Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
Question
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Chapter 2, Problem 2.14NP

(a)

Interpretation Introduction

Interpretation: The work done needs to be calculated for an isothermal and reversible expansion of 1.25 mol of an ideal gas with initial temperature and pressure is 320 K and 3.10 bar. The final temperature is 1.00 bar and CP,m=5R2 .

Concept Introduction: For an adiabatic process, the heat involved is equal to zero. The molar heat capacity at constant volume is represented as CV,m and molar heat capacity at constant pressure is CP,m .

(b)

Interpretation Introduction

Interpretation: The work done needs to be calculated for an adiabatic and reversible expansion of 1.25 mol of an ideal gas with initial temperature and pressure is 320 K and 3.10 bar. The final temperature is 1.00 bar and CP,m=5R2 . The difference between the two results needs to be explained.

Concept Introduction: For an adiabatic process, the heat involved is equal to zero. The molar heat capacity at constant volume is represented as CV,m and molar heat capacity at constant pressure is CP,m .

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