Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
bartleby

Concept explainers

Question
Book Icon
Chapter 2, Problem 2.111EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name has to be given for the substituted benzene derivative.

Concept Introduction:

When hydrogen atoms are replaced by one or more groups in benzene is known as substitution reaction and the compounds produced is benzene derivatives.

Benzene derivative with one substituent:

IUPAC system of naming monosubstituted benzene derivatives uses the name of substituent as prefix to the name benzene. If the group that is present in benzene cannot be named easily means, then the benzene ring is often treated as group attached to this substituent. The benzene ring is known as phenyl in this approach.

Benzene derivative with two substituents:

When benzene ring contains two substituents it is known as disubstituted benzene derivative. Three isomers are possible for the disubstituted benzene derivative. The prefix used in IUPAC name are,

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

When both the substituents present on the benzene ring imparts a special name, where all the substituents are cited in alphabetical order before the ending –benzene. The carbon that bears the group with alphabetical priority is given number 1.

Benzene derivatives with three or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name has to be given for the substituted benzene derivative.

Concept Introduction:

When hydrogen atoms are replaced by one or more groups in benzene is known as substitution reaction and the compounds produced is benzene derivatives.

Benzene derivative with one substituent:

IUPAC system of naming monosubstituted benzene derivatives uses the name of substituent as prefix to the name benzene. If the group that is present in benzene cannot be named easily means, then the benzene ring is often treated as group attached to this substituent. The benzene ring is known as phenyl in this approach.

Benzene derivative with two substituents:

When benzene ring contains two substituents it is known as disubstituted benzene derivative. Three isomers are possible for the disubstituted benzene derivative. The prefix used in IUPAC name are,

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

When both the substituents present on the benzene ring imparts a special name, where all the substituents are cited in alphabetical order before the ending –benzene. The carbon that bears the group with alphabetical priority is given number 1.

Benzene derivatives with three or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name has to be given for the substituted benzene derivative.

Concept Introduction:

When hydrogen atoms are replaced by one or more groups in benzene is known as substitution reaction and the compounds produced is benzene derivatives.

Benzene derivative with one substituent:

IUPAC system of naming monosubstituted benzene derivatives uses the name of substituent as prefix to the name benzene. If the group that is present in benzene cannot be named easily means, then the benzene ring is often treated as group attached to this substituent. The benzene ring is known as phenyl in this approach.

Benzene derivative with two substituents:

When benzene ring contains two substituents it is known as disubstituted benzene derivative. Three isomers are possible for the disubstituted benzene derivative. The prefix used in IUPAC name are,

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

When both the substituents present on the benzene ring imparts a special name, where all the substituents are cited in alphabetical order before the ending –benzene. The carbon that bears the group with alphabetical priority is given number 1.

Benzene derivatives with three or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name has to be given for the substituted benzene derivative.

Concept Introduction:

When hydrogen atoms are replaced by one or more groups in benzene is known as substitution reaction and the compounds produced is benzene derivatives.

Benzene derivative with one substituent:

IUPAC system of naming monosubstituted benzene derivatives uses the name of substituent as prefix to the name benzene. If the group that is present in benzene cannot be named easily means, then the benzene ring is often treated as group attached to this substituent. The benzene ring is known as phenyl in this approach.

Benzene derivative with two substituents:

When benzene ring contains two substituents it is known as disubstituted benzene derivative. Three isomers are possible for the disubstituted benzene derivative. The prefix used in IUPAC name are,

Ortho- means disubstitution in 1,2

Meta- means disubstitution in 1,3

Para- means disubstitution in 1,4

When both the substituents present on the benzene ring imparts a special name, where all the substituents are cited in alphabetical order before the ending –benzene. The carbon that bears the group with alphabetical priority is given number 1.

Benzene derivatives with three or more substituents:

More than two groups are present in the benzene ring means, their positions are numbered. The numbering is always done in a way that the carbon atom bearing substituent gets the lowest numbering possible. If there is a choice of numbering system, then the group that comes alphabetically first is given the lowest number.

