Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 18, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

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Chapter 18 Solutions

Essential Organic Chemistry, Global Edition

Ch. 18.7 - Prob. 11PCh. 18.8 - How many conjugated double bonds are there in a....Ch. 18.8 - Instead of adding to the 4a-position and...Ch. 18.8 - In succinate dehydrogenase, FAD is covalently...Ch. 18.8 - Prob. 15PCh. 18.9 - Acetolactate synthase is another TPP-requiring...Ch. 18.9 - Acetolactate synthase can also transfer the acyl...Ch. 18.9 - Prob. 18PCh. 18.9 - Prob. 19PCh. 18.10 - Prob. 21PCh. 18.11 - Prob. 23PCh. 18.11 - Which compound is more easily decarboxylated?Ch. 18.11 - Explain why the ability of PLP to catalyze an...Ch. 18.11 - Explain why the ability of PLP to catalyze an...Ch. 18.12 - What groups are interchanged in the following...Ch. 18.13 - Why is the coenzyme called tetrahydrofolate?Ch. 18.13 - What amino acid is formed by the following...Ch. 18.13 - How do the structures of tetrahydrofolate and...Ch. 18.13 - What is the source of the methyl group in...Ch. 18 - Prob. 32PCh. 18 - Prob. 33PCh. 18 - From what vitamins are the following coenzymes...Ch. 18 - Prob. 35PCh. 18 - For each of the following reaction, name both the...Ch. 18 - Explain why serine proteases do not catalyze...Ch. 18 - Prob. 38PCh. 18 - For each of the following enzyme catalyzed...Ch. 18 - Trisephosphate isomerase (TIM) catalyzes the...Ch. 18 - Prob. 41PCh. 18 - What acyl groups have we seen transferred by...Ch. 18 - When UMP is dissolved in T2O, exchange of T for H...Ch. 18 - Prob. 44PCh. 18 - When transaminated, the three branched-chain amino...Ch. 18 - Aldolase shows no activity if it is incubated with...
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