Atkins' Physical Chemistry
Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 19, Problem 19B.2ST
Interpretation Introduction

Interpretation:

The isosteric enthalpy of adsorption at this fractional coverage has to be calculated using the given data.

Concept Introduction:

Langmuir isotherm depends on α = kakd which actually depends on T, the relation of this T with ΔadH is as follows,

    (ln(αpo)T)θ = -ΔadHoR

Here, po is pressure, T is temperature; R is gas constant and ΔadHo is standard enthalpy of adsorption.

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