Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 2, Problem 155GQ
The mass spectrum of CH3$Cl is illustrated here. You know that carbon has two stable isotopes, and 13C with relative abundances of 98.9% and 1.1%, respectively, and chlorine has two isotopes, 35a and 37CI with abundances of 75.77% and 24.23%, respectively.
(a) What molecular species gives rise to the lines at m/Z of 50 and 52? Why is the line at 52 about 1/3 the height of the line at 50?
(b) What species might be responsible for the line at m/Z = 51?
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Chapter 2 Solutions
Chemistry & Chemical Reactivity
Ch. 2.2 - 1. What is the mass of an iron atom with 30...Ch. 2.2 - 1. The mass of an atom of manganese is 54.9380 u....Ch. 2.2 - An atom contains 12 neutrons and has a mass number...Ch. 2.3 - 1. Silver has two isotopes, one with 60 neutrons...Ch. 2.3 - 2. A naturally occurring sample of argon contains...Ch. 2.4 - Verify that the atomic weight of chlorine is...Ch. 2.4 - Neon has three stable isotopes, one with a small...Ch. 2.4 - 1. Which is the more abundant isotope of copper,...Ch. 2.4 - 2. Which of the following is closest to the...Ch. 2.4 - Prob. 3RC
Ch. 2.5 - Prob. 1QCh. 2.5 - Prob. 2QCh. 2.5 - Which of the following elements is a metalloid?...Ch. 2.5 - Prob. 2RCCh. 2.5 - Prob. 3RCCh. 2.5 - Prob. 4RCCh. 2.6 - Prob. 1RCCh. 2.7 - Give the number and identity of the constituent...Ch. 2.7 - (a) Write the formulas of all neutral ionic...Ch. 2.7 - Prob. 1RCCh. 2.7 - Prob. 2RCCh. 2.7 - Prob. 3RCCh. 2.7 - The formula of barium acetate is (a) Ba(CH3CO2)2...Ch. 2.7 - 5. The name of the compound with the formula V2O3...Ch. 2.7 - Which should have the higher melting point, MgO or...Ch. 2.8 - Prob. 1RCCh. 2.8 - Prob. 2RCCh. 2.8 - Prob. 3RCCh. 2.8 - Prob. 4RCCh. 2.9 - The density of gold, Au, is 19.32 g/cm3. What is...Ch. 2.9 - If you have 454 g of citric acid (H3C6H5O7), what...Ch. 2.9 - Prob. 1RCCh. 2.9 - Which of the following contains the largest number...Ch. 2.9 - Which of the following has the largest mass? (a)...Ch. 2.9 - Prob. 4RCCh. 2.9 - Prob. 5RCCh. 2.10 - 1. Express the composition of ammonium carbonate,...Ch. 2.10 - 1. What is the empirical formula of naphthalene,...Ch. 2.10 - Gallium oxide, GaxOy forms when gallium is combine...Ch. 2.10 - Hydrated nickel(II) chloride is a beautiful green,...Ch. 2.10 - Prob. 1QCh. 2.10 - Salvarsan was long thought to be a single...Ch. 2.10 - To determine the density of atmospheric nitrogen....Ch. 2.10 - The density of a mixture of gases may be...Ch. 2.10 - Atmospheric argon is a mixture of three stable...Ch. 2.10 - Given that the density of argon is 1.78 g/L under...Ch. 2.10 - 1. Which of the following hydrocarbons has the...Ch. 2.10 - 2. An organic compound has an empirical formula...Ch. 2.10 - Eugenol is the major component in oil of cloves....Ch. 2.10 - 4. Epsom salt is MgSO4 · 7H2O. When heated to 70...Ch. 2 - Prob. 1PSCh. 2 - Define mass number. What is the difference between...Ch. 2 - An atom has a very small nucleus surrounded by an...Ch. 2 - A gold atom has a radius of 145 pm. If you could...Ch. 2 - Give the complete symbol(ZAX), including atomic...Ch. 2 - Give the complete symbol(ZAX), including