Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 2, Problem 2.50SP
Label the reactants in these acid-base reactions as Lewis acids (electrophiles) or Lewis bases (nucleophiles). Use curved arrows to show the movement of electron pairs in the reactions.
- f. (CH3)3CCl + AlCl3 → (CH3)3C+ + −AlCl4
- h. CH2=CH2+BF3→BF–3—CH2—C+H2
- i. BF–3—CH2—C+H2+CH2=CH2→BF–3—CH2—CH2—CH2—CH+2
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Write the reaction as proton-transfer reactions. Label which reactant is the acid and which is the base, which product is the conjugate base of the original acid, and which is the conjugate acid of the original base. In addition, write Lewis structures for each reactant and product and use curved arrows to show the flow of electrons in each reaction.
identify the conjugate acid base pairs in this reaction
Acetic acid (HC2H3O2) reacts with pyridine (C5H5N). What are the products of this acid - base reaction?
HC2H3O2 + C5H5N = ???
Select one:
O a. C5H4N¯ and H2C2H3O2*
ОБ. СН302" and CsHsNH*
О с. СьНаN and Hз0*
O d. C2H3O2¯ and H30*
Ое.
H3O* and OH-
In the reaction
HSO4 (ag) + OH (6
= (be)
SOQ² (aq) + H2O(1)
the conjugate acid-base pairs are
Select one:
O a. HSO4¯ and OH" ; SO42- and H20.
O b. HSO4¯ and SO42- ; H20 and OH".
Ос.
HSO4¯ and H30*; so,²- and OH".
O d. HSO4¯ and H20 ; OH¯ and SO,2-.
e. HSO4¯ and OH" ; SO4²- and H3O*.
Chapter 2 Solutions
Organic Chemistry (9th Edition)
Ch. 2.1A - Prob. 2.1PCh. 2.1B - The NF bond is more polar than the NH bond: but...Ch. 2.1B - For each of the following compounds 1. Draw the...Ch. 2.1B - Two isomers of 1,2-dichloroethene are known One...Ch. 2.2C - Prob. 2.5PCh. 2.2C - Prob. 2.6PCh. 2.3 - Prob. 2.7PCh. 2.4 - Calculate the pH of the following solutions a....Ch. 2.6A - Ammonia appears in Table 2-2 as both an acid and a...Ch. 2.7 - Write equations for the following acid-base...
Ch. 2.7 - Ethanol, methylamine. and acetic acid are all...Ch. 2.8 - Prob. 2.12PCh. 2.10 - Write equations for the following acid-base...Ch. 2.10 - Rank the following acids in decreasing order of...Ch. 2.11 - Prob. 2.15PCh. 2.11 - Prob. 2.16PCh. 2.11 - Consider each pair of bases and explain which one...Ch. 2.12 - Which is a stronger base ethoxide ion or acetate...Ch. 2.12 - Prob. 2.19PCh. 2.12 - Prob. 2.20PCh. 2.12 - Prob. 2.21PCh. 2.12 - Choose the more basic member of each pair of...Ch. 2.14 - Prob. 2.23PCh. 2.15D - Classify the following hydrocarbons and draw a...Ch. 2.16D - Prob. 2.25PCh. 2.17C - Draw a Lewis structure and classify each of the...Ch. 2.17C - Circle the functional groups in the following...Ch. 2 - The CN triple bond in acetonitrile has a dipole...Ch. 2 - Prob. 2.29SPCh. 2 - Sulfur dioxide has a dipole moment of 1.60 D....Ch. 2 - Which of the following pure compounds can form...Ch. 2 - Predict which member of each pair is more soluble...Ch. 2 - Prob. 2.33SPCh. 2 - Prob. 2.34SPCh. 2 - Predict which compound in each pair has the higher...Ch. 2 - All of the following compounds can react as acids...Ch. 2 - Rank the following species in order of increasing...Ch. 2 - Rank the following species in order of increasing...Ch. 2 - The Ka of phenylacetic acid is 5 2 105, and the...Ch. 2 - The following compound can become protonated on...Ch. 2 - The following compounds are listed in increasing...Ch. 2 - Prob. 2.42SPCh. 2 - Prob. 2.43SPCh. 2 - Compare the relative acidity of 1-molar aqueous...Ch. 2 - The following compounds can all react as acids. a....Ch. 2 - The following compounds can all react as bases. a....Ch. 2 - The following compounds can all react as acids. a....Ch. 2 - Prob. 2.48SPCh. 2 - Methyllithium (CH3Li) is often used as a base in...Ch. 2 - Label the reactants in these acid-base reactions...Ch. 2 - In each reaction, label the reactants as Lewis...Ch. 2 - Prob. 2.52SPCh. 