Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 14.5, Problem 10TY
Interpretation Introduction

Interpretation:

The formation constant and E0 of the given reaction has to be calculated.

Cu++2ethylenediamineCu(ethylenediamine)2+

Concept Introduction:

Cell Voltage:

Cell voltage is the difference between cathode potential and anode potential.

Ecell=E+-E-

Nernst equation:

In electrochemistry, the standard reduction potentials are related with the temperature and gas constant and standard electrode potentials and concentrations.

Ecell=E0cell-RTnFlog[cathode]n[anode]n

Solubility constant:

The general form of a problem where the problem has the relation between E0 values for half reactions is,

K=10nE0/0.05916

Where,

K = solubility constant

n = no of electrons.

E0 =cell potential

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Chapter 14 Solutions

Quantitative Chemical Analysis

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