Concept explainers
Draw the product formed when pentanoyl chloride
a.
b.
(a)
Interpretation:
The product formed by the treatment of pentanoyl chloride
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.45P
The product formed by the treatment of pentanoyl chloride
Explanation of Solution
Acyl chloride on reaction with
Figure 1
The product formed by the treatment of pentanoyl chloride
(b)
Interpretation:
The product formed by the treatment of pentanoyl chloride
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.45P
The product formed by the treatment of pentanoyl chloride
Explanation of Solution
The acyl chloride on reaction with alcohol converts into ester. The oxygen atom of alcoholic
Figure 2
The product formed by the treatment of pentanoyl chloride
(c)
Interpretation:
The product formed by the treatment of pentanoyl chloride
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.45P
The product formed by the treatment of pentanoyl chloride
Explanation of Solution
The acyl chloride on reaction with acetate ion converts into acid anhydride. The oxygen atom of acetate ion contains negative charge. It undergoes nucleophilic attack on electron deficient carbonyl carbon atom and replaces chlorine atom. The reaction between pentanoyl chloride and
Figure 3
The product formed by the treatment of pentanoyl chloride
(d)
Interpretation:
The product formed by the treatment of pentanoyl chloride
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.45P
The product formed by the treatment of pentanoyl chloride
Explanation of Solution
The reaction of acyl chloride with ammonia
Figure 4
The product formed by the treatment of pentanoyl chloride
(e)
Interpretation:
The product formed by the treatment of pentanoyl chloride
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.45P
The product formed by the treatment of pentanoyl chloride
Explanation of Solution
The reaction of acyl chloride with secondary amine leads to the formation of amide. The nitrogen atom of
Figure 5
The product formed by the treatment of pentanoyl chloride
(f)
Interpretation:
The product formed by the treatment of pentanoyl chloride
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.45P
The product formed by the treatment of pentanoyl chloride
Explanation of Solution
The reaction of acyl chloride with primary amine leads to the formation of amide. The nitrogen atom of
Figure 6
The product formed by the treatment of pentanoyl chloride
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Chapter 22 Solutions
Organic Chemistry
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