Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 15.2, Problem 6P
List the following groups of monomers in order from most able to least able to undergo anionic
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Rank the following groups of monomers from most able to least able to undergo cationic polymerization:
Rank the following groups of monomers from most able to least able to undergo anionic polymerization:
When certain cycloalkenes are used in metathesis reactions, ringopening metathesis polymerization (ROMP) occurs to form a highmolecular- weight polymer, as shown with cyclopentene as the starting material. The reaction is driven to completion by relief of strain in the cycloalkene.What products are formed by ring-opening metathesis polymerization of each alkene?
Chapter 15 Solutions
Essential Organic Chemistry, Global Edition
Ch. 15.2 - Prob. 1PCh. 15.2 - Prob. 2PCh. 15.2 - Prob. 3PCh. 15.2 - Prob. 4PCh. 15.2 - List the following groups of monomers in order...Ch. 15.2 - List the following groups of monomers in order...Ch. 15.2 - Prob. 7PCh. 15.2 - Why does methyl methacrylate not undergo cationic...Ch. 15.2 - Which monomer and which type of initiator would...Ch. 15.2 - Prob. 10P
Ch. 15.2 - Prob. 11PCh. 15.5 - Draw a short segment of gutta-percha.Ch. 15.5 - Prob. 13PCh. 15.6 - Prob. 14PCh. 15.8 - Prob. 15PCh. 15.8 - Prob. 16PCh. 15.8 - Prob. 17PCh. 15.8 - a. Propose a mechanism for the formation of the...Ch. 15.8 - Propose a mechanism for the formation of Melmac.Ch. 15.8 - Explain why, when a small amount of glycerol is...Ch. 15.10 - Prob. 21PCh. 15 - Draw short segments of the polymers obtained from...Ch. 15 - Prob. 23PCh. 15 - Draw the structure of the monomer or monomers used...Ch. 15 - Draw short segments of the polymers obtained from...Ch. 15 - Prob. 26PCh. 15 - Prob. 27PCh. 15 - Prob. 28PCh. 15 - A particularly strong and rigid polyester used for...Ch. 15 - Prob. 30PCh. 15 - Prob. 31PCh. 15 - Prob. 32PCh. 15 - Prob. 33PCh. 15 - Prob. 34PCh. 15 - Prob. 35PCh. 15 - Delrin (polyoxymethylene) is a tough...
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- Explain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forwardA3 Anionic polymerization of styrene is generally known to produce polymers with a narrow molecular weight distribution. Explain the reason for this.arrow_forwardNH2 Dry-erase boards, or whiteboards, in classrooms consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. (a) Propose a structure for the polymer formed. (b) Why is this type of polymer suitable for use in whiteboards? 'N. H2N `NH2 Melaminearrow_forward
- 4.2) Draw the structure of the polymer produced in the following reaction. H₂N NH₂ Karrow_forwardDraw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.arrow_forwardWhat product is obtained from ring-opening metathesis polymerization of each of the following compounds? (Hint: In each case, the product is an unsaturated hydrocarbon with a high molecular weight.)arrow_forward
- One common type of cation exchange resin is prepared by polymerization of a mixture containing styrene and 1,4-divinylbenzene . The polymer is then treated with concentrated sulfuric acid to sulfonate a majority of the aromatic rings in the polymer. Q.) Show the product of sulfonation of each benzene ring.arrow_forwardSynthesize attached compound from toluene (C6H5CH3) and any other organic or inorganic reagents.arrow_forwardWhich reaction—dehydration synthesis or hydrolysis—converts a polymer to its monomers? Which one convertsmonomers to a polymer? Explain your answerarrow_forward
- (d) Another variation on this type of polymer is used in hair gels. In these, the polymer chains are cross-linked by a compound known as pentaerythritol. но- OH но- OH pentaerythritol ( By what type of chemicat reaction are the cross-links in this polymer formed? (i) it is important that the gel should be easily washed out of hair What is it about the structure of the polymer that allows this to happen?arrow_forward4. Which polymer in each of the following pairs would you expect to exhibit the higher glass transition temperature? Explain your choice in each case. 7. Which polymer each of the following pairs would you expect to exhibit the nigner glass transiti temperature? Explain your choice in each case. (a) CH₂CH or CH₂CH to occul] « toalemond] (b) or (c) -CH₂CH₂NH or CH₂CH₂O- 604-604 or (d) (e) +c- -COCH₂CH₂O- CH₂CH₂CH, - flor loreman of CH(CH₂)₂arrow_forwardStyrene derivatives such as A can be polymerized by way of cationic rather than radical intermediates. Cationic polymerization is an example of electrophilic addition to an alkene involving carbocations. a.) Draw a short segment of the polymer formed by the polymerization ofA.b.) Why does A react faster than styrene (C6H5CH=CH2) in a cationicpolymerization?arrow_forward
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