Chemistry
13th Edition
ISBN: 9781259911156
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 23, Problem 23.4QP
Without referring to the text, write the ground-state electron configurations of the first-row
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Explain how to write an electron configuration for a transition metal cation. Is the order of electron removal upon ionization simply the reverse of electron addition upon filling? Why or why not?
Chapter 23 Solutions
Chemistry
Ch. 23.1 - Identify the following transition metal atoms and...Ch. 23.3 - Write the oxidation numbers of the metals in the...Ch. 23.3 - Prob. 2PECh. 23.3 - Prob. 3PECh. 23.3 - Prob. 1RCFCh. 23.3 - What is the difference between these two...Ch. 23.3 - Prob. 3RCFCh. 23.4 - Prob. 1RCFCh. 23.5 - Prob. 4PECh. 23.5 - Prob. 1RCF
Ch. 23.5 - Determine the number of unpaired electrons in the...Ch. 23 - What distinguishes a transition metal from a...Ch. 23 - Why is zinc not considered a transition metal?Ch. 23 - Explain why atomic radii decrease very gradually...Ch. 23 - Without referring to the text, write the...Ch. 23 - Write the electron configurations of the following...Ch. 23 - Why do transition metals have more oxidation...Ch. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Define the following terms: coordination compound,...Ch. 23 - Describe the interaction between a donor atom and...Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - What are the systematic names for the following...Ch. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Define the following terms: stereoisomers,...Ch. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Draw structures of all the geometric and optical...Ch. 23 - Prob. 23.26QPCh. 23 - Briefly describe crystal field theory.Ch. 23 - Prob. 23.28QPCh. 23 - What is the origin of color in a coordination...Ch. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Prob. 23.35QPCh. 23 - The absorption maximum for the complex ion...Ch. 23 - Prob. 23.37QPCh. 23 - A solution made by dissolving 0.875 g of...Ch. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - The [Fe(CN)6]3 complex is more labile than the...Ch. 23 - Aqueous copper(II) sulfate solution is blue in...Ch. 23 - When aqueous potassium cyanide is added to a...Ch. 23 - A concentrated aqueous copper(II) chloride...Ch. 23 - Prob. 23.46QPCh. 23 - As we read across the first-row transition metals...Ch. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Chemical analysis shows that hemoglobin contains...Ch. 23 - Explain the following facts: (a) Copper and iron...Ch. 23 - A student in 1895 prepared three coordination...Ch. 23 - Prob. 23.55QPCh. 23 - From the standard reduction potentials listed in...Ch. 23 - Using the standard reduction potentials listed in...Ch. 23 - The Co2+-porphyrin complex is more stable than the...Ch. 23 - Prob. 23.59QPCh. 23 - Prob. 23.60QPCh. 23 - Hydrated Mn2+ ions are practically colorless (see...Ch. 23 - Which of the following hydrated cations are...Ch. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - The compound 1,1,1-trifluoroacetylacetone (tfa) is...Ch. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Commercial silver-plating operations frequently...Ch. 23 - Draw qualitative diagrams for the crystal field...Ch. 23 - (a) The free Cu(I) ion is unstable in solution and...Ch. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QP
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- What characteristics of the transition elements set them apart from the main-group elements?arrow_forwardGive the symbol of the main-group metals in period 4 with the following number of unpaired electrons per atom. (Transition metals are not included.) (a) 0(b) 1(c) 2(d) 3arrow_forwardThe compound cisplatin, Pt(NH3)2Cl2, has been studied extensively as an antitumor agent. The reaction for the synthesis of cisplatin is: K2PtCl4(aq)+2NH3(aq)Pt(NH3)2Cl2(s)+2KCl(aq) Write the electron configuration for platinum ion in cisplatin. Most d8 transition metal ions exhibit square planar geometry. With this and the name in mind, draw the structure of cisplatin.arrow_forward
- Use partial atomic orbital box diagrams to explain the number of unpaired electrons shown in Figure 20.2 for (a) Mn2+ and (b) Cr3+.arrow_forwardWhat two first-row transition metals have unexpected electron configurations? A statement in the text says that first-row transition metal ions do not have 4s electrons. Why not? Why do transition metal ions often have several oxidation states, whereas representative metals generally have only one?arrow_forwardDescribe how to write an electron configuration for a transition metal cation. Is the order of electron removal upon ionization simply the reverse of electron addition upon filling? Why or why not?arrow_forward
- The group 3 (or 3B) transition metals include scandium, yttrium, lanthanum, and actinium. Except for actinium, the group 3 elements are relatively abundant, with a natural abundance on the order of that of metals such as cobalt and nickel. You may also hear lutetium or lawrencium counted as group 3 metals. The electron configuration for both are similar with one electron in the corresponding dorbital. For this tutorial, we will consider the four elements scandium, yttrium, lanthanum, and actinium when answering parts. The group 4 (or 4B) transition metals include titanium, zirconium, hafnium, and rutherfordium. These elements vary widely in abundance, from the relatively abundant titanium and zirconium to rutherfordium, which does not occur naturally. The naturally occurring group 5 (or 5B) transition metals include vanadium, niobium, and tantalum. All three of these elements are normally found in nature as oxide ores in their highest oxidation state, +5. The naturally occurring group…arrow_forwardPlease don't provide handwritten solution ....arrow_forwardDifferentiate between the electron configurations of the transition elements (d block) and inner transition elements?arrow_forward
- Which three steps need to be taken for the synthesis of elemental transition metalsarrow_forwardGive typed explanation not a single word hand written otherwise leave it Determine electron configurations for the following. - Mn^2+ - platnium (II) - iron (IV)arrow_forwardExplain the reasons for the trends in transition metals -As you move across period, the atomic radius remains constant -As you move down a column, the atomic radius increasesarrow_forward
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