atomic...Ch. 2 - Prob. 7PSCh. 2 - Atomic structure. (a) The synthetic radioactive...Ch. 2 - Prob. 9PSCh. 2 - In 1886 Eugene Goldstein observed positively...Ch. 2 - Marie Curie was born in Poland but studied and...Ch. 2 - Prob. 12PSCh. 2 - The mass of an 16 O atom is 15.995 u. What is its...Ch. 2 - What is the mass of one 16O atom, in grams? (The...Ch. 2 - Cobalt has three radioactive isotopes used in...Ch. 2 - Naturally occurring silver exists as two isotopes...Ch. 2 - Name and describe the composition of the three...Ch. 2 - Which of the following are isotopes of element X,...Ch. 2 - Thallium has two stable isotopes, 203TIand 205Tl....Ch. 2 - Strontium has four stable isotopes. Strontium-84...Ch. 2 - Verify that the atomic weight of lithium is 6.94,...Ch. 2 - Verify that the atomic weight of magnesium is...Ch. 2 - Gallium has two naturally occurring isotopes, 69Ga...Ch. 2 - Europium has two stable isotopes, 151Eu and 153Eu,...Ch. 2 - Titanium and thallium have symbols that are easily...Ch. 2 - In Groups 4A-6A, there are several elements whose...Ch. 2 - How many periods of the periodic table have 8...Ch. 2 - Prob. 28PSCh. 2 - Prob. 29PSCh. 2 - Prob. 30PSCh. 2 - Classify the following elements as metals,...Ch. 2 - Prob. 32PSCh. 2 - Prob. 33PSCh. 2 - Prob. 34PSCh. 2 - What is the charge on the common monatomic ions of...Ch. 2 - What is the charge on the common monatomic ions of...Ch. 2 - Prob. 37PSCh. 2 - Prob. 38PSCh. 2 - When a potassium atom becomes a monatomic ion, how...Ch. 2 - When oxygen and sulfur atoms become monatomic...Ch. 2 - Prob. 41PSCh. 2 - Prob. 42PSCh. 2 - Give the formula and the number of each ion that...Ch. 2 - Give the formula and the number of each ion that...Ch. 2 - Prob. 45PSCh. 2 - Prob. 46PSCh. 2 - Prob. 47PSCh. 2 - Prob. 48PSCh. 2 - Prob. 49PSCh. 2 - Prob. 50PSCh. 2 - Prob. 51PSCh. 2 - Prob. 52PSCh. 2 - Write the formulas for the four ionic compounds...Ch. 2 - Write the formulas for the four ionic compounds...Ch. 2 - Sodium ions, Na+, form ionic compounds with...Ch. 2 - Consider the two ionic compounds NaCl and CaO. In...Ch. 2 - Prob. 57PSCh. 2 - Name each of the following binary, nonionic...Ch. 2 - Prob. 59PSCh. 2 - Prob. 60PSCh. 2 - Calculate the mass, in grams, of each the...Ch. 2 - Calculate the mass, in grams, of each the...Ch. 2 - Calculate the amount (moles) represented by each...Ch. 2 - Calculate the amount (moles) represented by each...Ch. 2 - You are given 1.0-g samples of He, Fe, Li, Si, and...Ch. 2 - You are given 0.10-g samples of K, Mo, Cr, and Al....Ch. 2 - Analysis of a 10.0-g sample of apatite (a major...Ch. 2 - A semiconducting material is composed of 52 g of...Ch. 2 - Calculate the molar mass of each of the following...Ch. 2 - Calculate the molar mass of each of the following...Ch. 2 - Calculate the molar mass of each hydrated...Ch. 2 - Prob. 72PSCh. 2 - What mass is represented by 0.0255 mol of each of...Ch. 2 - Assume you have 0.123 mol of each of the following...Ch. 2 - Sulfur trioxide, SO3, is made industrially in...Ch. 2 - How many ammonium ions and how many sulfate ions...Ch. 2 - Acetaminophen, whose structure is drawn below, is...Ch. 2 - An Alka-Seltzer tablet contains 324 mg of aspirin...Ch. 2 - Calculate the mass percent of each element in the...Ch. 2 - Calculate the mass percent of each element in the...Ch. 2 - Calculate the mass percent of copper in CuS,...Ch. 2 - Calculate the mass percent of titanium in the...Ch. 2 - Succinic acid occurs in fungi and lichens. 