Blurred answer
Students have asked these similar questions
Pick the aromatic compound: A. 1,2,3 B. 1,2,4 C. 2,3,4 D. 1,3,4
None
JON Determine the bund energy for UCI (in kJ/mol Hcl) using me balanced chemical equation and bund energies listed? का (My (9) +36/2(g)-(((3(g) + 3(g) A Hryn = -330. KJ bond energy и-н 432 bond bond C-1413 C=C 839 N-H 391 C=O 1010 S-H 363 б-н 467 02 498 N-N 160 N=N 243 418 C-C 341 C-0 358 C=C C-C 339 N-Br 243 Br-Br C-Br 274 193 614 (-1 214||(=olin (02) 799 C=N 615 AAL

Chapter 2 Solutions

Organic And Biological Chemistry

Ch. 2.3 - Prob. 4QQCh. 2.4 - Prob. 1QQCh. 2.4 - Prob. 2QQCh. 2.5 - Prob. 1QQCh. 2.5 - Prob. 2QQCh. 2.5 - Prob. 3QQCh. 2.6 - Prob. 1QQCh. 2.6 - Prob. 2QQCh. 2.6 - Prob. 3QQCh. 2.7 - Prob. 1QQCh. 2.7 - Prob. 2QQCh. 2.7 - Prob. 3QQCh. 2.8 - Prob. 1QQCh. 2.8 - Prob. 2QQCh. 2.9 - Prob. 1QQCh. 2.9 - Prob. 2QQCh. 2.10 - Prob. 1QQCh. 2.10 - Prob. 2QQCh. 2.10 - Prob. 3QQCh. 2.10 - Prob. 4QQCh. 2.10 - Prob. 5QQCh. 2.11 - Prob. 1QQCh. 2.11 - Prob. 2QQCh. 2.11 - Prob. 3QQCh. 2.11 - Prob. 4QQCh. 2.11 - Prob. 5QQCh. 2.12 - Prob. 1QQCh. 2.12 - Prob. 2QQCh. 2.12 - Prob. 3QQCh. 2.12 - Prob. 4QQCh. 2.12 - Prob. 5QQCh. 2.13 - Prob. 1QQCh. 2.13 - Prob. 2QQCh. 2.13 - Prob. 3QQCh. 2.14 - Prob. 1QQCh. 2.14 - Prob. 2QQCh. 2.14 - Prob. 3QQCh. 2.14 - Prob. 4QQCh. 2.15 - Prob. 1QQCh. 2.15 - Prob. 2QQCh. 2.15 - Prob. 3QQCh. 2.15 - Prob. 4QQCh. 2.16 - Prob. 1QQCh. 2.16 - Prob. 2QQCh. 2 - Classify each of the following hydrocarbons as...Ch. 2 - Prob. 2.2EPCh. 2 - Prob. 2.3EPCh. 2 - Prob. 2.4EPCh. 2 - Prob. 2.5EPCh. 2 - Prob. 2.6EPCh. 2 - Prob. 2.7EPCh. 2 - Characterize the physical properties of saturated...Ch. 2 - Prob. 2.9EPCh. 2 - Prob. 2.10EPCh. 2 - Prob. 2.11EPCh. 2 - Prob. 2.12EPCh. 2 - Prob. 2.13EPCh. 2 - Prob. 2.14EPCh. 2 - What is the name of the spatial arrangement for...Ch. 2 - Prob. 2.16EPCh. 2 - Prob. 2.17EPCh. 2 - Prob. 2.18EPCh. 2 - Draw a condensed structural formula for each of...Ch. 2 - Prob. 2.20EPCh. 2 - The following names are incorrect by IUPAC rules....Ch. 2 - The following names are incorrect by IUPAC rules....Ch. 2 - Prob. 2.23EPCh. 2 - Draw a condensed structural formula for each of...Ch. 2 - Prob. 2.25EPCh. 2 - Classify each of the following compounds as...Ch. 2 - Prob. 2.27EPCh. 2 - How many hydrogen atoms are present in a molecule...Ch. 2 - Draw a line-angle structural formula for each of...Ch. 2 - Draw a line-angle structural formula for each of...Ch. 2 - Prob. 2.31EPCh. 2 - Prob. 2.32EPCh. 2 - Prob. 2.33EPCh. 2 - Prob. 2.34EPCh. 2 - Prob. 2.35EPCh. 2 - Prob. 2.36EPCh. 2 - Prob. 