Whether the given compound will have a significant dipole moment is to be determined. If so, the direction of the dipole moment is to be determined. Concept introduction: If two rings are with conjugated double bonds and are joined by a double bond, it is possible that one or both may achieve aromatic stabilization if the π electron pair of the double bond in the middle moves to one carbon. The resulting charge separation will make the molecule polar. Additionally, the delocalization of the charge due to the aromatic character of the ring(s) will increase the separation between charges, giving the molecule a substantial dipole moment. The direction of a molecular dipole is from the atom or region with a positive charge toward the atom or region with a negative charge.

Question

Want to see the full answer?

Answer 1

Question

Chapter 14, Problem 14.54P

Interpretation Introduction

Interpretation:

Whether the given compound will have a significant dipole moment is to be determined. If so, the direction of the dipole moment is to be determined.

Concept introduction:

If two rings are with conjugated double bonds and are joined by a double bond, it is possible that one or both may achieve aromatic stabilization if the π electron pair of the double bond in the middle moves to one carbon.

The resulting charge separation will make the molecule polar. Additionally, the delocalization of the charge due to the aromatic character of the ring(s) will increase the separation between charges, giving the molecule a substantial dipole moment.

The direction of a molecular dipole is from the atom or region with a positive charge toward the atom or region with a negative charge.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

b) Draw the most important (most stable) resonance structures for the compound below. With the help of the resonance structures, explain which of the two nitrogen atoms is more basic.

Question (Organic Chemistry) Consider molecules A–D. Does the arrow pushing in each structure leadto an acceptable resonance form? If so, explain why it is acceptable or unacceptable? What are the rules and logic? If so, draw it and carefully explain your answer and provide explanations for why each structure leds to an acceptable or unacceptable resonance form. Why is the arrow pushing acceptable or unacceptable in each individual case? Explain you answer with many details, logic, and in a step-by-step fashion.

Current Attempt in Progress For the given cation, draw all significant resonance forms and rank them from most significant to least significant. Briefly explain the rankings. Part 1 Ⓒ H Because this is a charged species, let's focus on resonance patterns that can delocalize the charge. First, add curved arrow(s) to show the resonance using the following pattern: a lone pair next to a carbocation. Modify the second structure given to draw the new resonance structure. Include relevant formal charges in your structure. Use the + and tools to add/remove charges to an atom, and use the single bond tool to add/remove double bonds. Part 2 Edit Drawing eTextbook and Media Save for Later Attempts: 0 of 3 used Submit Answer