Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Textbook Question
Chapter 16, Problem 16.159MP
In qualitative analysis, Ca2+ and Ba2+ are separated from Na+ , K+ , and Mg2+ by adding aqueous (NH4)2CO3 to a solution that also contains aqueous NH3 (Figure 16.18). Assume that the concentrations after mixing are 0.080 M (NH4)2CO3 and 0.16 M NH3 .
(a) List all the Bronsted—Lowry acids and bases present initially, and identify the principal reaction.
(b) Calculate the pH and the concentrations of all species present in the solution.
(c) In order for the human eye to detect the appearance of a precipitate, a very large number of ions must come together to form solid particles. For this and other reasons, the ion product must often exceed Ksp by a factor of about 103 before a precipitate can be detected in a typical qualitative analysis experiment. Taking this fact into account, show quantitatively that the CO32- concentration is large enough to give observable precipitation of CaCO3 and BaCO3 but not MgCO3 . Assume that the metal-ion concentrations are 0.010 M.
(d) Show quantitatively which of the Mg2+ , Ca2+ , and Ba2+ ions, if any, should give an observable precipitate of the metal hydroxide.
(e) Could the separation of Ca2+ and Ba2+ from Mg2+ be accomplished using 0.80 M Na2CO3 in place of 0.080 M (NH4)2CO3 ? Show quantitatively why or why not.
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Chapter 16 Solutions
Chemistry (7th Edition)
Ch. 16 - Prob. 16.1PCh. 16 - APPLY 16.2 Write balanced net ionic equations for...Ch. 16 - PRACTICE 16.3 Calculate the concentrations of all...Ch. 16 - APPLY 16.4 Calculate the pH of a solution prepared...Ch. 16 - Conceptual PRACTICE 16.5 The following pictures...Ch. 16 - Conceptual APPLY 16.6 The following pictures...Ch. 16 - Prob. 16.7PCh. 16 - Prob. 16.8ACh. 16 - Prob. 16.9PCh. 16 - PRACTICE 16.10 Use the Henderson-Hasselbalch...
Ch. 16 - APPLY 16.11 The of the amine group of the amino...Ch. 16 - PRACTICE 16.12 How would you prepare anbuffer...Ch. 16 - APPLY 16.13 Suppose you are performing an...Ch. 16 - Prob. 16.14PCh. 16 - APPLY 16.15 A 40.0 mL volume of 0.100 M NaOH is...Ch. 16 - Prob. 16.16PCh. 16 - Prob. 16.17ACh. 16 - Prob. 16.18PCh. 16 - Prob. 16.19ACh. 16 - PRACTICE 16.20 Write the equilibrium-constant...Ch. 16 - Prob. 16.21ACh. 16 - Prob. 16.22PCh. 16 - Prob. 16.23ACh. 16 - Prob. 16.24PCh. 16 - Prob. 16.25ACh. 16 - Prob. 16.26PCh. 16 - Prob. 16.27ACh. 16 - Prob. 16.28PCh. 16 - Prob. 16.29PCh. 16 - Prob. 16.30ACh. 16 - Prob. 16.31PCh. 16 - Prob. 16.32ACh. 16 - Prob. 16.33PCh. 16 - Prob. 16.34ACh. 16 - PROBLEM 16.35 Determine whether Cd2+ can be...Ch. 16 - Prob. 16.36PCh. 16 - Prob. 16.37PCh. 16 - Prob. 16.38PCh. 16 - Prob. 16.39PCh. 16 - Prob. 16.40CPCh. 16 - The following pictures represent initial...Ch. 16 - Prob. 16.42CPCh. 16 - The following pictures represent solutions at...Ch. 16 - The following pictures represent solutions at...Ch. 16 - Prob. 16.45CPCh. 16 - Prob. 16.46CPCh. 16 - Prob. 16.47CPCh. 16 - Prob. 16.48CPCh. 16 - Prob. 16.49CPCh. 16 - 16.50 Is the pH greater than, equal to, or less...Ch. 16 - Is the pH greater than, equal to, or less than 7...Ch. 16 - Prob. 16.52SPCh. 16 - Prob. 16.53SPCh. 16 - Prob. 16.54SPCh. 16 - Prob. 16.55SPCh. 16 - 16.56 The equilibrium constant for the...Ch. 16 - 16.57 The equilibrium constant for the...Ch. 16 - 16.58 Does the pH increase, decrease, or remain...Ch. 16 - 16.59 Does the pH increase, decrease, or remain...Ch. 16 - 16.60 Calculate the pH of a solution that is 0.25...Ch. 16 - Prob. 16.61SPCh. 16 - Prob. 16.62SPCh. 16 - The pH of a solution of NH3 and NH4Br is 8.90....Ch. 16 - Prob. 16.64SPCh. 16 - Prob. 16.65SPCh. 16 - Prob. 16.66SPCh. 16 - Which of the following gives a buffer solution...Ch. 16 - Prob. 16.68SPCh. 16 - Prob. 16.69SPCh. 16 - Prob. 16.70SPCh. 16 - Prob. 16.71SPCh. 16 - Prob. 16.72SPCh. 16 - Calculate the pH of 0.375 L of a 0.18 M acetic...Ch. 16 - Prob. 16.74SPCh. 16 - Prob. 16.75SPCh. 16 - Prob. 16.76SPCh. 16 - Prob. 16.77SPCh. 16 - Prob. 16.78SPCh. 16 - Prob. 16.79SPCh. 16 - Prob. 16.80SPCh. 16 - Prob. 16.81SPCh. 16 - Prob. 16.82SPCh. 16 - Prob. 16.83SPCh. 16 - Prob. 16.84SPCh. 16 - Prob. 16.85SPCh. 16 - Prob. 16.86SPCh. 16 - Prob. 16.87SPCh. 16 - Prob. 16.88SPCh. 16 - Prob. 16.89SPCh. 16 - Prob. 16.90SPCh. 16 - Prob. 16.91SPCh. 16 - Prob. 16.92SPCh. 16 - Prob. 16.93SPCh. 16 - Prob. 16.94SPCh. 16 - Prob. 16.95SPCh. 16 - Prob. 16.96SPCh. 16 - 16.97 What is the pH at the equivalence point for...Ch. 16 - Prob. 16.98SPCh. 16 - Prob. 16.99SPCh. 16 - Prob. 16.100SPCh. 16 - Prob. 16.101SPCh. 16 - Prob. 16.102SPCh. 16 - Prob. 16.103SPCh. 16 - Prob. 16.104SPCh. 16 - Prob. 16.105SPCh. 16 - Prob. 16.106SPCh. 16 - Prob. 16.107SPCh. 16 - Use Le Châtelier’s principle to explain the...Ch. 16 - Use Le Châtelier’s principle to predict whether...Ch. 16 - Calculate the molar solubility of PbCrO4 in: (a)...Ch. 16 - Prob. 16.111SPCh. 16 - Prob. 16.112SPCh. 16 - Prob. 16.113SPCh. 16 - Prob. 16.114SPCh. 16 - Prob. 16.115SPCh. 16 - Prob. 16.116SPCh. 16 - Dissolution of 5.010-3 mol of CrOH3 in 1.0L of...Ch. 16 - Prob. 16.118SPCh. 16 - Prob. 16.119SPCh. 16 - Prob. 16.120SPCh. 16 - Prob. 16.121SPCh. 16 - Prob. 16.122SPCh. 16 - Prob. 16.123SPCh. 16 - Prob. 16.124SPCh. 16 - Prob. 16.125SPCh. 16 - Prob. 16.126SPCh. 16 - Prob. 16.127SPCh. 16 - Prob. 16.128SPCh. 16 - Prob. 16.129SPCh. 16 - Prob. 16.130SPCh. 16 - Prob. 16.131SPCh. 16 - Prob. 16.132CPCh. 16 - Prob. 16.133CPCh. 16 - Prob. 16.134CPCh. 16 - Prob. 16.135CPCh. 16 - Prob. 16.136CPCh. 16 - Prob. 16.137CPCh. 16 - Prob. 16.138CPCh. 16 - Prob. 16.139CPCh. 16 - Prob. 16.140CPCh. 16 - Prob. 16.141CPCh. 16 - Prob. 16.142CPCh. 16 - Prob. 16.143CPCh. 16 - Prob. 16.144CPCh. 16 - Prob. 16.145CPCh. 16 - Prob. 16.146CPCh. 16 - The acidity of lemon juice is derived primarily...Ch. 16 - Prob. 16.148CPCh. 16 - Prob. 16.149CPCh. 16 - Prob. 16.150CPCh. 16 - Prob. 16.151CPCh. 16 - Prob. 16.152MPCh. 16 - Prob. 16.153MPCh. 16 - Prob. 16.154MPCh. 16 - Prob. 16.155MPCh. 16 - Prob. 16.156MPCh. 16 - Prob. 16.157MPCh. 16 - Prob. 16.158MPCh. 16 - In qualitative analysis, Ca2+ and Ba2+ are...Ch. 16 - Prob. 16.160MPCh. 16 - Prob. 16.161MP
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