Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 15, Problem 15.13P

Consider a binary system of species 1 and 2 in which the liquid phase exhibits partial miscibility. In the regions of miscibility, the excess Gibbs energy at a particular temperature is expressed by the equation:

G E / R T = 2.25 x 1 x 2

In addition, the vapor pressures of the pure species are:

P 1 s a t = 75 k P a and P 2 s a t = 110 k P a

Making the usual assumptions for low-pressure VLE, prepare a Pxy diagram for this system at the given temperature.

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Introduction to Chemical Engineering Thermodynamics

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