2 - Each of these compounds can react as a nucleophile...Ch. 2 - Prob. 2.54SPCh. 2 - Give a definition and an example for each class of...Ch. 2 - Circle the functional groups in the following...Ch. 2 - Prob. 2.57SP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Reaction between hydrochloric acid and sodium hydroxide: HCl(aq) + NaOH (aq) → NaCl(aq) + H2O(l) Reaction between acetic acid and sodium hydroxide: CH3COOH(aq) + NaOH(aq) → CH3COONa(aq) + H2O(l) Consider the two reactions you have just written out above. Which reaction would you predict to have higher pH at the equivalence point? Explain your reasoning.arrow_forward10. The K, of methanol is 5.01 * 1016. Which side of the following reaction is favored, reactants or products? Explain your reasoning. Methanol (CH3OH) + NaOH H20 Con Basearrow_forwardPlease see attachedarrow_forward
- In reaction D: CuO + H2SO4= CUSO4 + H2O Students will occasionally use HNO3 (aq) instead of H2SO4 (aq) in reaction D, assuming that both strong acids will accomplish the same purpose. Briefly describe the results of this error.arrow_forward4. Using structures for all species, write the complete esterification reaction begun below: HSO, methanol (CH3OH) + salicylic acidarrow_forward1a. Predict the products of the following acid-base reactions, including formal charges. Label the acid, base, conjugate acid, and conjugate base. Indicate whether the equilibrium will favor the reactants or the products. dar shivon noitulaz zuosups 100 ↑ H₂C=CH₂ OH OH₂ CI H HC-C NH₂ OH - housesh aniwalat arit tol mainsiasms abiyonarrow_forward
- For the following acid-base reaction, (1) predict the products, showing both reactants and products complete Lewis structures and arrows showing electron flow; (2) label each structure with the lowing: Bronsted acid, Bronsted base, conjugate acid, conjugate base; (3) give a brief definition of a ronsted acid and Bronsted base; (4) predict the direction of the equilibrium and justify your answer. HC0OH + CH3 Nta PRん106Y pkb = 3.36arrow_forwardpropanoic acid + methanol (in concentrated sulfuric acid)arrow_forwardWhy does the dehydration of an alcohol more often use concentrated sulfuric acid, H2SO4H2SO4, as the acid catalyst rather than dilute hydrochloric acid, HCl? Select one or more: Hydrochloric acid is too small to effectively react with the alcohol in the reaction. The additional water solvent from a dilute solution could reverse the dehydration reaction. Only acids with more than one proton can complete the dehydration reaction. The presence of the chloride ion could result in a competing substitution reaction.arrow_forward
- Given the reaction HC1O4 + CN CIO + HCN The acid HCIO4 reacts with its conjugate acid CN to form CI0 and its conjugate base HCN. The acid HC104 reacts with the base CN to form the conjugate acid Clo and the conjugate base HCN. The acid HC104 reacts with its conjugate base CN to form C10 and its conjugate acid HCN The base HC104 reacts with the acid CN to form the conjugate acid ClO, and the conjugate base HCN. The acid HC104 reacts with the base CN to form the conjugate base Clo, and the conjugate acid HCN. Submit Questionarrow_forwardEquation 1 : HA + H2O -> A- + H3O+ weak acid conjugate base (a) Using Equation 1 as a guide, write an equation for the reaction of acetic acid (CH 3COOH) with water.(b) Identify the conjugate base of acetic acid in the reaction equation.arrow_forwardConsider the weak acid reaction: HA + H2O <-> H3O+ + A-1 and the reaction of its conjugate base: A-1 + H2O <-> HA + OH-1 Add the weak acid reaction and the conjugate base reaction together and write the net reaction. You do not need to include subscripts or superscripts. use the "=" sign for the arrow. [reaction]arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY