ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 1.3, Problem 1.2E
Interpretation Introduction
Interpretation:The electron-dot pictures for ionic compound LiBr, Na2O, BeF2, AlCl3 and MgS should be drawn.
Concept introduction:The formation of ion takes place either by lose of electron(s) to make cations or by addition of electron(s) to make anions. Generally, the addition or loss of electron(s) takes place in an atom to have eight electrons in their valence shell said to be octet rule.
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4. The common oxidation number for an alkaline earth metal is +2.
(a) Using the Born-Mayer equation (for determining the lattice enthalpy) and a Born-Haber
cycle (draw it), show that CaCl is an exothermic compound (negative AHf). Make a
reasonable prediction to estimate the ionic radius of Ca (explain your reasoning). The
sublimation (atomization) enthalpy for Ca(s) is 178 kJ/mol.
(b) Show that an explanation for the non-existence of CaCl can be found in the enthalpy
change for the reaction below. The AHf for CaCl2(s) is -190.2 kcal/mol.
2 CaCl(s) → Ca(s) + CaCl2(s)
Write the chemical formula for manganese(V) hydrogen carbonate
Estimate the ionic radius of Cs+. The lattice energy of CsCl is 633 kJ/mol. For CsCl the Madelungconstant, M, is 1.763, and the Born exponent, n, is 10.7. The ionic radius of Cl– is known to be 1.81 Å
Chapter 1 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
Ch. 1.3 - Prob. 1.1ECh. 1.3 - Prob. 1.2ECh. 1.3 - Prob. 1.3ECh. 1.3 - Prob. 1.4ECh. 1.3 - Prob. 1.5ECh. 1.4 - Prob. 1.6ECh. 1.4 - Prob. 1.8TIYCh. 1.5 - Prob. 1.9ECh. 1.5 - Prob. 1.11TIYCh. 1.6 - Prob. 1.12E
Ch. 1.6 - Prob. 1.13ECh. 1.7 - Prob. 1.15TIYCh. 1.8 - Prob. 1.16ECh. 1.8 - Prob. 1.18TIYCh. 1.9 - Prob. 1.19ECh. 1.9 - Prob. 1.20ECh. 1.9 - Prob. 1.21ECh. 1.9 - Prob. 1.22ECh. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Prob. 27PCh. 1 - Prob. 28PCh. 1 - Prob. 29PCh. 1 - Prob. 30PCh. 1 - Prob. 31PCh. 1 - Prob. 32PCh. 1 - Prob. 33PCh. 1 - Prob. 34PCh. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - Prob. 37PCh. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Prob. 44PCh. 1 - Prob. 45PCh. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - Prob. 50PCh. 1 - Prob. 51PCh. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Prob. 55PCh. 1 - Prob. 56PCh. 1 - Prob. 57PCh. 1 - Prob. 58P
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