Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 22, Problem 36P
Interpretation Introduction

(a)

Interpretation: The dicarbonyl compound which is needed to prepare given compound by an intramolecular aldol reaction is to be predicted.

Concept introduction: The Aldol condensation reaction that takes place in the different molecules in presence of strong base is known as intermolecular aldol reactions.

The Aldol condensation reaction that takes place within the same molecule in presence of strong base is known as intramolecular aldol reactions. This reaction takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate that acts as a nucleophile and reacts with second carbonyl group which acts as electrophile.

Interpretation Introduction

(b)

Interpretation: The dicarbonyl compound which is needed to prepare given compound by an intramolecular aldol reaction is to be predicted.

Concept introduction: The Aldol condensation reaction that takes place in the different molecules in presence of strong base is known as intermolecular aldol reactions.

The Aldol condensation reaction that takes place within the same molecule in presence of strong base is known as intramolecular aldol reactions. This reaction takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate that acts as a nucleophile and reacts with second carbonyl group which acts as electrophile.

Interpretation Introduction

(c)

Interpretation: The dicarbonyl compound which is needed to prepare given compound by an intramolecular aldol reaction is to be predicted.

Concept introduction: The Aldol condensation reaction that takes place in the different molecules in presence of strong base is known as intermolecular aldol reactions.

The Aldol condensation reaction that takes place within the same molecule in presence of strong base is known as intramolecular aldol reactions. This reaction takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate that acts as a nucleophile and reacts with second carbonyl group which acts as electrophile.

Interpretation Introduction

(d)

Interpretation: The dicarbonyl compound which is needed to prepare given compound by an intramolecular aldol reaction is to be predicted.

Concept introduction: The Aldol condensation reaction that takes place in the different molecules in presence of strong base is known as intermolecular aldol reactions.

The Aldol condensation reaction that takes place within the same molecule in presence of strong base is known as intramolecular aldol reactions. This reaction takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate that acts as a nucleophile and reacts with second carbonyl group which acts as electrophile.

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Problem 24.1 Draw the aldol product formed from each compound. CH,CHO b. (CH),CCH,CHO d. C. Problem 24.2 Which carbonyl compounds do not undergo an aldol reaction when treated with "OH in H,O? CHO сно b. C. (CH3)C a. d. H (CH);C
PROBLEM 18.24 Show how to synthesize the molecule shown here using an aldol reaction. of
L 16.32 Show how each of the following heterocycles could be synthesized. Ph. a) Ph. b) Ph d) NH Ph

Chapter 22 Solutions

Organic Chemistry (6th Edition)

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