EBK ORGANIC CHEMISTRY
10th Edition
ISBN: 9781259636875
Author: Carey
Publisher: MCGRAW HILL BOOK COMPANY
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Chapter 23.9, Problem 9P
Interpretation Introduction
Interpretation:
The chemical equations expressing each of the given reactions are to be written.
Concept Introduction:
The reactivity of acid anhydrides is less than that of acyl halides.
The esterification of phenolic oxygen results in the formation of an ester via
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PROBLEM 23.26 Draw the mechanism
for the formation of phenol from
bromobenzene and sodium hydroxide
shown in the first reaction. Suppose,
instead, that the deuterium-labeled
bromobenzene shown in the second
reaction were used. What percentage
of the product would you expect to
contain the deuterium atom? Explain.
Br
d
1. NaOH, A
2. H₂O, HCI
OH
6
Br
D
1. NaOH, A
2. H₂O, HCI
None
20.39 Draw the product formed when phenylacetic acid (C6 H5CH2COOH) is treated with each reagent. With some
reagents, no reaction occurs.
а. NaHCOз
Main content
b. NaOH
c. SOCI2
Chapter 23 Solutions
EBK ORGANIC CHEMISTRY
Ch. 23.1 - Prob. 1PCh. 23.3 - Problem 23.2 One of the hydroxybenzoic acids is...Ch. 23.4 - Prob. 3PCh. 23.5 - Prob. 4PCh. 23.6 - Problem 23.5 The compound shown was required for...Ch. 23.8 - Prob. 6PCh. 23.8 - Prob. 7PCh. 23.9 - Prob. 8PCh. 23.9 - Prob. 9PCh. 23.10 - Prob. 10P
Ch. 23.12 - Prob. 11PCh. 23 - The IUPAC rules permit the use of common names for...Ch. 23 - Prob. 13PCh. 23 - Prob. 14PCh. 23 - Prob. 15PCh. 23 - Prob. 16PCh. 23 - Prob. 17PCh. 23 - Prob. 18PCh. 23 - Prob. 19PCh. 23 - Prob. 20PCh. 23 - Prob. 21PCh. 23 - Prob. 22PCh. 23 - Prob. 23PCh. 23 - Prob. 24PCh. 23 - Prob. 25PCh. 23 - Prob. 26PCh. 23 - Choose the reaction in each of the following pairs...Ch. 23 - Pentafluorophenol is readily prepared by heating...Ch. 23 - Prob. 29PCh. 23 - Treatment of p-hydroxybenzoic acid with aqueous...Ch. 23 - Prob. 31PCh. 23 - Prob. 32PCh. 23 - Treatment of 2,4,6-tri-tert-butylphenol with...Ch. 23 - Prob. 34PCh. 23 - Prob. 35PCh. 23 - Prob. 36DSPCh. 23 - Prob. 37DSPCh. 23 - Prob. 38DSPCh. 23 - Prob. 39DSP
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