Chemistry: Principles and Practice
Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 18, Problem 18.80QE

The commercial production of magnesium is accomplished by electrolysis of molten MgCl2.

  1. (a) Why is electrolysis of an aqueous solution of MgCl2 not used in this process?
  2. (b) Write the anode and cathode half-reaction in the electrolysis of molten MgCl2.
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Magnesium is obtained by electrolysis of molten MgCl2. (a) Why is an aqueous solution of MgCl2 not used in the electrolysis?
(a) The half-reaction for formation of magnesium metal upon electrolysis molten MgCl2 is Mg2+ + 2e- Mg. Calculate the mass of magnesium formed upon passage of a current of 60.0 A for a period of 4.00 x 103 s. (b) How many seconds would be required to produce 50.0 g of Mg from MgCl2 if the current is 100.0 A?
A 0.100 M neutral aqueous CaCl2 solution is electrolyzed using platinum electrodes. A current of 1.50 A passes through the solution for 50.0 hours.(a) Write the half-reactions occurring at the anode and at the cathode.(b) What is the decomposition potential?(c) Calculate the mass, in grams, of the product formed at the cathode.

Chapter 18 Solutions

Chemistry: Principles and Practice

Ch. 18 - Assign the oxidation numbers of all atoms in the...Ch. 18 - Prob. 18.12QECh. 18 - Prob. 18.13QECh. 18 - Assign the oxidation numbers of all atoms in the...Ch. 18 - Prob. 18.15QECh. 18 - Prob. 18.16QECh. 18 - Prob. 18.17QECh. 18 - Prob. 18.18QECh. 18 - Prob. 18.19QECh. 18 - Prob. 18.20QECh. 18 - Prob. 18.21QECh. 18 - Prob. 18.22QECh. 18 - Prob. 18.23QECh. 18 - Prob. 18.24QECh. 18 - Complete and balance each half-reaction in acid...Ch. 18 - Prob. 18.26QECh. 18 - Prob. 18.27QECh. 18 - Prob. 18.28QECh. 18 - Prob. 18.29QECh. 18 - Balance each of the following redox reactions in...Ch. 18 - Prob. 18.31QECh. 18 - Prob. 18.32QECh. 18 - Prob. 18.33QECh. 18 - Prob. 18.34QECh. 18 - Prob. 18.35QECh. 18 - Prob. 18.36QECh. 18 - Prob. 18.37QECh. 18 - Prob. 18.38QECh. 18 - Prob. 18.39QECh. 18 - A voltaic cell is based on the reaction...Ch. 18 - For each of the reactions, calculate E from the...Ch. 18 - For each of the reactions, calculate E from the...Ch. 18 - Use the data from the table of standard reduction...Ch. 18 - Prob. 18.46QECh. 18 - Prob. 18.47QECh. 18 - The standard potential of the cell reaction...Ch. 18 - A half-cell that consists of a copper wire in a...Ch. 18 - Prob. 18.50QECh. 18 - Prob. 18.51QECh. 18 - Prob. 18.52QECh. 18 - Use the standard reduction potentials in Table...Ch. 18 - Use the standard reduction potentials in Table...Ch. 18 - Prob. 18.55QECh. 18 - Prob. 18.56QECh. 18 - Prob. 18.57QECh. 18 - Prob. 18.58QECh. 18 - Prob. 18.59QECh. 18 - Prob. 18.60QECh. 18 - Calculate the potential for each of the voltaic...Ch. 18 - Prob. 18.62QECh. 18 - Prob. 18.63QECh. 18 - Prob. 18.64QECh. 18 - Prob. 18.65QECh. 18 - Prob. 18.66QECh. 18 - Prob. 18.67QECh. 18 - Prob. 18.68QECh. 18 - What is the voltage of a concentration cell of...Ch. 18 - What is the voltage of a concentration cell of Cl...Ch. 18 - Prob. 18.71QECh. 18 - Prob. 18.72QECh. 18 - Prob. 18.73QECh. 18 - Prob. 18.74QECh. 18 - Prob. 18.75QECh. 18 - Prob. 18.76QECh. 18 - A solution contains the ions H+, Ag+, Pb2+, and...Ch. 18 - Prob. 18.78QECh. 18 - Prob. 18.79QECh. 18 - The commercial production of magnesium is...Ch. 18 - Prob. 18.81QECh. 18 - Prob. 18.82QECh. 18 - Find the mass of hydrogen produced by electrolysis...Ch. 18 - Prob. 18.84QECh. 18 - Prob. 18.85QECh. 18 - How long would it take to electroplate a metal...Ch. 18 - Prob. 18.87QECh. 18 - Prob. 18.88QECh. 18 - Prob. 18.89QECh. 18 - Prob. 18.90QECh. 18 - Prob. 18.91QECh. 18 - Prob. 18.92QECh. 18 - Prob. 18.93QECh. 18 - Use the standard reduction potentials in Appendix...Ch. 18 - Prob. 18.95QECh. 18 - Prob. 18.96QECh. 18 - Prob. 18.97QECh. 18 - Prob. 18.98QECh. 18 - Another type of battery is the alkaline...Ch. 18 - At 298 K, the solubility product constant for...Ch. 18 - At 298 K, the solubility product constant for...Ch. 18 - Prob. 18.103QECh. 18 - Prob. 18.104QECh. 18 - An electrolytic cell produces aluminum from Al2O3...Ch. 18 - Prob. 18.106QECh. 18 - Prob. 18.107QECh. 18 - At 298 K, the solubility product constant for...Ch. 18 - Prob. 18.109QE
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