Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Question
Chapter 22, Problem 141RQ
Interpretation Introduction
Interpretation:
The condensed structures of isomeric alcohols formed as products by
Concept Information:
Isomerism is the phenomenon in which the existing compounds have the same molecular formula but different structural formula. These compounds differ in their physical and chemical properties. Isomeric compounds have the same molecular mass and molecular formula.
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TRUE OR FALSE
(a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions.
(b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom.
(c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups.
(d) There are two alcohols with the molecular formula C3H8O.
(e) There are three amines with the molecular formula C3H9N.
(f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group.
(g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid.
(h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°.
(i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O.
(j) The molecular formula of the smallest carboxylic…
1. (a) Draw the structures of the eight isomeric pentyl
alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol
system.
(c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl
alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and
a tertiary alcohol of the formula C,H13OH.
A certain hydrocarbon has a molecular formula of C5H8. Which of the following is not a structural possibility for this hydrocarbon? (a) It is a cycloalkane. (b) It contains one ring and one double bond. (c) It contains two double bonds and no rings. (d) It is an alkyne.
Chapter 22 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 22 - Prob. 1PECh. 22 - Prob. 2PECh. 22 - Prob. 3PECh. 22 - Practice Exercise 22.4
Write the IUPAC names of...Ch. 22 - Oxidation of an alcohol gave the following...Ch. 22 - Prob. 6PECh. 22 - Prob. 7PECh. 22 - Prob. 8PECh. 22 - Prob. 9PECh. 22 - Prob. 10PE
Ch. 22 - Complete the following equation by drawing...Ch. 22 - Prob. 12PECh. 22 - Prob. 13PECh. 22 - Prob. 14PECh. 22 - Prob. 15PECh. 22 - Label the hydrophobic and hydrophilic portions of...Ch. 22 - Draw a ribose ring and a deoxyribose ring. What is...Ch. 22 - Practice Exercise 22.18
Which base pairs match in...Ch. 22 - Prob. 1RQCh. 22 - Prob. 2RQCh. 22 - Prob. 3RQCh. 22 - Prob. 4RQCh. 22 - Prob. 5RQCh. 22 - Prob. 6RQCh. 22 - Prob. 7RQCh. 22 - Which of the following compounds has the higher...Ch. 22 - In general terms, why do functional groups impart...Ch. 22 - Prob. 10RQCh. 22 - What is the difference between geometric isomers...Ch. 22 - Prob. 12RQCh. 22 - No number is needed to identify the location of...Ch. 22 - Prob. 14RQCh. 22 - Prob. 15RQCh. 22 - Prob. 16RQCh. 22 - 22.17 In general terms, why doesn't benzene...Ch. 22 - Prob. 18RQCh. 22 - 22.19 Explain why is more soluble in water than ....Ch. 22 - Prob. 20RQCh. 22 - Prob. 21RQCh. 22 - Why do aldehydes and ketones have boiling points...Ch. 22 - Acetic acid boils at 118C, higher even than...Ch. 22 - Methyl ethanoate has many more atoms than its...Ch. 22 - Prob. 25RQCh. 22 - 22.26 Write condensed structures of the following...Ch. 22 - 3-Butanol is not a proper name, but a structure...Ch. 22 - Prob. 28RQCh. 22 - Prob. 29RQCh. 22 - Prob. 30RQCh. 22 - Prob. 31RQCh. 22 - Prob. 32RQCh. 22 - Amines, RNH2, do not have boiling points as high...Ch. 22 - A monofunctional organic nitrogen compound...Ch. 22 - Prob. 35RQCh. 22 - Prob. 36RQCh. 22 - Prob. 37RQCh. 22 - Write the products that can be expected to form in...Ch. 22 - Prob. 39RQCh. 22 - Prob. 40RQCh. 22 - 22.41 What do we mean by the term