Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 14, Problem 71P
Phenolphthalein is an acid-base indicator. In solutions of pH < 8.5, it is colorless in solutions of pH > 8.5, it is deep red-purple. Account for the change in color.
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3. 40.00 mL of 0.0900 M NaOH is diluted to 100mL and titrated with 0.1000M HCI. Calculate the
pH after the addition of the following volumes of titrant (mL); (a) 0.00; (b) 10.00 ; (c) 18.00:
(d) 30.00 ; (e) 35.95 ; (f) 36.00 (g) 36.05 ; (h) 40.00.
3. Complete neutralization of 10 ml of phosphoric acid solution by NaOH 0.I N in the presence of
phenol phthalein until the appearance of purple color (pH, = 9) 11 ml. of NaOH is consumed. (a)
What is the concentration of phosphoric acid? (b) Calculate the indicator error.
pk2.1
pK. - 7.2 pK - 124
Phenolphthalein is an acid–base indicator. In solutions of pH 6 8.5, it is colorless; in solutions of pH 7 8.5, it is deep red-purple. Account for thechange in color.
Chapter 14 Solutions
Organic Chemistry
Ch. 14.1 - Which of the following fragments produced in a...Ch. 14.2 - What distinguishes the mass spectrum of...Ch. 14.2 - What is the most likely m/z value for the base...Ch. 14.3 - Prob. 5PCh. 14.3 - If a compound has a molecular ion with an...Ch. 14.3 - a. Suggest possible molecular formulas for a...Ch. 14.3 - Identify the hydrocarbon that has a molecular ion...Ch. 14.4 - Predict the relative intensities of the molecular...Ch. 14.5 - Which molecular formula has an exact molecular...Ch. 14.5 - Prob. 11P
Ch. 14.6 - Sketch the mass spectrum expected for...Ch. 14.6 - The mass spectra of 1-methoxybutane,...Ch. 14.6 - Prob. 14PCh. 14.6 - Identify the ketones responsible for the mass...Ch. 14.6 - Prob. 16PCh. 14.6 - Using curved arrows, show the principal fragments...Ch. 14.6 - The reaction of (Z)-2-pentene with water and a...Ch. 14.9 - Prob. 19PCh. 14.9 - Prob. 20PCh. 14.9 - Prob. 21PCh. 14.13 - Prob. 22PCh. 14.14 - Which occur at a larger wavenumber: a. the C O...Ch. 14.14 - Prob. 24PCh. 14.14 - Prob. 25PCh. 14.14 - Rank the following compounds from highest...Ch. 14.14 - Which shows an O H stretch at a larger...Ch. 14.15 - Prob. 28PCh. 14.15 - a. An oxygen-containing compound shows an...Ch. 14.15 - Prob. 30PCh. 14.15 - For each of the following pair of compounds, name...Ch. 14.16 - Which of the following compounds has a vibration...Ch. 14.16 - Prob. 33PCh. 14.17 - A compound with molecular formula C4H6O gives the...Ch. 14.19 - Prob. 35PCh. 14.19 - Prob. 36PCh. 14.20 - Predict the max of the following compound:Ch. 14.20 - Prob. 38PCh. 14.21 - a. At pH = 7 one of the ions shown here is purple...Ch. 14.21 - Prob. 40PCh. 14.22 - Prob. 41PCh. 14.22 - Prob. 42PCh. 14 - In the mass spectrum of the following compounds,...Ch. 14 - Prob. 44PCh. 14 - For each of the following pairs of compounds,...Ch. 14 - Draw structures for a saturated hydrocarbon that...Ch. 14 - a. How could you use IR spectroscopy to determine...Ch. 14 - Assuming that the force constant is approximately...Ch. 14 - In the following boxes, list the types of bonds...Ch. 14 - A mass spectrum shows significant peaks at m/z. =...Ch. 14 - Prob. 51PCh. 14 - Prob. 52PCh. 14 - Prob. 53PCh. 14 - How can you use UV spectroscopy to distinguish...Ch. 14 - Rank the following compounds from highest...Ch. 14 - Rank the following compounds from highest...Ch. 14 - What peaks in their mass spectra can be used to...Ch. 14 - Each of the IR spectra shown below is accompanied...Ch. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - How can IR spectroscopy distinguish between...Ch. 14 - 62. Draw the structure of a carboxylic acid that...Ch. 14 - Prob. 63PCh. 14 - Give approximate wavenumbers for the major...Ch. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - The IR spectrum of a compound with molecular...Ch. 14 - Which one of the following live compounds produced...Ch. 14 - Prob. 70PCh. 14 - Phenolphthalein is an acid-base indicator. In...Ch. 14 - Which one of the following five compounds produced...Ch. 14 - The IR and mass spectra for three different...
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- The value of Ksp for Mg3(AsO4)2 is 2.1 x 10-20. TheAsO43 - ion is derived from the weak acid H3AsO4 (pKa1 =2.22; pKa2 = 6.98; pKa3 = 11.50). (a) Calculate the molarsolubility of Mg3(AsO4)2 in water. (b) Calculate the pH of asaturated solution of Mg3(AsO4)2 in water.arrow_forward5.) What is K, for an acid whose pK, is 3.78?arrow_forwardThe indicator phenolphthalein may be regarded as a weak monobasic acid. Explain briefly why the indicator is coloured pink when the solution in which it is present has excess of alkali.arrow_forward
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