2.37EPCh. 2 - Prob. 2.38EPCh. 2 - For each of the following pairs of alkenes,...Ch. 2 - For each of the following pairs of alkenes,...Ch. 2 - Prob. 2.41EPCh. 2 - Prob. 2.42EPCh. 2 - Prob. 2.43EPCh. 2 - Prob. 2.44EPCh. 2 - Prob. 2.45EPCh. 2 - Prob. 2.46EPCh. 2 - For each molecule, indicate whether cistrans...Ch. 2 - Prob. 2.48EPCh. 2 - Prob. 2.49EPCh. 2 - Prob. 2.50EPCh. 2 - Draw a structural formula for each of the...Ch. 2 - Prob. 2.52EPCh. 2 - Prob. 2.53EPCh. 2 - For each of the following molecules, indicate...Ch. 2 - Prob. 2.55EPCh. 2 - Prob. 2.56EPCh. 2 - Prob. 2.57EPCh. 2 - Prob. 2.58EPCh. 2 - Prob. 2.59EPCh. 2 - How many isoprene units are present in a....Ch. 2 - Prob. 2.61EPCh. 2 - Indicate whether each of the following statements...Ch. 2 - Prob. 2.63EPCh. 2 - Prob. 2.64EPCh. 2 - Prob. 2.65EPCh. 2 - Prob. 2.66EPCh. 2 - Prob. 2.67EPCh. 2 - Prob. 2.68EPCh. 2 - Prob. 2.69EPCh. 2 - Prob. 2.70EPCh. 2 - Prob. 2.71EPCh. 2 - Prob. 2.72EPCh. 2 - Prob. 2.73EPCh. 2 - Prob. 2.74EPCh. 2 - Prob. 2.75EPCh. 2 - Prob. 2.76EPCh. 2 - Supply the structural formula of the product in...Ch. 2 - Prob. 2.78EPCh. 2 - Prob. 2.79EPCh. 2 - What reactant would you use to prepare each of the...Ch. 2 - Prob. 2.81EPCh. 2 - Prob. 2.82EPCh. 2 - Prob. 2.83EPCh. 2 - Prob. 2.84EPCh. 2 - Prob. 2.85EPCh. 2 - Prob. 2.86EPCh. 2 - Prob. 2.87EPCh. 2 - Prob. 2.88EPCh. 2 - Prob. 2.89EPCh. 2 - Prob. 2.90EPCh. 2 - Prob. 2.91EPCh. 2 - Prob. 2.92EPCh. 2 - Prob. 2.93EPCh. 2 - Prob. 2.94EPCh. 2 - Prob. 2.95EPCh. 2 - Prob. 2.96EPCh. 2 - Prob. 2.97EPCh. 2 - Prob. 2.98EPCh. 2 - Prob. 2.99EPCh. 2 - Prob. 2.100EPCh. 2 - Prob. 2.101EPCh. 2 - Prob. 2.102EPCh. 2 - Prob. 2.103EPCh. 2 - Prob. 2.104EPCh. 2 - Prob. 2.105EPCh. 2 - Prob. 2.106EPCh. 2 - Prob. 2.107EPCh. 2 - Prob. 2.108EPCh. 2 - Assign each of the compounds in Problem 13-107 an...Ch. 2 - Assign each of the compounds in Problem 13-108 an...Ch. 2 - Prob. 2.111EPCh. 2 - Prob. 2.112EPCh. 2 - Prob. 2.113EPCh. 2 - Prob. 2.114EPCh. 2 - Prob. 2.115EPCh. 2 - Prob. 2.116EPCh. 2 - Prob. 2.117EPCh. 2 - Prob. 2.118EPCh. 2 - Prob. 2.119EPCh. 2 - Prob. 2.120EPCh. 2 - Prob. 2.121EPCh. 2 - Prob. 2.122EPCh. 2 - Prob. 2.123EPCh. 2 - Prob. 2.124EPCh. 2 - Prob. 2.125EPCh. 2 - Prob. 2.126EPCh. 2 - Prob. 2.127EPCh. 2 - Prob. 2.128EPCh. 2 - Prob. 2.129EPCh. 2 - Prob. 2.130EP
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Introductory Chemistry For Today
Chemistry
ISBN:9781285644561
Author:Seager
Publisher:Cengage
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Text book image
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning