Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 21.10, Problem 20P

a)

Interpretation Introduction

Interpretation:

The structure of the given sugar β-D-galactopyranose is to be drawn by using Haworth projections.

Concept Introduction:

Haworth projections are used to represent the cyclic structures of the monosaccharides. In other words,

“A common way of writing a structural formula to represent the cyclic structure of monosaccharide with a simple three-dimensional perspective is called Haworth projection”.

b)

Interpretation Introduction

Interpretation:

The structure of the given sugar α-D-tagatopyranose is to be drawn by using Haworth projections.

Concept Introduction:

Haworth projections are used to represent the cyclic structures of the monosaccharides. In other words,

“A common way of writing a structural formula to represent the cyclic structure of monosaccharide with a simple three-dimensional perspective is called Haworth projection”.

c)

Interpretation Introduction

Interpretation: The structure of the given sugar α-D-tagatopyranose is to be drawn by using Haworth projections.

Concept Introduction:

Haworth projections are used to represent the cyclic structures of the monosaccharides. In other words,

“A common way of writing a structural formula to represent the cyclic structure of monosaccharide with a simple three-dimensional perspective is called Haworth projection”.

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Draw the products formed when B-D-galactose is treated with each reagent. a. Ag,0 + CH3I b. NaH + CgHsCH2CI c. The product in (b), then H30* d. Ac20 + pyridine e. CeHsCOCI + pyridine f. The product in (c), then CgHsCOCI + pyridine
1.Explain what is anomeric effect and why it happens?   2.Explain how a glycosyl acetimidate can loss its glycosyl donor activity?
Draw the following sugars using Haworth projections: b. a-D-tagatopyranose a. c. B-D-galactopyranose c. a-L-glucopyranose
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