(a) Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn. Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

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Answer 1

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Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

Answer 2

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

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Answer 3

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

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Answer 4

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

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Answer 5

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

Answer 6

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Answer 7

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation: The four possible stereoisomers of threonine by using wedges and dashes are to be drawn.

Concept introduction: Isomers are the compounds with similar formula and different structures. Stereoisomers are a type of isomers in which arrangement of atoms differ in space. Or the compounds that have same molecular formula but they differ in the arrangement of atoms or groups in the space are known as stereoisomers.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure which corresponds to an amino acid with 2S,3R configuration at its two stereogenic centers is to be predicted.

Concept introduction: The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. Complete the circle in decreasing order of priority from 1→2→3. The configuration of the compound is R and S when circle rotates in clockwise and anticlockwise direction.

Answer 10

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Answer 12

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Problem 19.2 Give the structure corresponding to...Ch. 19 - Problem 19.3 Draw the structure corresponding to...Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Problem 19.6 Rank the following compounds in order...Ch. 19 - Problem 19.7 Explain how you could use IR...Ch. 19 - Prob. 19.8P Ch. 19 - Problem 19.9 How many tetrahedral stereogenic...Ch. 19 - Problem 19.10 What alcohol can be oxidized to each...

Solution Summary: The author illustrates the four possible stereoisomers of threonine by using wedges and dashes.

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