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(a)
To determine: The product of the given reaction.
Interpretation: The product of the given reaction is to be predicted.
Concept introduction: The reaction of acid chloride with strong reducing agent such as LiAlH4 to give product primary alcohol.
Acid chlorides are reactive derivative of
(b)
To determine: The product of the given reaction.
Interpretation: The product of the given reaction is to be predicted.
Concept introduction: The reaction of acid chloride with mild reducing agent LiAl(O−t−Bu)3 to give the
Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom
(c)
To determine: The product of the given reaction.
Interpretation: The product of the given reaction is to be predicted.
Concept introduction: The reaction of acid chloride with lithium dialkylcuprate to give the product as
Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom
(d)
To determine: The product of the given reaction.
Interpretation: The product of the given reaction is to be predicted.
Concept introduction: The reaction of acid chloride with excess organolithium reagent then followed by the hydrolysis to give product as tertiary alcohol.
Acid chlorides are reactive derivative of carboxylic acids in which acidic hydroxy group are replaced by a chlorine atom
(e)
To determine: The product of the given reaction.
Interpretation: The product of the given reaction is to be predicted.
Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.
Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.
(f)
To determine: The product of the given reaction.
Interpretation: The product of the given reaction is to be predicted.
Concept introduction: The reaction of ester with diisobutylaluminium hydride at dry ice temperature to give aldehyde as a product.
Cold diisobutylaluminium hydride usually does not reduce the aldehydes further.
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Chapter 18 Solutions
Organic Chemistry (9th Edition)
- Don't used hand raiting and don't used Ai solutionarrow_forward2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENTChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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