Organic Chemistry, Books a la Carte Edition (8th Edition)
Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
Question
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Chapter 15, Problem 57P

(a)

Interpretation Introduction

Interpretation:

To suggest two methods one starting with an alcohol and one starting with alkyl halide for each of the given ester formations.

Concept introduction:

Esters can be prepared from the reaction of an alcohol with carboxylic acid. The general reaction between acid and alcohol can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  1

The oxygen atom in the ester is the oxygen atom that is initially present in the alcohol.

The reaction of an alkyl halide with the sodium salt of carboxylic acid can also be used to prepare esters. The general reaction between an alkyl halide and the sodium salt of carboxylic acid can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

To suggest two methods one starting with an alcohol and one starting with alkyl halide for each of the given ester formations.

Concept introduction:

Esters can be prepared from the reaction of an alcohol with carboxylic acid. The general reaction between acid and alcohol can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  3

The oxygen atom in the ester is the oxygen atom that is initially present in the alcohol.

The reaction of an alkyl halide with the sodium salt of carboxylic acid can also be used to prepare esters. The general reaction between an alkyl halide and the sodium salt of carboxylic acid can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

To suggest two methods one starting with an alcohol and one starting with alkyl halide for each of the given ester formations.

Concept introduction:

Esters can be prepared from the reaction of an alcohol with carboxylic acid. The general reaction between acid and alcohol can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  5

The oxygen atom in the ester is the oxygen atom that is initially present in the alcohol.

The reaction of an alkyl halide with the sodium salt of carboxylic acid can also be used to prepare esters. The general reaction between an alkyl halide and the sodium salt of carboxylic acid can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

To suggest two methods one starting with an alcohol and one starting with alkyl halide for each of the given ester formations.

Concept introduction:

Esters can be prepared from the reaction of an alcohol with carboxylic acid. The general reaction between acid and alcohol can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  7

The oxygen atom in the ester is the oxygen atom that is initially present in the alcohol.

The reaction of an alkyl halide with the sodium salt of carboxylic acid can also be used to prepare esters. The general reaction between an alkyl halide and the sodium salt of carboxylic acid can be given as,

Organic Chemistry, Books a la Carte Edition (8th Edition), Chapter 15, Problem 57P , additional homework tip  8

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Chapter 15 Solutions

Organic Chemistry, Books a la Carte Edition (8th Edition)

Ch. 15.5 - Is the following statement true or false? If the...Ch. 15.6 - Starting with acetyl chloride, what neutral...Ch. 15.6 - Prob. 13PCh. 15.7 - Starting with methyl acetate, what neutral...Ch. 15.7 - We saw that it is necessary to use excess amine in...Ch. 15.7 - Prob. 17PCh. 15.7 - Which ester hydrolyzes more rapidly? a. methyl...Ch. 15.7 - a. state three factors that cause the uncatalyzed...Ch. 15.8 - Prob. 21PCh. 15.8 - Using the mechanism for the acid-catalyzed...Ch. 15.8 - Prob. 23PCh. 15.8 - Show the mechanism for the acid-catalyzed...Ch. 15.8 - Prob. 25PCh. 15.8 - Write the mechanism for the acid-catalyzed...Ch. 15.8 - Write the mechanism for the acid-catalyzed...Ch. 15.9 - Prob. 28PCh. 15.9 - Prob. 29PCh. 15.10 - Show how each of the following esters could he...Ch. 15.10 - Prob. 32PCh. 15.11 - Prob. 33PCh. 15.11 - Which of the following reactions leads to the...Ch. 15.12 - Prob. 35PCh. 15.12 - Prob. 36PCh. 15.13 - Prob. 37PCh. 15.14 - Prob. 38PCh. 15.14 - Prob. 39PCh. 15.15 - Prob. 40PCh. 15.15 - Which alkyl halides from the carboxylic acids...Ch. 15.16 - Prob. 43PCh. 15.16 - Prob. 44PCh. 15.16 - Prob. 45PCh. 15.17 - Prob. 46PCh. 15.18 - How could you synthesize the following compounds...Ch. 15 - Prob. 48PCh. 15 - Name the following:Ch. 15 - Prob. 50PCh. 15 - What compound are obtained from the fallowing...Ch. 15 - a. Rank the following esters in order of...Ch. 15 - Because bromocyclohexane is a secondary alkyl...Ch. 15 - a. Which compound would you expect to have a...Ch. 15 - How could you use 1H NMR spectroscopy to...Ch. 15 - Rank the following compounds in order of...Ch. 15 - Prob. 57PCh. 15 - Prob. 58PCh. 15 - Prob. 59PCh. 15 - A compound with molecular formula C5H10O2 gives...Ch. 15 - Prob. 61PCh. 15 - Prob. 62PCh. 15 - Prob. 63PCh. 15 - Prob. 64PCh. 15 - Prob. 65PCh. 15 - Prob. 66PCh. 15 - Two products, A and B, are obtained from the...Ch. 15 - Prob. 68PCh. 15 - Prob. 69PCh. 15 - Prob. 70PCh. 15 - Prob. 71PCh. 15 - Prob. 72PCh. 15 - When treated with an equivalent of methanol,...Ch. 15 - a. Identify the two products obtained from the...Ch. 15 - Prob. 75PCh. 15 - Prob. 76PCh. 15 - a. When a carboxylic acid is dissolved in...Ch. 15 - Prob. 78PCh. 15 - Identity the major and minor products of the...Ch. 15 - When a compound with molecular formula C11H14O2...Ch. 15 - Prob. 81PCh. 15 - Prob. 82PCh. 15 - Prob. 83PCh. 15 - The 1H NMR spectra for two esters with molecular...Ch. 15 - Show how the following compounds could be prepared...Ch. 15 - Prob. 86PCh. 15 - Prob. 87PCh. 15 - The intermediate shown here is formed during the...Ch. 15 - Prob. 89PCh. 15 - Propose a mechanism that accounts for the...Ch. 15 - Catalytic antibodies catalyze a reaction by...Ch. 15 - Prob. 92P
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