24 - Prob. 24.19QPCh. 24 - Prob. 24.20QPCh. 24 - Prob. 24.21QPCh. 24 - How does an STM measure the peak and valley...Ch. 24 - Prob. 24.23QPCh. 24 - Prob. 24.24QPCh. 24 - Prob. 24.25QPCh. 24 - Prob. 24.26QPCh. 24 - Prob. 24.27QPCh. 24 - Prob. 24.28QPCh. 24 - Prob. 24.29QPCh. 24 - Prob. 24.30QPCh. 24 - Prob. 24.31QPCh. 24 - Prob. 24.32QPCh. 24 - Prob. 24.33QPCh. 24 - Prob. 24.34QPCh. 24 - Prob. 24.35QPCh. 24 - Prob. 24.36QPCh. 24 - Prob. 24.37QPCh. 24 - Draw representations of block copolymers and graft...Ch. 24 - Prob. 24.39QPCh. 24 - Prob. 24.40QPCh. 24 - Prob. 24.41QPCh. 24 - Prob. 24.42QPCh. 24 - Prob. 24.43QPCh. 24 - Prob. 24.44QPCh. 24 - Prob. 24.45QPCh. 24 - Prob. 24.46QPCh. 24 - Prob. 24.47QPCh. 24 - Prob. 24.48QP
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