Foundations of Materials Science and Engineering
Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Chapter 17.14, Problem 8KCP

What properties of biopolymers make them suitable for biomedical applications?

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( B ) A stress of 6.7 MPa is employed to one type of a polymer under constant strain . After 40 days at 20 ° C the stress is reduced to only 8.4 MPa . When the same polymer is heated to 40 ° C the relaxation time is 40 days . 1- Calculate the relaxation time constant for this material at 25 ° C ? 2- Estimate the stress after 50 days at 25 ° C ? 3- Estimate the stress relaxation activation energy for the same polymer .
For a given polymer, the activation energy for the stress relaxation was measured to be 59kj/mol. If the stress relaxation time for this polymer at 7 degree Celsius is 3150 seconds. What is the relaxation time at 110 degree Celsius
Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) are powerful tools for imaging the micro- and nano-structure of a material. (a) Which technique provides higher imaging resolution, SEM or TEM? (b) Why does this technique provide higher resolution? Describe your reasoning. (c) A polymer sample is mounted on a solid metal stub and coated with a conductive layer. Which electron microscopy technique is the sample prepared for? (d) Why do we need a conductive coating on the polymer sample? Explain in terms of both the material and the imaging technique. (e) What information could Energy Dispersive X-ray (EDX) spectroscopy tell us about the sample? (f) Atomic Force Microscopy (AFM) enables high resolution surface imaging and measuring surface properties of samples. Describe one way that this (stiffness mapping) procedure can be done?

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Foundations of Materials Science and Engineering

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