polymer...Ch. 22 - Prob. 42RQCh. 22 - Prob. 43RQCh. 22 - Prob. 44RQCh. 22 - Prob. 45RQCh. 22 - Prob. 46RQCh. 22 - Prob. 47RQCh. 22 - Prob. 48RQCh. 22 - Prob. 49RQCh. 22 - Prob. 50RQCh. 22 - Prob. 51RQCh. 22 - Prob. 52RQCh. 22 - Prob. 53RQCh. 22 - Prob. 54RQCh. 22 - Prob. 55RQCh. 22 - Prob. 56RQCh. 22 - Prob. 57RQCh. 22 - Prob. 58RQCh. 22 - What are the three fundamental needs for...Ch. 22 - Prob. 60RQCh. 22 - Prob. 61RQCh. 22 - Prob. 62RQCh. 22 - Name the compounds that form when sucrose is...Ch. 22 - Prob. 64RQCh. 22 - Prob. 65RQCh. 22 - Prob. 66RQCh. 22 - Prob. 67RQCh. 22 - 22.68 What function is served by glycogen in the...Ch. 22 - How are lipids defined?Ch. 22 - Why are lipids more soluble than carbohydrates in...Ch. 22 - 22.71 Cholesterol is not an ester, yet it is...Ch. 22 - A product such as corn oil is advertised as...Ch. 22 - Is it likely that the following compound could be...Ch. 22 - Describe the specific ways in which the monomers...Ch. 22 - What is the peptide bond? How is it similar to the...Ch. 22 - Prob. 76RQCh. 22 - Prob. 77RQCh. 22 - Why is a distinction made between the terms...Ch. 22 - Prob. 79RQCh. 22 - What kind of substance makes up most enzymes?Ch. 22 - Prob. 81RQCh. 22 - Prob. 82RQCh. 22 - Prob. 83RQCh. 22 - 22.84 How are the two DNA strands in a double...Ch. 22 - In what ways do DNA and RNA differ structurally.Ch. 22 - 22.86 Which base pairs with
Ch. 22 - The process of transcription begins with which...Ch. 22 - The process of translation begins with which...Ch. 22 - Prob. 89RQCh. 22 - 22.90 Write full (expanded) structures for each of...Ch. 22 - Prob. 91RQCh. 22 - Prob. 92RQCh. 22 - Prob. 93RQCh. 22 - Prob. 94RQCh. 22 - Prob. 95RQCh. 22 - Prob. 96RQCh. 22 - Prob. 97RQCh. 22 - Prob. 98RQCh. 22 - Prob. 99RQCh. 22 - Prob. 100RQCh. 22 - Prob. 101RQCh. 22 - 22.102 Write the structures of the cis and tram...Ch. 22 - 22.103 Write the structures of the products that...Ch. 22 - Prob. 104RQCh. 22 - 22.105 Repeat Problem 22.103 using...Ch. 22 - Repeat Problem 22.104 using cyclohexene. The...Ch. 22 - Prob. 107RQCh. 22 - Predict the products of the reaction of benzene...Ch. 22 - Prob. 109RQCh. 22 - Prob. 110RQCh. 22 - Prob. 111RQCh. 22 - Prob. 112RQCh. 22 - Prob. 113RQCh. 22 - Write the structure of the product of the...Ch. 22 - Prob. 115RQCh. 22 - Prob. 116RQCh. 22 - Prob. 117RQCh. 22 - Prob. 118RQCh. 22 - Prob. 119RQCh. 22 - Prob. 120RQCh. 22 - Prob. 121RQCh. 22 - Write the structures of the products that form in...Ch. 22 - Prob. 123RQCh. 22 - Prob. 124RQCh. 22 - Prob. 125RQCh. 22 - Prob. 126RQCh. 22 - Prob. 127RQCh. 22 - Prob. 128RQCh. 22 - 22.129 Write the structure of a triacylglycerol...Ch. 22 - 22.130 Write the structures of the products of the...Ch. 22 - Write the structure of the triacylglycerol that...Ch. 22 - *22.132 If the compound in Problem 22.130 is...Ch. 22 - *22.133 What parts of glyccrophospholipid...Ch. 22 - *22.134 In general terms, describe the structure...Ch. 22 - Prob. 135RQCh. 22 - What is the structure of the tripeptide that could...Ch. 22 - 22.137 What are the structures of the two...Ch. 22 - Prob. 138RQCh. 22 - Prob. 139RQCh. 22 - Prob. 140RQCh. 22 - Prob. 141RQCh. 22 - 22.142 Suggest a reason why trimethylamine, , has...Ch. 22 - Prob. 143RQCh. 22 - How many tripeptides can be made from three...Ch. 22 - Prob. 145RQCh. 22 - Prob. 146RQCh. 22 - Estimate the number of kilojoules of heat that...Ch. 22 - Prob. 148RQCh. 22 - Prob. 149RQCh. 22 - The compound that causes your eyes to water when...Ch. 22 - Prob. 151RQCh. 22 - Prob. 152RQCh. 22 - Use resonance structures to explain why urea,...Ch. 22 - Prob. 154RQCh. 22 - Prob. 155RQ
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