General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 15, Problem 15.11P
Interpretation Introduction

Interpretation:

The molar enthalpy of fusion of solid  NaCl has to be determined.

Concept Introduction:

Molar enthalpy for a process is the quantity of heat energy needed by one mole of a substance to undergo change in the process. The heat energy absorbed by n mole of substance to undergo change is as follows:

  q=n(ΔH)

Here,

q is the heat energy in kJ

n is the number of moles of substance.

ΔH is the enthalpy for process in kJ/mol .

The value of ΔH is positive always as energy is needed to overcome the interactions between the liquid molecules.

The formula to calculate the time required to transfer heat energy is as follows:

  time=heatenergyheating rate

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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