Thermodynamics: An Engineering Approach
9th Edition
ISBN: 9781259822674
Author: Yunus A. Cengel Dr., Michael A. Boles
Publisher: McGraw-Hill Education
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Chapter 12.6, Problem 18P
To determine
The relation
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Q4 Show that for a gas obeying van der Walls equation of state,
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Derive an expression for the specific heat difference of a substance whose equation of state is:
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Where a and b are empirical constants
1. The virial equation of state can be written as:
Z = 1+ BP/(RT)
Let B be given as :
B = a – b/T?
Derive the equation for the internal energy departure:
U(T, P) – U(T, P=0).
where a andb are constants.
Chapter 12 Solutions
Thermodynamics: An Engineering Approach
Ch. 12.6 - What is the difference between partial...Ch. 12.6 - Consider the function z(x, y). Plot a differential...Ch. 12.6 - Consider a function z(x, y) and its partial...Ch. 12.6 - Prob. 4PCh. 12.6 - Prob. 5PCh. 12.6 - Consider a function f(x) and its derivative df/dx....Ch. 12.6 - Conside the function z(x, y), its partial...Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Nitrogen gas at 800 R and 50 psia behaves as an...
Ch. 12.6 - Consider an ideal gas at 400 K and 100 kPa. As a...Ch. 12.6 - Using the equation of state P(v a) = RT, verify...Ch. 12.6 - Prove for an ideal gas that (a) the P = constant...Ch. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Show how you would evaluate T, v, u, a, and g from...Ch. 12.6 - Prob. 18PCh. 12.6 - Prob. 19PCh. 12.6 - Prob. 20PCh. 12.6 - Prove that (PT)=kk1(PT)v.Ch. 12.6 - Prob. 22PCh. 12.6 - Prob. 23PCh. 12.6 - Using the Clapeyron equation, estimate the...Ch. 12.6 - Prob. 26PCh. 12.6 - Determine the hfg of refrigerant-134a at 10F on...Ch. 12.6 - Prob. 28PCh. 12.6 - Prob. 29PCh. 12.6 - Two grams of a saturated liquid are converted to a...Ch. 12.6 - Prob. 31PCh. 12.6 - Prob. 32PCh. 12.6 - Prob. 33PCh. 12.6 - Prob. 34PCh. 12.6 - Prob. 35PCh. 12.6 - Prob. 36PCh. 12.6 - Determine the change in the internal energy of...Ch. 12.6 - Prob. 38PCh. 12.6 - Determine the change in the entropy of helium, in...Ch. 12.6 - Prob. 40PCh. 12.6 - Estimate the specific heat difference cp cv for...Ch. 12.6 - Derive expressions for (a) u, (b) h, and (c) s for...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the isothermal...Ch. 12.6 - Prob. 46PCh. 12.6 - Show that cpcv=T(PT)V(VT)P.Ch. 12.6 - Show that the enthalpy of an ideal gas is a...Ch. 12.6 - Prob. 49PCh. 12.6 - Show that = ( P/ T)v.Ch. 12.6 - Prob. 51PCh. 12.6 - Prob. 52PCh. 12.6 - Prob. 53PCh. 12.6 - Prob. 54PCh. 12.6 - Prob. 55PCh. 12.6 - Does the Joule-Thomson coefficient of a substance...Ch. 12.6 - The pressure of a fluid always decreases during an...Ch. 12.6 - Will the temperature of helium change if it is...Ch. 12.6 - Estimate the Joule-Thomson coefficient of...Ch. 12.6 - Estimate the Joule-Thomson coefficient of...Ch. 12.6 - Prob. 61PCh. 12.6 - Steam is throttled slightly from 1 MPa and 300C....Ch. 12.6 - What is the most general equation of state for...Ch. 12.6 - Prob. 64PCh. 12.6 - Consider a gas whose equation of state is P(v a)...Ch. 12.6 - Prob. 66PCh. 12.6 - What is the enthalpy departure?Ch. 12.6 - On the generalized enthalpy departure chart, the...Ch. 12.6 - Why is the generalized enthalpy departure chart...Ch. 12.6 - What is the error involved in the (a) enthalpy and...Ch. 12.6 - Prob. 71PCh. 12.6 - Saturated water vapor at 300C is expanded while...Ch. 12.6 - Determine the enthalpy change and the entropy...Ch. 12.6 - Prob. 74PCh. 12.6 - Prob. 75PCh. 12.6 - Prob. 77PCh. 12.6 - Propane is compressed isothermally by a...Ch. 12.6 - Prob. 81PCh. 12.6 - Prob. 82RPCh. 12.6 - Starting with the relation dh = T ds + vdP, show...Ch. 12.6 - Using the cyclic relation and the first Maxwell...Ch. 12.6 - For ideal gases, the development of the...Ch. 12.6 - Show that cv=T(vT)s(PT)vandcp=T(PT)s(vT)PCh. 12.6 - Temperature and pressure may be defined as...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - Prob. 90RPCh. 12.6 - Prob. 91RPCh. 12.6 - Estimate the cpof nitrogen at 300 kPa and 400 K,...Ch. 12.6 - Prob. 93RPCh. 12.6 - Prob. 94RPCh. 12.6 - Prob. 95RPCh. 12.6 - Methane is to be adiabatically and reversibly...Ch. 12.6 - Prob. 97RPCh. 12.6 - Prob. 98RPCh. 12.6 - Prob. 99RPCh. 12.6 - An adiabatic 0.2-m3 storage tank that is initially...Ch. 12.6 - Prob. 102FEPCh. 12.6 - Consider the liquidvapor saturation curve of a...Ch. 12.6 - For a gas whose equation of state is P(v b) = RT,...Ch. 12.6 - Prob. 105FEPCh. 12.6 - Prob. 106FEP
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- The equation dU = T dS – P dV is applicable to infinitesimal changes occurring in A.A closed system with changes in composition B.An open system with changes in composition C.An open system of constant composition D.A closed system of constant composition E.None of thesearrow_forwardDefine the van der Waals Equation of State.arrow_forwardHelium at 20 bar and 40o is contained in a small cylinder having a volume of 15 cm3. The cylinder is placed in a large container having a volume of 1500 cm3.The large container is perfectly insulated and evacuated.Now helium is allowed to discharge and fill the large container.Calculate final pressure after entire assembly reches equilibrium.arrow_forward
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