Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
Question
Book Icon
Chapter 18, Problem 18.55E
Interpretation Introduction

(a)

Interpretation:

The equivalent force constant is to be calculated.

Concept introduction:

The Hook’s law states that the strain produced in a solid is directly proportional to the applied force on it. The classical harmonic oscillator shows repetitive motion. It follows the Hook’s law. The Hook’s law is given by,

F=Kx

Where,

F is the force.

K is the spring constant.

x is the deformation.

Interpretation Introduction

(b)

Interpretation:

The wavenumber of the light is to be calculated.

Concept introduction:

The relation between wavenumber and frequency is given by the formula,

ν=cv¯

Where,

c is the speed of light.

v¯ is the wavenumber.

ν is the frequency.

Interpretation Introduction

(c)

Interpretation:

Whether the answer of part b agrees with the generality that many solid materials are very good absorbers of low-energy infrared light is to be stated.

Concept introduction:

The relation between wavenumber and frequency is given by the formula,

ν=cv¯

Where,

c is the speed of light.

v¯ is the wavenumber.

ν is the frequency.

The relation between wavenumber and energy is given by the formula,

E=hcv¯

Where,

h is the planck’s constant.

Blurred answer
Students have asked these similar questions
3. ^14N^16O (the superscripts represent the atomic mass number)  (a) NO molecules rotate at an angular velocity of 2.01x10^12 rev/s, at the quantized rotational state with the rotational quantum number J of 3. Calculate the bond length of NO molecules. (b) Can NO molecules rotate under light irradiation? Explain your answer. (c) Calculate the effective force constant of the vibrational mode of NO at a frequency of 5.63x10^13 Hz measured by the infrared absorption spectrum. (d) NO has a bond energy of 6.29 eV. Applying the parabolic approximation to estimate the longest distance in which N and O atoms can be stretched before the dissociation of the molecular bond
6. The NaH molecule undergoes a rotational transition from J=0 to J=1 when it absorbs a photon of frequency 2.94×10' Hz. What is the equilibrium bond length of the molecule?
2. Molecules absorb IR radiation consistent with vibrational energy and rotational energy. Which of these is present in condensed phases (liquid, solution, solid)?
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY