EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 8220100659461
Author: Bruice
Publisher: PEARSON
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Chapter 16.8, Problem 12P
Interpretation Introduction
Interpretation:
The products (in chair conformers formed), from the reaction of
Concept Introduction:
Glycoside formation: carbohydrates react with an alcohol in acid which produce both anomers acetals are formed, if alkoxy group points down then it is α, alkoxy group points up then it is β.
Sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as
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Draw the products formed when B-D-galactose reacts with ethanol and HCl.
Draw the products formed when β-D-galactose is treated with below reagent.
Ag2O + CH3I
Draw an open-chain tautomer of galactose that has an aldehyde group
Chapter 16 Solutions
EBK ESSENTIAL ORGANIC CHEMISTRY
Ch. 16.1 - Prob. 1PCh. 16.2 - Prob. 2PCh. 16.3 - Prob. 3PCh. 16.3 - Prob. 4PCh. 16.4 - Prob. 5PCh. 16.4 - Prob. 6PCh. 16.5 - Prob. 7PCh. 16.5 - Prob. 8PCh. 16.6 - Prob. 10PCh. 16.8 - Prob. 12P
Ch. 16.8 - Prob. 14PCh. 16.9 - Prob. 15PCh. 16.10 - Prob. 16PCh. 16.11 - Refer to Figure 16.4 to answer the following...Ch. 16 - Prob. 18PCh. 16 - Prob. 19PCh. 16 - Prob. 20PCh. 16 - Prob. 21PCh. 16 - Prob. 22PCh. 16 - Prob. 23PCh. 16 - Prob. 24PCh. 16 - Prob. 25PCh. 16 - Name the following compounds:Ch. 16 - Prob. 28PCh. 16 - Prob. 29PCh. 16 - Prob. 31PCh. 16 - Prob. 32PCh. 16 - Prob. 33PCh. 16 - Prob. 34PCh. 16 - Prob. 35PCh. 16 - Prob. 36PCh. 16 - Prob. 37PCh. 16 - Draw the mechanism for the acid-catalyzed...Ch. 16 - Prob. 39PCh. 16 - Prob. 40PCh. 16 - Prob. 41P
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- What product or products are obtained when d-galactose reacts with the following? nitric acid + Δarrow_forwardWhat product or products are obtained when d-galactose reacts with the following? Br2 in waterarrow_forwardDraw the products formed when b-d-galactose reacts with ethanol and HCl. (Show all structures aschair conformers.)arrow_forward
- + Mannose is a monosaccharide involved in the glycosylation of certain proteins. Several genetic disorders are associated with enzymes involved in mannose metabolism. Monosaccharides form a new functional group when the straight chain sugar cyclizes. What is the type of functional group formed in mannose after it undergoes cyclization to form the furanose ring? HO OH OH 0- OH OH A) aldehyde B) ketone C) hemi-acetal D) ether E) esterarrow_forwardWhat product or products are obtained when d-galactose reacts with the following? Ag+, NH3, HO-arrow_forwardWhat product or products are obtained when d-galactose reacts with the following? NaBH4, followed by H3O+arrow_forward
- product formed by reaction of D-Galactose with:Tollens’ reagentarrow_forwardIn an aqueous solution, d-glucose exists in equilibrium with two six-membered ring compounds. Draw the structures of these compounds.arrow_forwardWhich of the following will produce both glucose and galactose when it is hydrolyzed? a) Sucrose b) maltose c) lactose d) amylosearrow_forward
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