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(a) What is the average mass of one...Ch. 2 - Prob. 102GQCh. 2 - Prob. 103GQCh. 2 - Identify two nonmetallic elements that have...Ch. 2 - Prob. 105GQCh. 2 - Prob. 106GQCh. 2 - Prob. 107GQCh. 2 - When a sample of phosphorus burns in air, the...Ch. 2 - Although carbon-12 is now used as the standard for...Ch. 2 - A reagent occasionally used in chemical synthesis...Ch. 2 - Prob. 111GQCh. 2 - Prob. 112GQCh. 2 - Which of the following compounds has the highest...Ch. 2 - Which of the following samples has the largest...Ch. 2 - The structure of one of the bases in DNA, adenine,...Ch. 2 - Prob. 116GQCh. 2 - A drop of water has a volume of about 0.050 mL....Ch. 2 - Capsaicin, the compound that gives the hot taste...Ch. 2 - Prob. 119GQCh. 2 - Write the molecular formula and calculate the...Ch. 2 - Malic acid, an organic acid found in apples,...Ch. 2 - Your doctor has diagnosed you as being anemicthat...Ch. 2 - A compound composed of iron and carbon monoxide,...Ch. 2 - Ma huang, an extract from the ephedra species of...Ch. 2 - Saccharin, a molecular model of which is shown...Ch. 2 - Prob. 126GQCh. 2 - Write the formula for each of the following pounds...Ch. 2 - Complete the table by placing symbols, formulas,...Ch. 2 - Empirical and molecular formulas. (a)...Ch. 2 - Cacodyl, a compound containing arsenic, was...Ch. 2 - The action of bacteria on meat and fish produces a...Ch. 2 - In the laboratory you combine 0.125 g of nickel...Ch. 2 - A compound called MMT was once used to boost the...Ch. 2 - Elemental phosphorus is made by heating calcium...Ch. 2 - Chromium is obtained by heating chromium(III)...Ch. 2 - Stibnite, Sb2S3, is a dark gray mineral from which...Ch. 2 - Direct reaction of iodine (I2) and chlorine (Cl2)...Ch. 2 - In a reaction, 2.04 g of vanadium combined with...Ch. 2 - Iron pyrite, often called fools gold, has the...Ch. 2 - Which of the following statements about 57.1 g of...Ch. 2 - The formula of barium molybdate is BaMoO4. 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(a) You are...Ch. 2 - A piece of nickel foil, 0.550 mm thick and 1.25 cm...Ch. 2 - Uranium is used as a fuel, primarily in the form...Ch. 2 - In an experiment, you need 0.125 mol of sodium...Ch. 2 - Mass spectrometric analysis showed that there are...Ch. 2 - The mass spectrum of CH3Cl is illustrated here....Ch. 2 - Prob. 156GQCh. 2 - If Epsom salt, MgSO4 x H2O, is heated to 250 C,...Ch. 2 - The alum used in cooking is potassium aluminum...Ch. 2 - Tin metal (Sn) and purple iodine (I2) combine to...Ch. 2 - When analyzed, an unknown compound gave these...Ch. 2 - Two general chemistry students working together in...Ch. 2 - To find the empirical formula of tin oxide, you...Ch. 2 - Prob. 163SCQCh. 2 - Prob. 164SCQCh. 2 - The photo here depicts what happens when a coil of...Ch. 2 - A jar contains some number of jelly beans. To find...
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