Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 20, Problem 9QAP
Interpretation Introduction

Interpretation:

The volume of air should be obtained in cubic feet which will react with the coke under given condition of 25 ? and 1.00 atm should be determined.

Concept introduction:

The conversion factor for metric ton is:

1 metric ton = 1000 kg

Number of moles is obtained as:

n=mM

Where n is number of moles, m is given mass, and M is molar mass.

To obtain the volume of gases, the ideal gas equation is used as:

PV=nRT or V=nRTP

Where P is pressure, T is temperature, n is number of moles, R is gas constant, and V is volume of gas.

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage
Which carbocation is more stable?
Are the products of the given reaction correct?  Why or why not?

Chapter 20 Solutions

Chemistry: Principles and Reactions

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